Adsorption of Methylene Blue, Brilliant Green and Rhodamine B from Aqueous Solution Using Collagen-g-p(AA-co-NVP)/Fe3O4@SiO2 Nanocomposite Hydrogel
In this study, the collagen-g-poly(acrylic acid-co-N-vinylpyrrolidone)/Fe 3 O 4 @SiO 2 (collagen-g-p(AA-co-NVP)/Fe 3 O 4 @SiO 2 ) as magnetic nanocomposite hydrogel was synthesized by graft copolymerization of acrylic acid (AA) and N-vinylpyrrolidone (NVP) onto collagen in the presence of the Fe 3 O...
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creator | Nakhjiri, Mahdi Taghvay Bagheri Marandi, Gholam Kurdtabar, Mehran |
description | In this study, the collagen-g-poly(acrylic acid-co-N-vinylpyrrolidone)/Fe
3
O
4
@SiO
2
(collagen-g-p(AA-co-NVP)/Fe
3
O
4
@SiO
2
) as magnetic nanocomposite hydrogel was synthesized by graft copolymerization of acrylic acid (AA) and N-vinylpyrrolidone (NVP) onto collagen in the presence of the Fe
3
O
4
@SiO
2
using ammonium persulfate as a free radical initiator and bis[2-(methacryloyloxy)ethyl] phosphate as a crosslinker under ultrasound-assisted condition. The blank collagen-g-p(AA-co-NVP) hydrogel and its composite with the Fe
3
O
4
@SiO
2
nanoparticles were characterized by means of FTIR, SEM-EDS, XRD, VSM and TGA methods. The effects of different parameters such as pH, dose of adsorbent and time on swelling behavior were examined. The swelling ratio of the collagen-g-p(AA-co-NVP) hydrogel increased in the presence of the Fe
3
O
4
@SiO
2
nanoparticles. Adsorption behavior of magnetic nanocomposite hydrogel was investigated for the adsorption of dyes and it was found to remove about 93% for methylene blue, 96% for brilliant green and 89% for rhodamine B in 50 mg/L of dyes solutions at pH 7. Kinetic study revealed the applicability of pseudo-first-order and pseudo-second-order models for the adsorption of mentioned dyes. The adsorption isotherm was studied in 25, 35, 45 and 55 °C using Langmuir, Freundlich, Temkin and Sips models and the adsorption data were well described by Langmuir isotherm model. Negative values of ΔG
º
for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel. Desorption of dyes from the dye loaded nanocomposite hydrogel was simply done in ethanol. The results indicate that the prepared magnetic nanocomposite hydrogel is an efficient adsorbent with high adsorption capacity for the aforementioned dyes. |
doi_str_mv | 10.1007/s10924-019-01372-8 |
format | Article |
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3
O
4
@SiO
2
(collagen-g-p(AA-co-NVP)/Fe
3
O
4
@SiO
2
) as magnetic nanocomposite hydrogel was synthesized by graft copolymerization of acrylic acid (AA) and N-vinylpyrrolidone (NVP) onto collagen in the presence of the Fe
3
O
4
@SiO
2
using ammonium persulfate as a free radical initiator and bis[2-(methacryloyloxy)ethyl] phosphate as a crosslinker under ultrasound-assisted condition. The blank collagen-g-p(AA-co-NVP) hydrogel and its composite with the Fe
3
O
4
@SiO
2
nanoparticles were characterized by means of FTIR, SEM-EDS, XRD, VSM and TGA methods. The effects of different parameters such as pH, dose of adsorbent and time on swelling behavior were examined. The swelling ratio of the collagen-g-p(AA-co-NVP) hydrogel increased in the presence of the Fe
3
O
4
@SiO
2
nanoparticles. Adsorption behavior of magnetic nanocomposite hydrogel was investigated for the adsorption of dyes and it was found to remove about 93% for methylene blue, 96% for brilliant green and 89% for rhodamine B in 50 mg/L of dyes solutions at pH 7. Kinetic study revealed the applicability of pseudo-first-order and pseudo-second-order models for the adsorption of mentioned dyes. The adsorption isotherm was studied in 25, 35, 45 and 55 °C using Langmuir, Freundlich, Temkin and Sips models and the adsorption data were well described by Langmuir isotherm model. Negative values of ΔG
