Fe/Fe2O3@N‐dopped Porous Carbon: A High‐Performance Catalyst for Selective Hydrogenation of Nitro Compounds
Herein, we designed and prepared a novel Fe/Fe2O3‐based catalyst, in which a remarkable synergistic effect has been revealed between Fe and Fe2O3 encapsulated in N‐doping porous carbon. The Fe‐based catalysts were fabricated via pyrolysis a mixture of MIL‐101(Fe) and melamine. The catalyst exhibits...
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| Veröffentlicht in: | ChemCatChem 2019-01, Vol.11 (2), p.724-728 |
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| creator | Yun, Ruirui Hong, Lirui Ma, Wanjiao Jia, Weiguo Liu, Shoujie Zheng, Baishu |
| description | Herein, we designed and prepared a novel Fe/Fe2O3‐based catalyst, in which a remarkable synergistic effect has been revealed between Fe and Fe2O3 encapsulated in N‐doping porous carbon. The Fe‐based catalysts were fabricated via pyrolysis a mixture of MIL‐101(Fe) and melamine. The catalyst exhibits exceptionally high catalytic activity (TOFs up to 8898 h−1 which is about 100 times higher than the similar kinds of catalysts) and chemoselectivity for nitroarene reduction under mild conditions.
Catalysis magic! Fe‐based NPs catalyst encapsulated in N‐doping porous carbon exhibits high catalytic active (with TOF=8898 h−1 which is about 100 of times higher than the similar catalysts) and chemoselectivity for nitro compounds reduction. |
| doi_str_mv | 10.1002/cctc.201801626 |
| format | Article |
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Catalysis magic! Fe‐based NPs catalyst encapsulated in N‐doping porous carbon exhibits high catalytic active (with TOF=8898 h−1 which is about 100 of times higher than the similar catalysts) and chemoselectivity for nitro compounds reduction.</description><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemoselectivity</subject><subject>Fe-based catalyst</subject><subject>Melamine</subject><subject>N-doped porous carbon</subject><subject>Nitro compounds</subject><subject>Pyrolysis</subject><subject>Synergistic effect</subject><issn>1867-3880</issn><issn>1867-3899</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNo9kN9KwzAUh4MoOKe3Xge87naStGnilaM4J4xt4O5Dmqazo2tq2iq98xF8Rp_Ejsmuzp_fxznwIXRPYEIA6NSY1kwoEAGEU36BRkTwOGBCystzL-Aa3TTNHoBLFkcj5OZ2Ord0zZ5Wv98_matrm-GN865rcKJ96qpHPMOLYvc-xBvrc-cPujJ2CFtd9k2Lhw1-s6U1bfFp8aLPvNvZSreFq7DL8apovcOJO9Suq7LmFl3lumzs3X8do-38eZssguX65TWZLYOaMsaDNE4hg5wIYqRgPDJxTkCDTHWUSkONidJIszQTUcjjkDIYCCGNtiGXIEM2Rg-ns7V3H51tWrV3na-Gj4qSGISQnMBAyRP1VZS2V7UvDtr3ioA6ClVHoeosVCXJNjlP7A8LvG22</recordid><startdate>20190123</startdate><enddate>20190123</enddate><creator>Yun, Ruirui</creator><creator>Hong, Lirui</creator><creator>Ma, Wanjiao</creator><creator>Jia, Weiguo</creator><creator>Liu, Shoujie</creator><creator>Zheng, Baishu</creator><general>Wiley Subscription Services, Inc</general><scope/><orcidid>https://orcid.org/0000-0002-5598-5076</orcidid></search><sort><creationdate>20190123</creationdate><title>Fe/Fe2O3@N‐dopped Porous Carbon: A High‐Performance Catalyst for Selective Hydrogenation of Nitro Compounds</title><author>Yun, Ruirui ; Hong, Lirui ; Ma, Wanjiao ; Jia, Weiguo ; Liu, Shoujie ; Zheng, Baishu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2336-b7b0d0f181c98365c7f10a09ba5b9c2cc5b5a3bd8546742305c789cae4690943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Carbon</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemoselectivity</topic><topic>Fe-based catalyst</topic><topic>Melamine</topic><topic>N-doped porous carbon</topic><topic>Nitro compounds</topic><topic>Pyrolysis</topic><topic>Synergistic effect</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yun, Ruirui</creatorcontrib><creatorcontrib>Hong, Lirui</creatorcontrib><creatorcontrib>Ma, Wanjiao</creatorcontrib><creatorcontrib>Jia, Weiguo</creatorcontrib><creatorcontrib>Liu, Shoujie</creatorcontrib><creatorcontrib>Zheng, Baishu</creatorcontrib><jtitle>ChemCatChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yun, Ruirui</au><au>Hong, Lirui</au><au>Ma, Wanjiao</au><au>Jia, Weiguo</au><au>Liu, Shoujie</au><au>Zheng, Baishu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fe/Fe2O3@N‐dopped Porous Carbon: A High‐Performance Catalyst for Selective Hydrogenation of Nitro Compounds</atitle><jtitle>ChemCatChem</jtitle><date>2019-01-23</date><risdate>2019</risdate><volume>11</volume><issue>2</issue><spage>724</spage><epage>728</epage><pages>724-728</pages><issn>1867-3880</issn><eissn>1867-3899</eissn><abstract>Herein, we designed and prepared a novel Fe/Fe2O3‐based catalyst, in which a remarkable synergistic effect has been revealed between Fe and Fe2O3 encapsulated in N‐doping porous carbon. The Fe‐based catalysts were fabricated via pyrolysis a mixture of MIL‐101(Fe) and melamine. The catalyst exhibits exceptionally high catalytic activity (TOFs up to 8898 h−1 which is about 100 times higher than the similar kinds of catalysts) and chemoselectivity for nitroarene reduction under mild conditions.
Catalysis magic! Fe‐based NPs catalyst encapsulated in N‐doping porous carbon exhibits high catalytic active (with TOF=8898 h−1 which is about 100 of times higher than the similar catalysts) and chemoselectivity for nitro compounds reduction.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/cctc.201801626</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-5598-5076</orcidid></addata></record> |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Carbon Catalysis Catalysts Catalytic activity Chemoselectivity Fe-based catalyst Melamine N-doped porous carbon Nitro compounds Pyrolysis Synergistic effect |
| title | Fe/Fe2O3@N‐dopped Porous Carbon: A High‐Performance Catalyst for Selective Hydrogenation of Nitro Compounds |
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