Superelectrophilic activation in superacid HF/SbF^sub 5^: Expanding molecular diversity in nitrogen-containing compounds series by fluorination

In superacid, such as HF/SbF5, functionalized organic molecules can be (poly)protonated to deliver cationic species which can react with very poor nucleophiles. This superelectrophilic activation can be applied to the development of unprecedented organic reactions. Through the use of ammonium-carben...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of fluorine chemistry 2018-10, Vol.214, p.68
Hauptverfasser:	Michelet, Bastien, Carreyre, Hélène, Lecornué, Frédéric, Mingot, Agnès, Thibaudeau, Sébastien
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Activation Ammonium Bioactive compounds Biotechnology Chemical reactions Fluorination Genomes Nitrogen Nucleophiles Organic chemistry Pharmaceuticals
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!