The electrochemical reduction kinetics of oxygen in dimethylsulfoxide

The quasi-reversible one-electron reduction of oxygen in dimethylsulfoxide is reported for a range of electrode materials (C, Pt, Pd, and Au) and temperatures (293–343 K). Modelling was undertaken using Butler-Volmer and symmetric Marcus-Hush methods, with the former found to provide more reproducib...

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Veröffentlicht in:	Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2018-11, Vol.829, p.16-19
Hauptverfasser:	Hendi, Ruba, Robbs, Peter H., Sampson, Beatrice, Pearce, Ryan, Rees, Neil V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Butler-Volmer Chemical reduction DMSO Electrode materials Electrodes Energy Gold Kinetics Marcus-Hush Organic chemicals Outer-sphere Oxygen Palladium Platinum Reaction kinetics Reduction Symmetry
Online-Zugang:	Volltext
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