3D solvent-free energetic metal–organic framework (EMOF) achieved by removing inclusion molecules from a new coordination polymer

The reaction of CuCl and NaN 3 with 4,4′-azo-1,2,4-triazol-5-one (H 2 ZTO) under solvothermal conditions produced a new 3D heteronuclear Cu( i )-Na( i ) energetic metal–organic framework (EMOF), [Cu 3 Na(ZTO) 2 ] n · n CH 3 CN ( 1 ). Compound 1 underwent a heating–desolvation process that resulted i...

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Veröffentlicht in:	CrystEngComm 2019, Vol.21 (4), p.583-588
Hauptverfasser:	Zhang, Sheng, Wu, Shuo, Zhang, Wendou, Yang, Qi, Wei, Qing, Xie, Gang, Chen, Sanping, Gao, Shengli, Lu, Jack Y.
Format:	Artikel
Sprache:	eng
Schlagworte:	Coordination polymers Copper Crystallography Detonation Exothermic reactions Metal-organic frameworks Sodium azides Solvents Thermal stability
Online-Zugang:	Volltext
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