Raman Scattering in Nanocomposites Based on Synthetic Opal and Nanocrystalline Bi2TeO5

— This paper presents a systematic Raman scattering study of novel nanostructured materials based on synthetic opal and Bi 2 TeO 5 nanocrystals, which offer high photorefractive sensitivity. Bismuth tellurite was introduced into opal pores in a molten state. The crystal structure of the material in...

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Veröffentlicht in:Inorganic materials 2018-12, Vol.54 (12), p.1250-1255
Hauptverfasser: Moiseyenko, V. N., Brynza, N. P., Abu Sal, B., Holze, R., Gorelik, V. S., Sverbil’, P. P.
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container_end_page 1255
container_issue 12
container_start_page 1250
container_title Inorganic materials
container_volume 54
creator Moiseyenko, V. N.
Brynza, N. P.
Abu Sal, B.
Holze, R.
Gorelik, V. S.
Sverbil’, P. P.
description — This paper presents a systematic Raman scattering study of novel nanostructured materials based on synthetic opal and Bi 2 TeO 5 nanocrystals, which offer high photorefractive sensitivity. Bismuth tellurite was introduced into opal pores in a molten state. The crystal structure of the material in the opal pores was determined by Raman spectroscopy. Comparison of the measured Raman spectra of the opal–Bi 2 TeO 5 nanocomposite and those of polycrystalline powders and single crystals made it possible to reveal a number of new bands and analyze their origin. The observed variation in the intensity of Raman bands from point to point on the sample surface can be interpreted as due to structural light focusing and excitation field localization at surface and volume defects of the photonic crystal structure of the material.
doi_str_mv 10.1134/S0020168518120117
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subjects Bismuth
Chemistry
Chemistry and Materials Science
Crystal defects
Crystal structure
Industrial Chemistry/Chemical Engineering
Inorganic Chemistry
Materials Science
Nanocomposites
Nanocrystals
Nanostructured materials
Photonic crystals
Photorefractivity
Raman spectra
Raman spectroscopy
Single crystals
Spectrum analysis
Tellurium dioxide
title Raman Scattering in Nanocomposites Based on Synthetic Opal and Nanocrystalline Bi2TeO5
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