Synthesis of polyfluorenes by oxidative polymerization, their characterization and implementation in organic solar cells
Polyfluorene materials have demonstrated to be important components in the fabrication of organic solar cell devices, in both: the active and electron transport layers. The oxidative synthesis as well as optical and electrical properties of new polyfluorene copolymers containing 2,2′-(9,9-dioctyl-9...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2019-02, Vol.30 (3), p.2716-2725 |
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| creator | Espinosa-Roa, Arián Cruz-Carrillo, María de Jesús Ledesma-Juárez, Arelis Montoya del Angel, Alejandra Romero-Borja, Daniel Güizado-Rodríguez, Marisol Rodríguez, Mario Galindo, Rosario Maldonado, José Luis Barba, Victor |
| description | Polyfluorene materials have demonstrated to be important components in the fabrication of organic solar cell devices, in both: the active and electron transport layers. The oxidative synthesis as well as optical and electrical properties of new polyfluorene copolymers containing 2,2′-(9,9-dioctyl-9
H
-fluorene-2,7-diyl) bistiophene and 3-alkylthiophene, alkyl = hexyl (
PA1)
and octyl (
PA2
) or 3,4-ethylenedioxythiophene (EDOT) (
PM)
were investigated. Changes in the HOMO–LUMO energy gap promoted for the insertion of EDOT ring were studied in thick film by using cyclic-voltammetry measurements and compared with the optical properties analyzed by UV–Visible spectroscopy. DFT calculations were used to investigate the possible electronic density distribution and conformational parameter for repetition units into the polymeric structure. Finally, these polymer were preliminary evaluated as donor materials into organic solar cells with architecture ITO/PEDOT:PSS/co-polymer:PC
71
BM/Field’s metal. Photovoltaic devices showed a very acceptable open circuit voltage (V
oc
) value, up to 0.92 V. |
| doi_str_mv | 10.1007/s10854-018-0547-2 |
| format | Article |
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H
-fluorene-2,7-diyl) bistiophene and 3-alkylthiophene, alkyl = hexyl (
PA1)
and octyl (
PA2
) or 3,4-ethylenedioxythiophene (EDOT) (
PM)
were investigated. Changes in the HOMO–LUMO energy gap promoted for the insertion of EDOT ring were studied in thick film by using cyclic-voltammetry measurements and compared with the optical properties analyzed by UV–Visible spectroscopy. DFT calculations were used to investigate the possible electronic density distribution and conformational parameter for repetition units into the polymeric structure. Finally, these polymer were preliminary evaluated as donor materials into organic solar cells with architecture ITO/PEDOT:PSS/co-polymer:PC
71
BM/Field’s metal. Photovoltaic devices showed a very acceptable open circuit voltage (V
oc
) value, up to 0.92 V.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-018-0547-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemical synthesis ; Chemistry and Materials Science ; Copolymers ; Density distribution ; Donor materials ; Electrical properties ; Electron transport ; Energy gap ; Materials Science ; Molecular orbitals ; Open circuit voltage ; Optical and Electronic Materials ; Optical properties ; Organic chemistry ; Photovoltaic cells ; Polymers ; Solar cells</subject><ispartof>Journal of materials science. Materials in electronics, 2019-02, Vol.30 (3), p.2716-2725</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>Journal of Materials Science: Materials in Electronics is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-b1efb90effe44e63e709be9183cb549495127f2e54db6c9b5c011697abde98e33</citedby><cites>FETCH-LOGICAL-c355t-b1efb90effe44e63e709be9183cb549495127f2e54db6c9b5c011697abde98e33</cites><orcidid>0000-0001-5403-4968</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-018-0547-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-018-0547-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27928,27929,41492,42561,51323</link.rule.ids></links><search><creatorcontrib>Espinosa-Roa, Arián</creatorcontrib><creatorcontrib>Cruz-Carrillo, María de Jesús</creatorcontrib><creatorcontrib>Ledesma-Juárez, Arelis</creatorcontrib><creatorcontrib>Montoya del Angel, Alejandra</creatorcontrib><creatorcontrib>Romero-Borja, Daniel</creatorcontrib><creatorcontrib>Güizado-Rodríguez, Marisol</creatorcontrib><creatorcontrib>Rodríguez, Mario</creatorcontrib><creatorcontrib>Galindo, Rosario</creatorcontrib><creatorcontrib>Maldonado, José Luis</creatorcontrib><creatorcontrib>Barba, Victor</creatorcontrib><title>Synthesis of polyfluorenes by oxidative polymerization, their characterization and implementation in organic solar cells</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Polyfluorene materials have demonstrated to be important components in the fabrication of organic solar cell devices, in both: the active and electron transport layers. The oxidative synthesis as well as optical and electrical properties of new polyfluorene copolymers containing 2,2′-(9,9-dioctyl-9
H
-fluorene-2,7-diyl) bistiophene and 3-alkylthiophene, alkyl = hexyl (
PA1)
and octyl (
PA2
) or 3,4-ethylenedioxythiophene (EDOT) (
PM)
were investigated. Changes in the HOMO–LUMO energy gap promoted for the insertion of EDOT ring were studied in thick film by using cyclic-voltammetry measurements and compared with the optical properties analyzed by UV–Visible spectroscopy. DFT calculations were used to investigate the possible electronic density distribution and conformational parameter for repetition units into the polymeric structure. Finally, these polymer were preliminary evaluated as donor materials into organic solar cells with architecture ITO/PEDOT:PSS/co-polymer:PC
