Sulfite‐Induced N‐Alkylation and Thioketonization of Azoles Enable Access to Diverse Azole Thiones

The direct modification of azole skeletons enables access to drug‐like molecules. The development of a highly compatible reaction platform for this pursuit still remains challenging. Herein, we report the use of sulfite as the single electron transfer (SET) reducing agent for the activation of funct...

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Veröffentlicht in:	Advanced synthesis & catalysis 2018-12, Vol.360 (24), p.4795-4806
Hauptverfasser:	Deng, Jian‐Chao, Chen, Jia‐Hao, Zhang, Jun‐Rong, Lu, Ting‐Ting, Tang, Ri‐Yuan
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylation azoles Electron transfer Functional groups Heterocyclic compounds nitrogen heterocycles Reducing agents Selenium single electron transfer sulfite sulfur Transition metals
Online-Zugang:	Volltext
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