º
for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel. Desorption of dyes from the dye loaded nanocomposite hydrogel was simply done in ethanol. The results indicate that the prepared magnetic nanocomposite hydrogel is an efficient adsorbent with high adsorption capacity for the aforementioned dyes.</description><identifier>ISSN: 1566-2543</identifier><identifier>EISSN: 1572-8919</identifier><identifier>DOI: 10.1007/s10924-019-01372-8</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acrylic acid ; Adsorbents ; Adsorption ; Ammonium ; Ammonium peroxodisulfate ; Aqueous solutions ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Cobalt ; Collagen ; Color removal ; Copolymerization ; Crosslinking ; Dyes ; Environmental Chemistry ; Environmental Engineering/Biotechnology ; Ethanol ; Free radicals ; Graft copolymers ; Hydrogels ; Industrial Chemistry/Chemical Engineering ; Iron oxides ; Isotherms ; Materials Science ; Methylene blue ; Nanocomposites ; Nanoparticles ; Original Paper ; pH effects ; Polymer Sciences ; Rhodamine ; Silicon dioxide ; Swelling ratio ; Ultrasound ; Vinylpyrrolidone</subject><ispartof>Journal of polymers and the environment, 2019-03, Vol.27 (3), p.581-599</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Journal of Polymers and the Environment is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-f1fb2b77b64567196efde55b5b6e74d2a89e21e734c782a7135859dad57d4a6a3</citedby><cites>FETCH-LOGICAL-c249t-f1fb2b77b64567196efde55b5b6e74d2a89e21e734c782a7135859dad57d4a6a3</cites><orcidid>0000-0003-2527-9119</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10924-019-01372-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10924-019-01372-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Nakhjiri, Mahdi Taghvay</creatorcontrib><creatorcontrib>Bagheri Marandi, Gholam</creatorcontrib><creatorcontrib>Kurdtabar, Mehran</creatorcontrib><title>Adsorption of Methylene Blue, Brilliant Green and Rhodamine B from Aqueous Solution Using Collagen-g-p(AA-co-NVP)/Fe3O4@SiO2 Nanocomposite Hydrogel</title><title>Journal of polymers and the environment</title><addtitle>J Polym Environ</addtitle><description>In this study, the collagen-g-poly(acrylic acid-co-N-vinylpyrrolidone)/Fe
3
O
4
@SiO
2
(collagen-g-p(AA-co-NVP)/Fe
3
O
4
@SiO
2
) as magnetic nanocomposite hydrogel was synthesized by graft copolymerization of acrylic acid (AA) and N-vinylpyrrolidone (NVP) onto collagen in the presence of the Fe
3
O
4
@SiO
2
using ammonium persulfate as a free radical initiator and bis[2-(methacryloyloxy)ethyl] phosphate as a crosslinker under ultrasound-assisted condition. The blank collagen-g-p(AA-co-NVP) hydrogel and its composite with the Fe
3
O
4
@SiO
2
nanoparticles were characterized by means of FTIR, SEM-EDS, XRD, VSM and TGA methods. The effects of different parameters such as pH, dose of adsorbent and time on swelling behavior were examined. The swelling ratio of the collagen-g-p(AA-co-NVP) hydrogel increased in the presence of the Fe
3
O
4
@SiO
2
nanoparticles. Adsorption behavior of magnetic nanocomposite hydrogel was investigated for the adsorption of dyes and it was found to remove about 93% for methylene blue, 96% for brilliant green and 89% for rhodamine B in 50 mg/L of dyes solutions at pH 7. Kinetic study revealed the applicability of pseudo-first-order and pseudo-second-order models for the adsorption of mentioned dyes. The adsorption isotherm was studied in 25, 35, 45 and 55 °C using Langmuir, Freundlich, Temkin and Sips models and the adsorption data were well described by Langmuir isotherm model. Negative values of ΔG
