Synthesis and characterization of Cu(I) isocyanide complexes exhibiting reversible luminescence

Herein, we describe the synthesis of Cu(I) isocyanide complexes, namely, the [CuI(PDI)] (PDI = 1,4-phenylene diisocyanide) dimer and [Cu2I2(PPh3)2(PDI)2] (PPh3 = triphenylphosphine), which exhibit weak orange (quantum yield Φ = 1%) and intense pale blue (Φ = 13%) emissions in the solid state under U...

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Veröffentlicht in:	Japanese Journal of Applied Physics 2018-08, Vol.57 (8), p.81601
Hauptverfasser:	Hayakawa, Takuya, Nanzan, Chika, Hashimoto, Masashi, Teramae, Hiroyuki, Sakata, Tomomi
Format:	Artikel
Sprache:	eng
Schlagworte:	Charge transfer Density functional theory Dimers Emission spectra Luminescence Synthesis Thermochromism Time dependence Ultraviolet radiation
Online-Zugang:	Volltext
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