Yttrium‐Containing Sandwich‐, Ring‐, and Cage‐Type Polyoxovanadates: Synthesis and Characterization

By the reaction of Y(NO3)3 and {Et4N}[VO3] in organic media, yttrium‐containing polyoxovanadates are synthesized and classified into sandwich‐type {Et4N}5[Y(H2O)n(V4O12)2] (1, n = 0–2), ring‐type {Et4N}6[Y(V9O27)] (2), and cage‐type {Et4N}8[Y4(OH)4V20O58] (3). Both compounds 1 and 2 contain a mononu...

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Veröffentlicht in:	European journal of inorganic chemistry 2019-01, Vol.2019 (3-4), p.529-533
Hauptverfasser:	Maruyama, Tatsuya, Kawabata, Hiroko, Kikukawa, Yuji, Hayashi, Yoshihito
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Additives Cages Cations Chemical synthesis Cubane Cubanes Inorganic chemistry Polyoxometalates Polyoxovanadates Vanadates Yttrium
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