º
for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel. Desorption of dyes from the dye loaded nanocomposite hydrogel was simply done in ethanol. The results indicate that the prepared magnetic nanocomposite hydrogel is an efficient adsorbent with high adsorption capacity for the aforementioned dyes.</description><subject>Acrylic acid</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Ammonium</subject><subject>Ammonium peroxodisulfate</subject><subject>Aqueous solutions</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt</subject><subject>Collagen</subject><subject>Color removal</subject><subject>Copolymerization</subject><subject>Crosslinking</subject><subject>Dyes</subject><subject>Environmental Chemistry</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Ethanol</subject><subject>Free radicals</subject><subject>Graft copolymers</subject><subject>Hydrogels</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Iron oxides</subject><subject>Isotherms</subject><subject>Materials Science</subject><subject>Methylene blue</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Original Paper</subject><subject>pH effects</subject><subject>Polymer Sciences</subject><subject>Rhodamine</subject><subject>Silicon dioxide</subject><subject>Swelling ratio</subject><subject>Ultrasound</subject><subject>Vinylpyrrolidone</subject><issn>1566-2543</issn><issn>1572-8919</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kM1O3DAUhaOKSgXaF2BlqZtWqsF27DjeNTMqPxKdqTrQreXENyHIYwc7Wcxz8MJkmErsWFzds_jOubony84oOaeEyItEiWIcE6rmySXD5YfsmIq9UFQd7XVRYCZ4_ik7SemREKJm43H2XNkU4jD2waPQot8wPuwceEALN8EPtIi9c73xI7qKAB4Zb9Hfh2DNtt8zqI1hi6qnCcKU0Ca46TXoPvW-Q8vgnOnA4w4P36oKNwGv_v35fnEJ-Zr_3PRrhlbGhyZsh5D6EdD1zsbQgfucfWyNS_Dl_z7N7i9_3S2v8e366mZZ3eKGcTXilrY1q6WsCy4KSVUBrQUhalEXILllplTAKMicN7JkRtJclEJZY4W03BQmP82-HnKHGOYX0qgfwxT9fFIzWihKec7kTLED1cSQUoRWD7HfmrjTlOh9-fpQvp7L16_l63I25QdTmmHfQXyLfsf1Al-0hxI</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Nakhjiri, Mahdi Taghvay</creator><creator>Bagheri Marandi, Gholam</creator><creator>Kurdtabar, Mehran</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><orcidid>https://orcid.org/0000-0003-2527-9119</orcidid></search><sort><creationdate>20190301</creationdate><title>Adsorption of Methylene Blue, Brilliant Green and Rhodamine B from Aqueous Solution Using Collagen-g-p(AA-co-NVP)/Fe3O4@SiO2 Nanocomposite Hydrogel</title><author>Nakhjiri, Mahdi Taghvay ; Bagheri Marandi, Gholam ; Kurdtabar, Mehran</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-f1fb2b77b64567196efde55b5b6e74d2a89e21e734c782a7135859dad57d4a6a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acrylic acid</topic><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Ammonium</topic><topic>Ammonium peroxodisulfate</topic><topic>Aqueous solutions</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt</topic><topic>Collagen</topic><topic>Color removal</topic><topic>Copolymerization</topic><topic>Crosslinking</topic><topic>Dyes</topic><topic>Environmental Chemistry</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Ethanol</topic><topic>Free radicals</topic><topic>Graft copolymers</topic><topic>Hydrogels</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Iron oxides</topic><topic>Isotherms</topic><topic>Materials Science</topic><topic>Methylene blue</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Original Paper</topic><topic>pH effects</topic><topic>Polymer Sciences</topic><topic>Rhodamine</topic><topic>Silicon dioxide</topic><topic>Swelling ratio</topic><topic>Ultrasound</topic><topic>Vinylpyrrolidone</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nakhjiri, Mahdi Taghvay</creatorcontrib><creatorcontrib>Bagheri