Synthesis of Deuterated or Tritiated Glycine and Its Methyl Ester
Heating glycine (Gly) and methyl glycinate (GlyOCH 3 ) supported on 5% Pd/C or 5% Pt/C in a deuterium or tritium gas atmosphere gave the isotope-labeled products. The experiments were carried out at 180°C for 10 min. The deuterium atom inclusion under these conditions averaged up to 1.8 atoms per mo...
Gespeichert in:
| Veröffentlicht in: | Doklady. Chemistry 2018-12, Vol.483 (1), p.266-267 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 267 |
|---|---|
| container_issue | 1 |
| container_start_page | 266 |
| container_title | Doklady. Chemistry |
| container_volume | 483 |
| creator | Shevchenko, V. P. Andreeva, L. A. Nagaev, I. Yu Myasoedov, N. F. |
| description | Heating glycine (Gly) and methyl glycinate (GlyOCH
3
) supported on 5% Pd/C or 5% Pt/C in a deuterium or tritium gas atmosphere gave the isotope-labeled products. The experiments were carried out at 180°C for 10 min. The deuterium atom inclusion under these conditions averaged up to 1.8 atoms per molecule for Gly and up to 1.0 atom per molecule for GlyOCH
3
. The reaction with tritium gas gave labeled products with a specific radioactivity of 27–31 Ci/mmol for Gly and 18 Ci/mmol for GlyOCH
3
. |
| doi_str_mv | 10.1134/S0012500818110071 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2155975351</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2155975351</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-8eec30fcadf193d98f3c32677f4eb2f383125aa1ce93c67b19c6c7b60fc928593</originalsourceid><addsrcrecordid>eNp1kDFPwzAQhS0EEqHwA9gsMQd8dhPbY1VKqVTE0DJHjnOmqUpSbHfIv8elSAyI6XR633t3eoTcArsHEOOHFWPAC8YUKADGJJyRDEqmcpHkc5Id5fyoX5KrELaMMS2FyshkNXRxg6ENtHf0EQ8RvYnY0N7TtW9j-73Md4NtO6Sma-giBvqCcTPs6Cwk-ppcOLMLePMzR-TtabaePufL1_liOlnmlpcq5grRCuasaRxo0WjlhBW8lNKNseZOKJH-NwYsamFLWYO2pZV1mSyaq0KLEbk75e59_3nAEKttf_BdOllxKAotC1FAouBEWd-H4NFVe99-GD9UwKpjU9WfppKHnzwhsd07-t_k_01foHNpHw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2155975351</pqid></control><display><type>article</type><title>Synthesis of Deuterated or Tritiated Glycine and Its Methyl Ester</title><source>Springer Online Journals Complete</source><creator>Shevchenko, V. P. ; Andreeva, L. A. ; Nagaev, I. Yu ; Myasoedov, N. F.</creator><creatorcontrib>Shevchenko, V. P. ; Andreeva, L. A. ; Nagaev, I. Yu ; Myasoedov, N. F.</creatorcontrib><description>Heating glycine (Gly) and methyl glycinate (GlyOCH
3
) supported on 5% Pd/C or 5% Pt/C in a deuterium or tritium gas atmosphere gave the isotope-labeled products. The experiments were carried out at 180°C for 10 min. The deuterium atom inclusion under these conditions averaged up to 1.8 atoms per molecule for Gly and up to 1.0 atom per molecule for GlyOCH
3
. The reaction with tritium gas gave labeled products with a specific radioactivity of 27–31 Ci/mmol for Gly and 18 Ci/mmol for GlyOCH
3
.</description><identifier>ISSN: 0012-5008</identifier><identifier>EISSN: 1608-3113</identifier><identifier>DOI: 10.1134/S0012500818110071</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Deuteration ; Deuterium ; Glycine ; Industrial Chemistry/Chemical Engineering ; Palladium ; Platinum ; Radioactivity ; Tritium</subject><ispartof>Doklady. Chemistry, 2018-12, Vol.483 (1), p.266-267</ispartof><rights>Pleiades Publishing, Inc. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0012500818110071$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0012500818110071$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Shevchenko, V. P.</creatorcontrib><creatorcontrib>Andreeva, L. A.</creatorcontrib><creatorcontrib>Nagaev, I. Yu</creatorcontrib><creatorcontrib>Myasoedov, N. F.</creatorcontrib><title>Synthesis of Deuterated or Tritiated Glycine and Its Methyl Ester</title><title>Doklady. Chemistry</title><addtitle>Dokl Chem</addtitle><description>Heating glycine (Gly) and methyl glycinate (GlyOCH
3
) supported on 5% Pd/C or 5% Pt/C in a deuterium or tritium gas atmosphere gave the isotope-labeled products. The experiments were carried out at 180°C for 10 min. The deuterium atom inclusion under these conditions averaged up to 1.8 atoms per molecule for Gly and up to 1.0 atom per molecule for GlyOCH
