Effects of lithium chloride and chain extender on the properties of wood fiber reinforced polyamide 6 composites
Lithium chloride (LiCl) and 2,2‘-(1,4-phenylene)bis(2-oxazoline) (PBO) were first used as the modifier and chain extender to decrease the melting temperature and increase the molecular weight (Mη) of polyamide 6 (PA6), respectively. Then, poplar wood fiber reinforced composites based on PA6 were pre...
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| Veröffentlicht in: | Polymer testing 2018-12, Vol.72, p.132-139 |
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| creator | Xu, Shihua Fang, Yiqun Yi, Shunmin He, Jun Zhai, Xianglin Song, Yongming Wang, Haigang Wang, Qingwen |
| description | Lithium chloride (LiCl) and 2,2‘-(1,4-phenylene)bis(2-oxazoline) (PBO) were first used as the modifier and chain extender to decrease the melting temperature and increase the molecular weight (Mη) of polyamide 6 (PA6), respectively. Then, poplar wood fiber reinforced composites based on PA6 were prepared via hot pressing. The results showed a decrease in the melting point of PA6 (from 220 °C to 190 °C) and the processing temperature (from 240 °C to 210 °C). Thereby, the thermal degradation and discoloration of the composites were significantly restricted. The molecular weight of PA6 could be increased from 33000 to 72800 by PBO. LiCl and PBO increased the impact strength by 50% and 43%, respectively, as well as enhanced the interfacial compatibility between PA6 and poplar wood fiber. Poplar wood fiber improved the flexural strength and modulus by 17% and 122%, respectively.
•LiCl and PBO were used to prepare WPCs based on engineering plastic (PA6).•LiCl modified processing temperature of PA6, and then restricted degradation of WPCs.•Chain extender(PBO) increased the intrinsic viscosity and molecular weight of PA6.•LiCl and PBO significantly improved the mechanical properties of the composites.•LiCl and PBO enhanced the interfacial compatibility of PA6 and wood fiber. |
| doi_str_mv | 10.1016/j.polymertesting.2018.10.005 |
| format | Article |
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•LiCl and PBO were used to prepare WPCs based on engineering plastic (PA6).•LiCl modified processing temperature of PA6, and then restricted degradation of WPCs.•Chain extender(PBO) increased the intrinsic viscosity and molecular weight of PA6.•LiCl and PBO significantly improved the mechanical properties of the composites.•LiCl and PBO enhanced the interfacial compatibility of PA6 and wood fiber.</description><identifier>ISSN: 0142-9418</identifier><identifier>EISSN: 1873-2348</identifier><identifier>DOI: 10.1016/j.polymertesting.2018.10.005</identifier><language>eng</language><publisher>Barking: Elsevier Ltd</publisher><subject>Chain extender ; Chains ; Discoloration ; Fiber composites ; Fiber reinforced polymers ; Hot pressing ; Impact strength ; Lithium ; Lithium chloride ; Melt temperature ; Melting points ; Molecular weight ; Polyamide 6 ; Polyamide resins ; Polymer matrix composites ; Poplar ; Thermal degradation ; Wood fiber ; Wood fiber reinforcement ; Wood fibers</subject><ispartof>Polymer testing, 2018-12, Vol.72, p.132-139</ispartof><rights>2018</rights><rights>Copyright Elsevier BV Dec 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c395t-4df615861e05637e453d8e2082fcd52fce08a63ed14f2f6e652d6c2cd76d18a73</citedby><cites>FETCH-LOGICAL-c395t-4df615861e05637e453d8e2082fcd52fce08a63ed14f2f6e652d6c2cd76d18a73</cites><orcidid>0000-0002-6434-0528</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0142941818312492$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Xu, Shihua</creatorcontrib><creatorcontrib>Fang, Yiqun</creatorcontrib><creatorcontrib>Yi, Shunmin</creatorcontrib><creatorcontrib>He, Jun</creatorcontrib><creatorcontrib>Zhai, Xianglin</creatorcontrib><creatorcontrib>Song, Yongming</creatorcontrib><creatorcontrib>Wang, Haigang</creatorcontrib><creatorcontrib>Wang, Qingwen</creatorcontrib><title>Effects