Marandi, Gholam</creatorcontrib><creatorcontrib>Kurdtabar, Mehran</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of polymers and the environment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nakhjiri, Mahdi Taghvay</au><au>Bagheri Marandi, Gholam</au><au>Kurdtabar, Mehran</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of Methylene Blue, Brilliant Green and Rhodamine B from Aqueous Solution Using Collagen-g-p(AA-co-NVP)/Fe3O4@SiO2 Nanocomposite Hydrogel</atitle><jtitle>Journal of polymers and the environment</jtitle><stitle>J Polym Environ</stitle><date>2019-03-01</date><risdate>2019</risdate><volume>27</volume><issue>3</issue><spage>581</spage><epage>599</epage><pages>581-599</pages><issn>1566-2543</issn><eissn>1572-8919</eissn><abstract>In this study, the collagen-g-poly(acrylic acid-co-N-vinylpyrrolidone)/Fe
3
O
4
@SiO
2
(collagen-g-p(AA-co-NVP)/Fe
3
O
4
@SiO
2
) as magnetic nanocomposite hydrogel was synthesized by graft copolymerization of acrylic acid (AA) and N-vinylpyrrolidone (NVP) onto collagen in the presence of the Fe
3
O
4
@SiO
2
using ammonium persulfate as a free radical initiator and bis[2-(methacryloyloxy)ethyl] phosphate as a crosslinker under ultrasound-assisted condition. The blank collagen-g-p(AA-co-NVP) hydrogel and its composite with the Fe
3
O
4
@SiO
2
nanoparticles were characterized by means of FTIR, SEM-EDS, XRD, VSM and TGA methods. The effects of different parameters such as pH, dose of adsorbent and time on swelling behavior were examined. The swelling ratio of the collagen-g-p(AA-co-NVP) hydrogel increased in the presence of the Fe
3
O
4
@SiO
2
nanoparticles. Adsorption behavior of magnetic nanocomposite hydrogel was investigated for the adsorption of dyes and it was found to remove about 93% for methylene blue, 96% for brilliant green and 89% for rhodamine B in 50 mg/L of dyes solutions at pH 7. Kinetic study revealed the applicability of pseudo-first-order and pseudo-second-order models for the adsorption of mentioned dyes. The adsorption isotherm was studied in 25, 35, 45 and 55 °C using Langmuir, Freundlich, Temkin and Sips models and the adsorption data were well described by Langmuir isotherm model. Negative values of ΔG
º
for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of mentioned dyes on magnetic nanocomposite hydrogel. Desorption of dyes from the dye loaded nanocomposite hydrogel was simply done in ethanol. The results indicate that the prepared magnetic nanocomposite hydrogel is an efficient adsorbent with high adsorption capacity for the aforementioned dyes.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10924-019-01372-8</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0003-2527-9119</orcidid></addata></record> |
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language | eng |
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source | SpringerNature Journals |
subjects | Acrylic acid Adsorbents Adsorption Ammonium Ammonium peroxodisulfate Aqueous solutions Chemical synthesis Chemistry Chemistry and Materials Science Cobalt Collagen Color removal Copolymerization Crosslinking Dyes Environmental Chemistry Environmental Engineering/Biotechnology Ethanol Free radicals Graft copolymers Hydrogels Industrial Chemistry/Chemical Engineering Iron oxides Isotherms Materials Science Methylene blue Nanocomposites Nanoparticles Original Paper pH effects Polymer Sciences Rhodamine Silicon dioxide Swelling ratio Ultrasound Vinylpyrrolidone |
title | Adsorption of Methylene Blue, Brilliant Green and Rhodamine B from Aqueous Solution Using Collagen-g-p(AA-co-NVP)/Fe3O4@SiO2 Nanocomposite Hydrogel |
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