Plasma Based Synthesis of Nanomaterials for Development of Plasmon Enhanced Infrared Responsive Optoelectronic Device

We report plasma based fabrication of an optoelectronic device with plasmon enhanced infrared sensitivity realized by integrating plasmonic gold nanoparticles (Au NPs) with an organic semiconductor matrix. A blend of plasma polymerized aniline (PPA)-Rubrene, prepared by a novel plasma based method a...

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Veröffentlicht in:Plasma chemistry and plasma processing 2019-01, Vol.39 (1), p.277-292
Hauptverfasser: Gogoi, Deepshikha, Hussain, Amreen A., Pal, Arup R.
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creator Gogoi, Deepshikha
Hussain, Amreen A.
Pal, Arup R.
description We report plasma based fabrication of an optoelectronic device with plasmon enhanced infrared sensitivity realized by integrating plasmonic gold nanoparticles (Au NPs) with an organic semiconductor matrix. A blend of plasma polymerized aniline (PPA)-Rubrene, prepared by a novel plasma based method acts as the semiconductor matrix for charge transport in the device geometry. Significantly improved photovoltaic property of the device with an open circuit voltage (V OC ) of 1.08 V is obtained with the addition of Au NPs in the device. We experimentally demonstrate very efficient plasmon generated charge transfer between Au NPs and PPA-Rubrene system leading to significant enhancement of infrared responsivity of 2200% at the plasmon absorption band of Au. This study demonstrates how plasma based processes can be utilized to prepare plasmonic nano-materials and also to synthesize organic semiconductor materials suitable for development of plasmonic charge generating devices responsive to infrared region of the electromagnetic spectrum.
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subjects Absorption spectra
Aniline
Characterization and Evaluation of Materials
Charge transport
Chemistry
Chemistry and Materials Science
Classical Mechanics
Gold
Infrared radiation
Inorganic Chemistry
Mechanical Engineering
Nanomaterials
Nanoparticles
Open circuit voltage
Optoelectronic devices
Original Paper
Plasma
Semiconductor materials
Sensitivity enhancement
title Plasma Based Synthesis of Nanomaterials for Development of Plasmon Enhanced Infrared Responsive Optoelectronic Device
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