Kinetics of Np(VI) Reduction with Diformylhydrazine in Nitric Acid
The kinetics of the Np(VI) reduction with diformylhydrazine in a nitric acid solution was studied by spectrophotometry. The reaction rate increases with an increase in the reductant concentration and temperature and decreases with an increase in the HNO 3 concentration. The reaction order with respe...
Gespeichert in:
| Veröffentlicht in: | Radiochemistry (New York, N.Y.) N.Y.), 2018-11, Vol.60 (6), p.581-587 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 587 |
|---|---|
| container_issue | 6 |
| container_start_page | 581 |
| container_title | Radiochemistry (New York, N.Y.) |
| container_volume | 60 |
| creator | Dvoeglazov, K. N. Pavlyukevich, E. Yu Mitrikas, P. V. |
| description | The kinetics of the Np(VI) reduction with diformylhydrazine in a nitric acid solution was studied by spectrophotometry. The reaction rate increases with an increase in the reductant concentration and temperature and decreases with an increase in the HNO
3
concentration. The reaction order with respect to Np, diformylhydrazine, and HNO
3
is 1, 1.3, and–1.55, respectively. The activation energy of the reaction is 85 ± 10 kJ mol
–1
. |
| doi_str_mv | 10.1134/S1066362218060036 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2160779042</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2160779042</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-abe833fe528e3d62135753c2379f7d562a065dde691a7e7fccb4c61bbb481e413</originalsourceid><addsrcrecordid>eNp1kEtLAzEUhYMoWKs_wF3AjS5Gc5OZm3RZ38VSwdd2mMnDprQzNZki9debUsGFuLoXznfO5R5CjoGdA4j84hkYokDOQTFkTOAO6QEylQmu1G7ak5xt9H1yEOOMMaYAVY9cPvjGdl5H2jo6WZ6-jc7okzUr3fm2oZ--m9Jr79qwWM-naxOqr4RT39CJ74LXdKi9OSR7rppHe_Qz--T19ubl6j4bP96NrobjTAvALqtqq4RwtuDKCoMcRCELobmQAydNgbxiWBhjcQCVtNJpXecaoa7rXIHNQfTJyTZ3GdqPlY1dOWtXoUknS55elXLAcp4o2FI6tDEG68pl8IsqrEtg5aaq8k9VycO3npjY5t2G3-T_Td-B02kJ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2160779042</pqid></control><display><type>article</type><title>Kinetics of Np(VI) Reduction with Diformylhydrazine in Nitric Acid</title><source>SpringerNature Journals</source><creator>Dvoeglazov, K. N. ; Pavlyukevich, E. Yu ; Mitrikas, P. V.</creator><creatorcontrib>Dvoeglazov, K. N. ; Pavlyukevich, E. Yu ; Mitrikas, P. V.</creatorcontrib><description>The kinetics of the Np(VI) reduction with diformylhydrazine in a nitric acid solution was studied by spectrophotometry. The reaction rate increases with an increase in the reductant concentration and temperature and decreases with an increase in the HNO
3
concentration. The reaction order with respect to Np, diformylhydrazine, and HNO
3
is 1, 1.3, and–1.55, respectively. The activation energy of the reaction is 85 ± 10 kJ mol
–1
.</description><identifier>ISSN: 1066-3622</identifier><identifier>EISSN: 1608-3288</identifier><identifier>DOI: 10.1134/S1066362218060036</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Nitric acid ; Nuclear Chemistry ; Oxidation ; Reaction kinetics ; Reduction ; Spectrophotometry</subject><ispartof>Radiochemistry (New York, N.Y.), 2018-11, Vol.60 (6), p.581-587</ispartof><rights>Pleiades Publishing, Inc. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-abe833fe528e3d62135753c2379f7d562a065dde691a7e7fccb4c61bbb481e413</citedby><cites>FETCH-LOGICAL-c316t-abe833fe528e3d62135753c2379f7d562a065dde691a7e7fccb4c61bbb481e413</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1066362218060036$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1066362218060036$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Dvoeglazov, K. N.</creatorcontrib><creatorcontrib>Pavlyukevich, E. Yu</creatorcontrib><creatorcontrib>Mitrikas, P. V.</creatorcontrib><title>Kinetics of Np(VI) Reduction with Diformylhydrazine in Nitric Acid</title><title>Radiochemistry (New York, N.Y.)</title><addtitle>Radiochemistry</addtitle><description>The kinetics of the Np(VI) reduction with diformylhydrazine in a nitric acid solution was studied by spectrophotometry. The reaction rate increases with an increase in the reductant concentration and temperature and decreases with an increase in the HNO
