Preparation of conductive layer on polyimide ion-track membrane by Ar ion implantation
We implanted polyimide (PI) ion-track membranes with 100 keV Ar+ to prepare a cathode for the galvanic deposition of platinum (Pt) nanocones. The surface layer of the irradiated PI films was carbonized to produce a graphitic structure at a fluence of 7.6 × 1016 ions/cm2. The carbonized surface exhib...
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| Veröffentlicht in: | Surface & coatings technology 2018-12, Vol.355, p.181-185 |
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| container_title | Surface & coatings technology |
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| creator | Kakitani, Kenta Koshikawa, Hiroshi Yamaki, Tetsuya Yamamoto, Shunya Sato, Yuma Sugimoto, Masaki Sawada, Shin-ichi |
| description | We implanted polyimide (PI) ion-track membranes with 100 keV Ar+ to prepare a cathode for the galvanic deposition of platinum (Pt) nanocones. The surface layer of the irradiated PI films was carbonized to produce a graphitic structure at a fluence of 7.6 × 1016 ions/cm2. The carbonized surface exhibited an electric conductivity and electrochemical stability, which could be sufficient for use as a cathode. Pt nanocones were electrodeposited into the pores of the PI ion-track membrane after the implantation under the same conditions. This indicated that the Ar+ irradiation resulted in the preparation of a conductive layer on the total surface area of the ion-track membrane including the innermost regions of the pores.
•Polyimide ion-track membranes were irradiated with 100 keV argon ions (Ar+).•The surface of the membranes became conductive due to carbonization.•The Ar+-irradiated surface was employed as an electrode for electrodeposition.•Platinum nanocones were electrodeposited into the pores of the membrane. |
| doi_str_mv | 10.1016/j.surfcoat.2018.05.057 |
| format | Article |
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•Polyimide ion-track membranes were irradiated with 100 keV argon ions (Ar+).•The surface of the membranes became conductive due to carbonization.•The Ar+-irradiated surface was employed as an electrode for electrodeposition.•Platinum nanocones were electrodeposited into the pores of the membrane.</description><identifier>ISSN: 0257-8972</identifier><identifier>EISSN: 1879-3347</identifier><identifier>DOI: 10.1016/j.surfcoat.2018.05.057</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Argon ion implantation ; Carbonization ; Cathodes ; Electrical resistivity ; Fluence ; Graphitic structure ; Heat conductivity ; Ion implantation ; Ion-track membrane ; Irradiation ; Membranes ; Platinum ; Polyimide ; Pt nanocones ; Surface layers</subject><ispartof>Surface & coatings technology, 2018-12, Vol.355, p.181-185</ispartof><rights>2018 Elsevier B.V.</rights><rights>Copyright Elsevier BV Dec 15, 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-d391fc7d2b790c602d241ce6a8d6b432b12b9f230e03da52dc64288257cd6fca3</citedby><cites>FETCH-LOGICAL-c406t-d391fc7d2b790c602d241ce6a8d6b432b12b9f230e03da52dc64288257cd6fca3</cites><orcidid>0000-0002-6574-3011</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0257897218305425$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Kakitani, Kenta</creatorcontrib><creatorcontrib>Koshikawa, Hiroshi</creatorcontrib><creatorcontrib>Yamaki, Tetsuya</creatorcontrib><creatorcontrib>Yamamoto, Shunya</creatorcontrib><creatorcontrib>Sato, Yuma</creatorcontrib><creatorcontrib>Sugimoto, Masaki</creatorcontrib><creatorcontrib>Sawada, Shin-ichi</creatorcontrib><title>Preparation of conductive layer on polyimide ion-track membrane by Ar ion implantation</title><title>Surface & coatings technology</title><description>We implanted polyimide (PI) ion-track membranes with 100 keV Ar+ to prepare a cathode for the galvanic deposition of platinum (Pt) nanocones. The surface layer of the irradiated PI films was carbonized to produce a graphitic structure at a fluence of 7.6 × 1016 ions/cm2. The carbonized surface exhibited an electric conductivity and electrochemical stability, which could be sufficient for use as a cathode. Pt nanocones were electrodeposited into the pores of the PI ion-track membrane after the implantation under the same conditions. This indicated that the Ar+ irradiation resulted in the preparation of a conductive layer on the total surface area of the ion-track membrane including the innermost regions of the pores.