of lithium chloride and chain extender on the properties of wood fiber reinforced polyamide 6 composites</title><title>Polymer testing</title><description>Lithium chloride (LiCl) and 2,2‘-(1,4-phenylene)bis(2-oxazoline) (PBO) were first used as the modifier and chain extender to decrease the melting temperature and increase the molecular weight (Mη) of polyamide 6 (PA6), respectively. Then, poplar wood fiber reinforced composites based on PA6 were prepared via hot pressing. The results showed a decrease in the melting point of PA6 (from 220 °C to 190 °C) and the processing temperature (from 240 °C to 210 °C). Thereby, the thermal degradation and discoloration of the composites were significantly restricted. The molecular weight of PA6 could be increased from 33000 to 72800 by PBO. LiCl and PBO increased the impact strength by 50% and 43%, respectively, as well as enhanced the interfacial compatibility between PA6 and poplar wood fiber. Poplar wood fiber improved the flexural strength and modulus by 17% and 122%, respectively.
•LiCl and PBO were used to prepare WPCs based on engineering plastic (PA6).•LiCl modified processing temperature of PA6, and then restricted degradation of WPCs.•Chain extender(PBO) increased the intrinsic viscosity and molecular weight of PA6.•LiCl and PBO significantly improved the mechanical properties of the composites.•LiCl and PBO enhanced the interfacial compatibility of PA6 and wood fiber.</description><subject>Chain extender</subject><subject>Chains</subject><subject>Discoloration</subject><subject>Fiber composites</subject><subject>Fiber reinforced polymers</subject><subject>Hot pressing</subject><subject>Impact strength</subject><subject>Lithium</subject><subject>Lithium chloride</subject><subject>Melt temperature</subject><subject>Melting points</subject><subject>Molecular weight</subject><subject>Polyamide 6</subject><subject>Polyamide resins</subject><subject>Polymer matrix composites</subject><subject>Poplar</subject><subject>Thermal degradation</subject><subject>Wood fiber</subject><subject>Wood fiber reinforcement</subject><subject>Wood fibers</subject><issn>0142-9418</issn><issn>1873-2348</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqNUMtOwzAQtBBIlMI_WIJriu0kjiNxQVULSJW4wNkK9pq6SuJgpzz-ng3lwo2LV9Y8dnYIueJswRmX17vFENqvDuIIafT960IwrhBaMFYekRlXVZ6JvFDHZMZ4IbK64OqUnKW0Y8hAhxkZVs6BGRMNjrZ-3Pp9R822DdFboE1v8dP4nsLnCL2FSENPxy3QIYYB13r4EX6EYKnzL4hH8L0L0YClU7amm3wkNaEbQvKY85ycuKZNcPE75-R5vXpa3mebx7uH5e0mM3ldjllhneSlkhxYKfMKijK3CgRTwhlb4gNMNTIHywsnnARZCiuNMLaSlqumyufk8uCLUd_22I_ehX3scaUWXEpW13lZI-vmwDIxpBTB6SH6rolfmjM9dax3-m_Heup4QrFBlK8PcsBL3j1EnYyHHq_3EVvVNvj_GX0D5T2QVA</recordid><startdate>20181201</startdate><enddate>20181201</enddate><creator>Xu, Shihua</creator><creator>Fang, Yiqun</creator><creator>Yi, Shunmin</creator><creator>He, Jun</creator><creator>Zhai, Xianglin</creator><creator>Song, Yongming</creator><creator>Wang, Haigang</creator><creator>Wang, Qingwen</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-6434-0528</orcidid></search><sort><creationdate>20181201</creationdate><title>Effects of lithium chloride and chain extender on the properties of wood fiber reinforced polyamide 6 composites</title><author>Xu, Shihua ; Fang, Yiqun ; Yi, Shunmin ; He, Jun ; Zhai, Xianglin ; Song, Yongming ; Wang, Haigang ; Wang, Qingwen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c395t-4df615861e05637e453d8e2082fcd52fce08a63ed14f2f6e652d6c2cd76d18a73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chain