Basic and Coordination Properties of Tetraphenylporphine Derivatives
Basic and coordination properties of 5,10,15,20-tetrakis(3,5-dibromophenyl)porphine and 5,10,15,20-tetrakis(4-methoxy-3-bromophenyl)porphine in acetonitrile have been investigated by means of spectrophotometry. The optimization of the geometry parameters of polysubstituted porphyrins has been perfor...
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Veröffentlicht in: | Russian journal of general chemistry 2018-10, Vol.88 (10), p.2103-2107 |
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container_title | Russian journal of general chemistry |
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creator | Ivanova, Yu. B. Plotnikova, A. O. Semeikin, A. S. Pukhovskaya, S. G. Mamardashvili, N. Zh |
description | Basic and coordination properties of 5,10,15,20-tetrakis(3,5-dibromophenyl)porphine and 5,10,15,20-tetrakis(4-methoxy-3-bromophenyl)porphine in acetonitrile have been investigated by means of spectrophotometry. The optimization of the geometry parameters of polysubstituted porphyrins has been performed using quantum-chemical method (РМ3). The relationship between geometric structure of the studied porphyrins and their coordination, basic, and spectral properties is discussed. |
doi_str_mv | 10.1134/S1070363218100122 |
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The relationship between geometric structure of the studied porphyrins and their coordination, basic, and spectral properties is discussed.</description><subject>Acetonitrile</subject><subject>Analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Organic chemistry</subject><subject>Porphyrins</subject><subject>Properties (attributes)</subject><subject>Quantum chemistry</subject><subject>Spectrophotometry</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kF1LwzAUhoMoOKc_wLuC153nJG3TXM7NLxgoOK9LmqZbxpbUpBvs35tRwQuRXCTkfZ5zDoeQW4QJIsvuPxA4sIJRLBEAKT0jIyygTBnL4Ty-Y5ye8ktyFcImIgAFHZH5gwxGJdI2ycw53xgre-Ns8u5dp31vdEhcmyx172W31va47Zzv1sbqZK69OUT4oMM1uWjlNuibn3tMPp8el7OXdPH2_DqbLlLFgPepqimrFdI2tq5RMAEqk4pTIQRXmcga1gIvs7Iu5SnOGM9FQZXigqmCUsbG5G6o23n3tdehrzZu721sWVGMNHABGKnJQK3kVlfGti4Or-Jp9M4oZ3Vr4v-U0yIXFDCPAg6C8i4Er9uq82Yn_bFCqE7brf5sNzp0cEJk7Ur731H-l74BzYl5mw</recordid><startdate>20181001</startdate><enddate>20181001</enddate><creator>Ivanova, Yu. 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Zh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Basic and Coordination Properties of Tetraphenylporphine Derivatives</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2018-10-01</date><risdate>2018</risdate><volume>88</volume><issue>10</issue><spage>2103</spage><epage>2107</epage><pages>2103-2107</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>Basic and coordination properties of 5,10,15,20-tetrakis(3,5-dibromophenyl)porphine and 5,10,15,20-tetrakis(4-methoxy-3-bromophenyl)porphine in acetonitrile have been investigated by means of spectrophotometry. The optimization of the geometry parameters of polysubstituted porphyrins has been performed using quantum-chemical method (РМ3). The relationship between geometric structure of the studied porphyrins and their coordination, basic, and spectral properties is discussed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363218100122</doi><tpages>5</tpages></addata></record> |
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subjects | Acetonitrile Analysis Chemistry Chemistry and Materials Science Chemistry/Food Science Organic chemistry Porphyrins Properties (attributes) Quantum chemistry Spectrophotometry |
title | Basic and Coordination Properties of Tetraphenylporphine Derivatives |
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