3
. The reaction with tritium gas gave labeled products with a specific radioactivity of 27–31 Ci/mmol for Gly and 18 Ci/mmol for GlyOCH
3
.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Deuteration</subject><subject>Deuterium</subject><subject>Glycine</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Palladium</subject><subject>Platinum</subject><subject>Radioactivity</subject><subject>Tritium</subject><issn>0012-5008</issn><issn>1608-3113</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kDFPwzAQhS0EEqHwA9gsMQd8dhPbY1VKqVTE0DJHjnOmqUpSbHfIv8elSAyI6XR633t3eoTcArsHEOOHFWPAC8YUKADGJJyRDEqmcpHkc5Id5fyoX5KrELaMMS2FyshkNXRxg6ENtHf0EQ8RvYnY0N7TtW9j-73Md4NtO6Sma-giBvqCcTPs6Cwk-ppcOLMLePMzR-TtabaePufL1_liOlnmlpcq5grRCuasaRxo0WjlhBW8lNKNseZOKJH-NwYsamFLWYO2pZV1mSyaq0KLEbk75e59_3nAEKttf_BdOllxKAotC1FAouBEWd-H4NFVe99-GD9UwKpjU9WfppKHnzwhsd07-t_k_01foHNpHw</recordid><startdate>20181201</startdate><enddate>20181201</enddate><creator>Shevchenko, V. P.</creator><creator>Andreeva, L. A.</creator><creator>Nagaev, I. Yu</creator><creator>Myasoedov, N. F.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20181201</creationdate><title>Synthesis of Deuterated or Tritiated Glycine and Its Methyl Ester</title><author>Shevchenko, V. P. ; Andreeva, L. A. ; Nagaev, I. Yu ; Myasoedov, N. F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-8eec30fcadf193d98f3c32677f4eb2f383125aa1ce93c67b19c6c7b60fc928593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Deuteration</topic><topic>Deuterium</topic><topic>Glycine</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Palladium</topic><topic>Platinum</topic><topic>Radioactivity</topic><topic>Tritium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shevchenko, V. P.</creatorcontrib><creatorcontrib>Andreeva, L. A.</creatorcontrib><creatorcontrib>Nagaev, I. Yu</creatorcontrib><creatorcontrib>Myasoedov, N. F.</creatorcontrib><collection>CrossRef</collection><jtitle>Doklady. Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shevchenko, V. P.</au><au>Andreeva, L. A.</au><au>Nagaev, I. Yu</au><au>Myasoedov, N. F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Deuterated or Tritiated Glycine and Its Methyl Ester</atitle><jtitle>Doklady. Chemistry</jtitle><stitle>Dokl Chem</stitle><date>2018-12-01</date><risdate>2018</risdate><volume>483</volume><issue>1</issue><spage>266</spage><epage>267</epage><pages>266-267</pages><issn>0012-5008</issn><eissn>1608-3113</eissn><abstract>Heating glycine (Gly) and methyl glycinate (GlyOCH
3
) supported on 5% Pd/C or 5% Pt/C in a deuterium or tritium gas atmosphere gave the isotope-labeled products. The experiments were carried out at 180°C for 10 min. The deuterium atom inclusion under these conditions averaged up to 1.8 atoms per molecule for Gly and up to 1.0 atom per molecule for GlyOCH
3
. The reaction with tritium gas gave labeled products with a specific radioactivity of 27–31 Ci/mmol for Gly and 18 Ci/mmol for GlyOCH
3
.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0012500818110071</doi><tpages>2</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0012-5008 |
| ispartof | Doklady. Chemistry, 2018-12, Vol.483 (1), p.266-267 |
| issn | 0012-5008 1608-3113 |
| language | eng |
| recordid | cdi_proquest_journals_2155975351 |
| source | Springer Online Journals Complete |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Deuteration Deuterium Glycine Industrial Chemistry/Chemical Engineering Palladium Platinum Radioactivity Tritium |
| title | Synthesis of Deuterated or Tritiated Glycine and Its Methyl Ester |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T19%3A02%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20Deuterated%20or%20Tritiated%20Glycine%20and%20Its%20Methyl%20Ester&rft.jtitle=Doklady.%20Chemistry&rft.au=Shevchenko,%20V.%20P.&rft.date=2018-12-01&rft.volume=483&rft.issue=1&rft.spage=266&rft.epage=267&rft.pages=266-267&rft.issn=0012-5008&rft.eissn=1608-3113&rft_id=info:doi/10.1134/S0012500818110071&rft_dat=%3Cproquest_cross%3E2155975351%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2155975351&rft_id=info:pmid/&rfr_iscdi=true |