3
concentration. The reaction order with respect to Np, diformylhydrazine, and HNO
3
is 1, 1.3, and–1.55, respectively. The activation energy of the reaction is 85 ± 10 kJ mol
–1
.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Nitric acid</subject><subject>Nuclear Chemistry</subject><subject>Oxidation</subject><subject>Reaction kinetics</subject><subject>Reduction</subject><subject>Spectrophotometry</subject><issn>1066-3622</issn><issn>1608-3288</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLAzEUhYMoWKs_wF3AjS5Gc5OZm3RZ38VSwdd2mMnDprQzNZki9debUsGFuLoXznfO5R5CjoGdA4j84hkYokDOQTFkTOAO6QEylQmu1G7ak5xt9H1yEOOMMaYAVY9cPvjGdl5H2jo6WZ6-jc7okzUr3fm2oZ--m9Jr79qwWM-naxOqr4RT39CJ74LXdKi9OSR7rppHe_Qz--T19ubl6j4bP96NrobjTAvALqtqq4RwtuDKCoMcRCELobmQAydNgbxiWBhjcQCVtNJpXecaoa7rXIHNQfTJyTZ3GdqPlY1dOWtXoUknS55elXLAcp4o2FI6tDEG68pl8IsqrEtg5aaq8k9VycO3npjY5t2G3-T_Td-B02kJ</recordid><startdate>20181101</startdate><enddate>20181101</enddate><creator>Dvoeglazov, K. N.</creator><creator>Pavlyukevich, E. Yu</creator><creator>Mitrikas, P. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20181101</creationdate><title>Kinetics of Np(VI) Reduction with Diformylhydrazine in Nitric Acid</title><author>Dvoeglazov, K. N. ; Pavlyukevich, E. Yu ; Mitrikas, P. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-abe833fe528e3d62135753c2379f7d562a065dde691a7e7fccb4c61bbb481e413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Nitric acid</topic><topic>Nuclear Chemistry</topic><topic>Oxidation</topic><topic>Reaction kinetics</topic><topic>Reduction</topic><topic>Spectrophotometry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dvoeglazov, K. N.</creatorcontrib><creatorcontrib>Pavlyukevich, E. Yu</creatorcontrib><creatorcontrib>Mitrikas, P. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Radiochemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dvoeglazov, K. N.</au><au>Pavlyukevich, E. Yu</au><au>Mitrikas, P. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetics of Np(VI) Reduction with Diformylhydrazine in Nitric Acid</atitle><jtitle>Radiochemistry (New York, N.Y.)</jtitle><stitle>Radiochemistry</stitle><date>2018-11-01</date><risdate>2018</risdate><volume>60</volume><issue>6</issue><spage>581</spage><epage>587</epage><pages>581-587</pages><issn>1066-3622</issn><eissn>1608-3288</eissn><abstract>The kinetics of the Np(VI) reduction with diformylhydrazine in a nitric acid solution was studied by spectrophotometry. The reaction rate increases with an increase in the reductant concentration and temperature and decreases with an increase in the HNO
3
concentration. The reaction order with respect to Np, diformylhydrazine, and HNO
3
is 1, 1.3, and–1.55, respectively. The activation energy of the reaction is 85 ± 10 kJ mol
–1
.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1066362218060036</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1066-3622 |
| ispartof | Radiochemistry (New York, N.Y.), 2018-11, Vol.60 (6), p.581-587 |
| issn | 1066-3622 1608-3288 |
| language | eng |
| recordid | cdi_proquest_journals_2160779042 |
| source | SpringerNature Journals |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Nitric acid Nuclear Chemistry Oxidation Reaction kinetics Reduction Spectrophotometry |
| title | Kinetics of Np(VI) Reduction with Diformylhydrazine in Nitric Acid |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T17%3A03%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Kinetics%20of%20Np(VI)%20Reduction%20with%20Diformylhydrazine%20in%20Nitric%20Acid&rft.jtitle=Radiochemistry%20(New%20York,%20N.Y.)&rft.au=Dvoeglazov,%20K.%20N.&rft.date=2018-11-01&rft.volume=60&rft.issue=6&rft.spage=581&rft.epage=587&rft.pages=581-587&rft.issn=1066-3622&rft.eissn=1608-3288&rft_id=info:doi/10.1134/S1066362218060036&rft_dat=%3Cproquest_cross%3E2160779042%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2160779042&rft_id=info:pmid/&rfr_iscdi=true |