•Polyimide ion-track membranes were irradiated with 100 keV argon ions (Ar+).•The surface of the membranes became conductive due to carbonization.•The Ar+-irradiated surface was employed as an electrode for electrodeposition.•Platinum nanocones were electrodeposited into the pores of the membrane.</description><subject>Argon ion implantation</subject><subject>Carbonization</subject><subject>Cathodes</subject><subject>Electrical resistivity</subject><subject>Fluence</subject><subject>Graphitic structure</subject><subject>Heat conductivity</subject><subject>Ion implantation</subject><subject>Ion-track membrane</subject><subject>Irradiation</subject><subject>Membranes</subject><subject>Platinum</subject><subject>Polyimide</subject><subject>Pt nanocones</subject><subject>Surface layers</subject><issn>0257-8972</issn><issn>1879-3347</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFUE1LxDAUDKLguvoXJOC5NR9t0t5cFr9gQQ_qNaRJCqltU5N0of_erKtnYeDBezPzmAHgGqMcI8xuuzzMvlVOxpwgXOWoTOAnYIUrXmeUFvwUrBApeVbVnJyDixA6hBDmdbECH6_eTNLLaN0IXQuVG_Wsot0b2MvFeJjWk-sXO1htYCJl0Uv1CQczNF6OBjYL3PjDAdph6uUYf6wuwVkr-2CufucavD_cv22fst3L4_N2s8tUgVjMNK1xq7gmDa-RYohoUmBlmKw0awpKGkyauiUUGUS1LIlWrCBVlbIozVol6RrcHH0n775mE6Lo3OzH9FIQzBAty6ooEosdWcq7ELxpxeTtIP0iMBKHDkUn_joUhw4FKhN4Et4dhSZl2FvjRVDWjMpo642KQjv7n8U3gkV_GQ</recordid><startdate>20181215</startdate><enddate>20181215</enddate><creator>Kakitani, Kenta</creator><creator>Koshikawa, Hiroshi</creator><creator>Yamaki, Tetsuya</creator><creator>Yamamoto, Shunya</creator><creator>Sato, Yuma</creator><creator>Sugimoto, Masaki</creator><creator>Sawada, Shin-ichi</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-6574-3011</orcidid></search><sort><creationdate>20181215</creationdate><title>Preparation of conductive layer on polyimide ion-track membrane by Ar ion implantation</title><author>Kakitani, Kenta ; Koshikawa, Hiroshi ; Yamaki, Tetsuya ; Yamamoto, Shunya ; Sato, Yuma ; Sugimoto, Masaki ; Sawada, Shin-ichi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-d391fc7d2b790c602d241ce6a8d6b432b12b9f230e03da52dc64288257cd6fca3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Argon ion implantation</topic><topic>Carbonization</topic><topic>Cathodes</topic><topic>Electrical resistivity</topic><topic>Fluence</topic><topic>Graphitic structure</topic><topic>Heat conductivity</topic><topic>Ion implantation</topic><topic>Ion-track membrane</topic><topic>Irradiation</topic><topic>Membranes</topic><topic>Platinum</topic><topic>Polyimide</topic><topic>Pt nanocones</topic><topic>Surface layers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kakitani, Kenta</creatorcontrib><creatorcontrib>Koshikawa, Hiroshi</creatorcontrib><creatorcontrib>Yamaki, Tetsuya</creatorcontrib><creatorcontrib>Yamamoto, Shunya</creatorcontrib><creatorcontrib>Sato, Yuma</creatorcontrib><creatorcontrib>Sugimoto, Masaki</creatorcontrib><creatorcontrib>Sawada, Shin-ichi</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Surface & coatings technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kakitani, Kenta</au><au>Koshikawa, Hiroshi</au><au>Yamaki, Tetsuya</au><au>Yamamoto, Shunya</au><au>Sato, Yuma</au><au>Sugimoto, Masaki</au><au>Sawada, Shin-ichi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of conductive layer on polyimide ion-track membrane by Ar ion implantation</atitle><jtitle>Surface & coatings technology</jtitle><date>2018-12-15</date><risdate>2018</risdate><volume>355</volume><spage>181</spage><epage>185</epage><pages>181-185</pages><issn>0257-8972</issn><eissn>1879-3347</eissn><abstract>We implanted polyimide (PI) ion-track membranes with 100 keV Ar+ to prepare a cathode for the galvanic deposition of platinum (Pt) nanocones. The surface layer of the irradiated PI films was carbonized to produce a graphitic structure at a fluence of 7.6 × 1016 ions/cm2. The carbonized surface exhibited an electric conductivity and electrochemical stability, which could be sufficient for use as a cathode. Pt nanocones were electrodeposited into the pores of the PI ion-track membrane after the implantation under the same conditions. This indicated that the Ar+ irradiation resulted in the preparation of a conductive layer on the total surface area of the ion-track membrane including the innermost regions of the pores.
•Polyimide ion-track membranes were irradiated with 100 keV argon ions (Ar+).•The surface of the membranes became conductive due to carbonization.•The Ar+-irradiated surface was employed as an electrode for electrodeposition.•Platinum nanocones were electrodeposited into the pores of the membrane.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.surfcoat.2018.05.057</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-6574-3011</orcidid></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | Argon ion implantation Carbonization Cathodes Electrical resistivity Fluence Graphitic structure Heat conductivity Ion implantation Ion-track membrane Irradiation Membranes Platinum Polyimide Pt nanocones Surface layers |
| title | Preparation of conductive layer on polyimide ion-track membrane by Ar ion implantation |
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