extender</topic><topic>Chains</topic><topic>Discoloration</topic><topic>Fiber composites</topic><topic>Fiber reinforced polymers</topic><topic>Hot pressing</topic><topic>Impact strength</topic><topic>Lithium</topic><topic>Lithium chloride</topic><topic>Melt temperature</topic><topic>Melting points</topic><topic>Molecular weight</topic><topic>Polyamide 6</topic><topic>Polyamide resins</topic><topic>Polymer matrix composites</topic><topic>Poplar</topic><topic>Thermal degradation</topic><topic>Wood fiber</topic><topic>Wood fiber reinforcement</topic><topic>Wood fibers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Shihua</creatorcontrib><creatorcontrib>Fang, Yiqun</creatorcontrib><creatorcontrib>Yi, Shunmin</creatorcontrib><creatorcontrib>He, Jun</creatorcontrib><creatorcontrib>Zhai, Xianglin</creatorcontrib><creatorcontrib>Song, Yongming</creatorcontrib><creatorcontrib>Wang, Haigang</creatorcontrib><creatorcontrib>Wang, Qingwen</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer testing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Shihua</au><au>Fang, Yiqun</au><au>Yi, Shunmin</au><au>He, Jun</au><au>Zhai, Xianglin</au><au>Song, Yongming</au><au>Wang, Haigang</au><au>Wang, Qingwen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of lithium chloride and chain extender on the properties of wood fiber reinforced polyamide 6 composites</atitle><jtitle>Polymer testing</jtitle><date>2018-12-01</date><risdate>2018</risdate><volume>72</volume><spage>132</spage><epage>139</epage><pages>132-139</pages><issn>0142-9418</issn><eissn>1873-2348</eissn><abstract>Lithium chloride (LiCl) and 2,2‘-(1,4-phenylene)bis(2-oxazoline) (PBO) were first used as the modifier and chain extender to decrease the melting temperature and increase the molecular weight (Mη) of polyamide 6 (PA6), respectively. Then, poplar wood fiber reinforced composites based on PA6 were prepared via hot pressing. The results showed a decrease in the melting point of PA6 (from 220 °C to 190 °C) and the processing temperature (from 240 °C to 210 °C). Thereby, the thermal degradation and discoloration of the composites were significantly restricted. The molecular weight of PA6 could be increased from 33000 to 72800 by PBO. LiCl and PBO increased the impact strength by 50% and 43%, respectively, as well as enhanced the interfacial compatibility between PA6 and poplar wood fiber. Poplar wood fiber improved the flexural strength and modulus by 17% and 122%, respectively.
•LiCl and PBO were used to prepare WPCs based on engineering plastic (PA6).•LiCl modified processing temperature of PA6, and then restricted degradation of WPCs.•Chain extender(PBO) increased the intrinsic viscosity and molecular weight of PA6.•LiCl and PBO significantly improved the mechanical properties of the composites.•LiCl and PBO enhanced the interfacial compatibility of PA6 and wood fiber.</abstract><cop>Barking</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymertesting.2018.10.005</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-6434-0528</orcidid></addata></record> |
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| source | Elsevier ScienceDirect Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
| subjects | Chain extender Chains Discoloration Fiber composites Fiber reinforced polymers Hot pressing Impact strength Lithium Lithium chloride Melt temperature Melting points Molecular weight Polyamide 6 Polyamide resins Polymer matrix composites Poplar Thermal degradation Wood fiber Wood fiber reinforcement Wood fibers |
| title | Effects of lithium chloride and chain extender on the properties of wood fiber reinforced polyamide 6 composites |
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