71
BM/Field’s metal. Photovoltaic devices showed a very acceptable open circuit voltage (V
oc
) value, up to 0.92 V.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Copolymers</subject><subject>Density distribution</subject><subject>Donor materials</subject><subject>Electrical properties</subject><subject>Electron transport</subject><subject>Energy gap</subject><subject>Materials Science</subject><subject>Molecular orbitals</subject><subject>Open circuit voltage</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Organic chemistry</subject><subject>Photovoltaic cells</subject><subject>Polymers</subject><subject>Solar cells</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kE9LxDAQxYMouK5-AG8Br0aTNGmboyz-gwUPKngLaTvdzdImNenK1k9v14qePA3z5v3ewEPonNErRml2HRnNpSCU5YRKkRF-gGZMZgkROX87RDOqZEaE5PwYncS4oZSmIslnaPc8uH4N0Ubsa9z5ZqibrQ_gIOJiwH5nK9PbD_g-tRDs57h6d4lHyAZcrk0wZf-rY-MqbNuugRZcP0nWYR9WxtkSR9-YEYKmiafoqDZNhLOfOUevd7cviweyfLp_XNwsSZlI2ZOCQV0oCnUNQkCaQEZVAYrlSVlIoYSSjGc1BymqIi1VIUvKWKoyU1SgckiSObqYcrvg37cQe73x2-DGl5ozmaZ5luZsdLHJVQYfY4Bad8G2JgyaUb0vWE8F67FgvS9Y85HhExNHr1tB-Ev-H_oC6ZGBrg</recordid><startdate>20190201</startdate><enddate>20190201</enddate><creator>Espinosa-Roa, Arián</creator><creator>Cruz-Carrillo, María de Jesús</creator><creator>Ledesma-Juárez, Arelis</creator><creator>Montoya del Angel, Alejandra</creator><creator>Romero-Borja, Daniel</creator><creator>Güizado-Rodríguez, Marisol</creator><creator>Rodríguez, Mario</creator><creator>Galindo, Rosario</creator><creator>Maldonado, José Luis</creator><creator>Barba, Victor</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>S0W</scope><orcidid>https://orcid.org/0000-0001-5403-4968</orcidid></search><sort><creationdate>20190201</creationdate><title>Synthesis of polyfluorenes by oxidative polymerization, their characterization and implementation in organic solar cells</title><author>Espinosa-Roa, Arián ; Cruz-Carrillo, María de Jesús ; Ledesma-Juárez, Arelis ; Montoya del Angel, Alejandra ; Romero-Borja, Daniel ; Güizado-Rodríguez, Marisol ; Rodríguez, Mario ; Galindo, Rosario ; Maldonado, José Luis ; Barba, Victor</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-b1efb90effe44e63e709be9183cb549495127f2e54db6c9b5c011697abde98e33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Copolymers</topic><topic>Density distribution</topic><topic>Donor materials</topic><topic>Electrical properties</topic><topic>Electron transport</topic><topic>Energy gap</topic><topic>Materials Science</topic><topic>Molecular orbitals</topic><topic>Open circuit voltage</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Organic chemistry</topic><topic>Photovoltaic cells</topic><topic>Polymers</topic><topic>Solar cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Espinosa-Roa, Arián</creatorcontrib><creatorcontrib>Cruz-Carrillo, María de Jesús</creatorcontrib><creatorcontrib>Ledesma-Juárez, Arelis</creatorcontrib><creatorcontrib>Montoya del Angel, Alejandra</creatorcontrib><creatorcontrib>Romero-Borja, Daniel</creatorcontrib><creatorcontrib>Güizado-Rodríguez, Marisol</creatorcontrib><creatorcontrib>Rodríguez, Mario</creatorcontrib><creatorcontrib>Galindo, Rosario</creatorcontrib><creatorcontrib>Maldonado, José Luis</creatorcontrib><creatorcontrib>Barba, Victor</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. 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Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2019-02-01</date><risdate>2019</risdate><volume>30</volume><issue>3</issue><spage>2716</spage><epage>2725</epage><pages>2716-2725</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Polyfluorene materials have demonstrated to be important components in the fabrication of organic solar cell devices, in both: the active and electron transport layers. The oxidative synthesis as well as optical and electrical properties of new polyfluorene copolymers containing 2,2′-(9,9-dioctyl-9
H
-fluorene-2,7-diyl) bistiophene and 3-alkylthiophene, alkyl = hexyl (
PA1)
and octyl (
PA2
) or 3,4-ethylenedioxythiophene (EDOT) (
PM)
were investigated. Changes in the HOMO–LUMO energy gap promoted for the insertion of EDOT ring were studied in thick film by using cyclic-voltammetry measurements and compared with the optical properties analyzed by UV–Visible spectroscopy. DFT calculations were used to investigate the possible electronic density distribution and conformational parameter for repetition units into the polymeric structure. Finally, these polymer were preliminary evaluated as donor materials into organic solar cells with architecture ITO/PEDOT:PSS/co-polymer:PC
71
BM/Field’s metal. Photovoltaic devices showed a very acceptable open circuit voltage (V
oc
) value, up to 0.92 V.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-018-0547-2</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-5403-4968</orcidid></addata></record> |
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| identifier | ISSN: 0957-4522 |
| ispartof | Journal of materials science. Materials in electronics, 2019-02, Vol.30 (3), p.2716-2725 |
| issn | 0957-4522 1573-482X |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Characterization and Evaluation of Materials Chemical synthesis Chemistry and Materials Science Copolymers Density distribution Donor materials Electrical properties Electron transport Energy gap Materials Science Molecular orbitals Open circuit voltage Optical and Electronic Materials Optical properties Organic chemistry Photovoltaic cells Polymers Solar cells |
| title | Synthesis of polyfluorenes by oxidative polymerization, their characterization and implementation in organic solar cells |
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