An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites
The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF 1.2 –thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the co...
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| Veröffentlicht in: | Journal of structural chemistry 2018-12, Vol.59 (8), p.1841-1848 |
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| container_issue | 8 |
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| container_title | Journal of structural chemistry |
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| creator | Mitkin, V. N. Asanov, I. P. Sagidullin, A. K. |
| description | The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF
1.2
–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF
1+
x
coated by an outer nanolayer
sp
2
-C–
sp
3
-C–F. |
| doi_str_mv | 10.1134/S0022476618080127 |
| format | Article |
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1.2
–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF
1+
x
coated by an outer nanolayer
sp
2
-C–
sp
3
-C–F.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476618080127</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Adsorption ; Atomic ; Atomic/Molecular Structure and Spectra ; Carbon ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Low temperature ; Molecular ; Nanocomposites ; Nanomaterials ; Nanoparticles ; Optical and Plasma Physics ; Perfluorocarbons ; Photoelectrons ; Physical Chemistry ; Solid State Physics ; Surface layers ; X ray photoelectron spectroscopy</subject><ispartof>Journal of structural chemistry, 2018-12, Vol.59 (8), p.1841-1848</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-fab614dfa2593843f66b1abae18fdd01c7b73a50e861d448a7e052fb42594e7c3</citedby><cites>FETCH-LOGICAL-c316t-fab614dfa2593843f66b1abae18fdd01c7b73a50e861d448a7e052fb42594e7c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476618080127$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476618080127$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Mitkin, V. N.</creatorcontrib><creatorcontrib>Asanov, I. P.</creatorcontrib><creatorcontrib>Sagidullin, A. K.</creatorcontrib><title>An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF
1.2
–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF
1+
x
coated by an outer nanolayer
sp
2
-C–
sp
3
-C–F.</description><subject>Adsorption</subject><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Carbon</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Low temperature</subject><subject>Molecular</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Optical and Plasma Physics</subject><subject>Perfluorocarbons</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Solid State Physics</subject><subject>Surface layers</subject><subject>X ray photoelectron spectroscopy</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEQxYMoWKsfwFvA82omm02yx1L8B6UeWsHbkt1N6tY2WZMs0m9v2goexNPw5v3eGxiEroHcAuTsbkEIpUxwDpJIAlScoBEUIs-kEOUpGu3tbO-fo4sQ1oSQUpZ8hD4mFr_1ASvb4pn7ypZ622uv4uA1nnfRu5W2eNIG5_vYOYsXcWh32Bkc33USfmgOaFpMla-dzR42g_OuOQg8V9Y1btu70EUdLtGZUZugr37mGL0-3C-nT9ns5fF5OpllTQ48ZkbVHFhrFC3KXLLccF6DqpUGadqWQCNqkauCaMmhZUwqoUlBTc0Sz7Ro8jG6Ofb23n0OOsRq7QZv08mKAmeclpKXiYIj1XgXgtem6n23VX5XAan2P63-_DRl6DETEmtX2v82_x_6BrD5eaU</recordid><startdate>20181201</startdate><enddate>20181201</enddate><creator>Mitkin, V. N.</creator><creator>Asanov, I. P.</creator><creator>Sagidullin, A. K.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20181201</creationdate><title>An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites</title><author>Mitkin, V. N. ; Asanov, I. P. ; Sagidullin, A. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-fab614dfa2593843f66b1abae18fdd01c7b73a50e861d448a7e052fb42594e7c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Adsorption</topic><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Carbon</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Low temperature</topic><topic>Molecular</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Optical and Plasma Physics</topic><topic>Perfluorocarbons</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Solid State Physics</topic><topic>Surface layers</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mitkin, V. N.</creatorcontrib><creatorcontrib>Asanov, I. P.</creatorcontrib><creatorcontrib>Sagidullin, A. K.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mitkin, V. N.</au><au>Asanov, I. P.</au><au>Sagidullin, A. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2018-12-01</date><risdate>2018</risdate><volume>59</volume><issue>8</issue><spage>1841</spage><epage>1848</epage><pages>1841-1848</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF
1.2
–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF
1+
x
coated by an outer nanolayer
sp
2
-C–
sp
3
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| ispartof | Journal of structural chemistry, 2018-12, Vol.59 (8), p.1841-1848 |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Adsorption Atomic Atomic/Molecular Structure and Spectra Carbon Chemistry Chemistry and Materials Science Inorganic Chemistry Low temperature Molecular Nanocomposites Nanomaterials Nanoparticles Optical and Plasma Physics Perfluorocarbons Photoelectrons Physical Chemistry Solid State Physics Surface layers X ray photoelectron spectroscopy |
| title | An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites |
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