Metal-free catalyzed ring-opening polymerization and block copolymerization of ω-pentadecalactone using amino-ended initiators

[Display omitted] •ROP of pentadecalactone initiated by amino-ended compounds and catalyzed by organic bases or enzymes is described.•The described method allows obtaining polyesters absent of metallic contaminants.•Triblock copolymers of ethylene glycol and pentadecalactone with controlled polyeste...

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Veröffentlicht in:	European polymer journal 2018-11, Vol.108, p.380-389
Hauptverfasser:	Tinajero-Díaz, E., Martínez-de Ilarduya, A., Muñoz-Guerra, S., de-Paz, M.-V., Galbis, Elsa
Format:	Artikel
Sprache:	eng
Schlagworte:	Amphiphilic block copolymer nanoparticles Amphiphilic block copolymers Biomedical materials Block copolymers Catalysis Chemical synthesis Copolymerization Copolymers Enzymatic ring-opening polymerization Enzymes Initiators Macrolactones polymerization Morphology Nanoparticles NMR Nuclear magnetic resonance Polyester resins Polyethylene glycol Polyethyleneglycol-polyester copolymers Polymerization Ring opening polymerization
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