Synthesis and Physicochemical Properties of Ruthenium(II) Complexes Having Pentadentate Scaffolds: Water Oxidation Activity and Deactivation Pathway

Five mononuclear RuII complexes supported by two pentadentate polypyridyl ligands, N,N‐bis(2‐pyridylmethyl)‐N‐(bis‐2‐pyridylmethyl)amine (N4Py) {[Ru(N4Py)(Cl)](PF6), 1Cl; [Ru(N4Py)(OH2)](PF6)2, 1Aq} and newly designed N‐benzyl‐N‐((6‐(6‐methylpyridin‐2‐yl)pyridin‐2‐yl)methyl)dipyridin‐2‐yl‐methanamin...

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Veröffentlicht in:	European journal of inorganic chemistry 2019-01, Vol.2019 (2), p.164-177
Hauptverfasser:	Kundu, Animesh, Khan, Srimoyee, Dey, Subhasis, Dutta, Chiranjit, Anoop, Anakuthil, Mandal, Sukanta
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Deactivation Infrared spectroscopy Inorganic chemistry Ligands Mass spectrometry NMR spectroscopy Oxidation Reaction mechanisms Ruthenium Ruthenium compounds Structural analysis Structure elucidation X-ray diffraction
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