Adsorption of Methylene Blue, Brilliant Green and Rhodamine B from Aqueous Solution Using Collagen-g-p(AA-co-NVP)/Fe3O4@SiO2 Nanocomposite Hydrogel

In this study, the collagen-g-poly(acrylic acid-co-N-vinylpyrrolidone)/Fe 3 O 4 @SiO 2 (collagen-g-p(AA-co-NVP)/Fe 3 O 4 @SiO 2 ) as magnetic nanocomposite hydrogel was synthesized by graft copolymerization of acrylic acid (AA) and N-vinylpyrrolidone (NVP) onto collagen in the presence of the Fe 3 O...

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Veröffentlicht in:Journal of polymers and the environment 2019-03, Vol.27 (3), p.581-599
Hauptverfasser: Nakhjiri, Mahdi Taghvay, Bagheri Marandi, Gholam, Kurdtabar, Mehran
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description In this study, the collagen-g-poly(acrylic acid-co-N-vinylpyrrolidone)/Fe 3 O 4 @SiO 2 (collagen-g-p(AA-co-NVP)/Fe 3 O 4 @SiO 2 ) as magnetic nanocomposite hydrogel was synthesized by graft copolymerization of acrylic acid (AA) and N-vinylpyrrolidone (NVP) onto collagen in the presence of the Fe 3 O 4 @SiO 2 using ammonium persulfate as a free radical initiator and bis[2-(methacryloyloxy)ethyl] phosphate as a crosslinker under ultrasound-assisted condition. The blank collagen-g-p(AA-co-NVP) hydrogel and its composite with the Fe 3 O 4 @SiO 2 nanoparticles were characterized by means of FTIR, SEM-EDS, XRD, VSM and TGA methods. The effects of different parameters such as pH, dose of adsorbent and time on swelling behavior were examined. The swelling ratio of the collagen-g-p(AA-co-NVP) hydrogel increased in the presence of the Fe 3 O 4 @SiO 2 nanoparticles. Adsorption behavior of magnetic nanocomposite hydrogel was investigated for the adsorption of dyes and it was found to remove about 93% for methylene blue, 96% for brilliant green and 89% for rhodamine B in 50 mg/L of dyes solutions at pH 7. Kinetic study revealed the applicability of pseudo-first-order and pseudo-second-order models for the adsorption of mentioned dyes. The adsorption isotherm was studied in 25, 35, 45 and 55 °C using Langmuir, Freundlich, Temkin and Sips models and the adsorption data were well described by Langmuir isotherm model. Negative values of ΔG º for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel. Desorption of dyes from the dye loaded nanocomposite hydrogel was simply done in ethanol. The results indicate that the prepared magnetic nanocomposite hydrogel is an efficient adsorbent with high adsorption capacity for the aforementioned dyes.
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Negative values of ΔG º for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel. Desorption of dyes from the dye loaded nanocomposite hydrogel was simply done in ethanol. 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Negative values of ΔG º for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel. Desorption of dyes from the dye loaded nanocomposite hydrogel was simply done in ethanol. 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Negative values of ΔG º for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel. Desorption of dyes from the dye loaded nanocomposite hydrogel was simply done in ethanol. The results indicate that the prepared magnetic nanocomposite hydrogel is an efficient adsorbent with high adsorption capacity for the aforementioned dyes.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10924-019-01372-8</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0003-2527-9119</orcidid></addata></record>
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subjects Acrylic acid
Adsorbents
Adsorption
Ammonium
Ammonium peroxodisulfate
Aqueous solutions
Chemical synthesis
Chemistry
Chemistry and Materials Science
Cobalt
Collagen
Color removal
Copolymerization
Crosslinking
Dyes
Environmental Chemistry
Environmental Engineering/Biotechnology
Ethanol
Free radicals
Graft copolymers
Hydrogels
Industrial Chemistry/Chemical Engineering
Iron oxides
Isotherms
Materials Science
Methylene blue
Nanocomposites
Nanoparticles
Original Paper
pH effects
Polymer Sciences
Rhodamine
Silicon dioxide
Swelling ratio
Ultrasound
Vinylpyrrolidone
title Adsorption of Methylene Blue, Brilliant Green and Rhodamine B from Aqueous Solution Using Collagen-g-p(AA-co-NVP)/Fe3O4@SiO2 Nanocomposite Hydrogel
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