Chlorocyanoborates: Synthesis, Spectroscopic and Structural Characterization, and Properties of Ionic Liquids

A set of first mixed chlorocyanoborates was synthesized and fully characterized by elemental analysis, NMR and vibrational spectroscopy. Two different synthetic approaches were developed: Exchange of chlorine against CN in case of [BCl3(CN)]– and reaction of [BHx(CN)4–x]– with Cl2 or tBuOCl for the...

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Veröffentlicht in:	Zeitschrift für anorganische und allgemeine Chemie (1950) 2018-11, Vol.644 (21), p.1285-1292
Hauptverfasser:	Bischoff, Lisa A., Sprenger, Jan A. P., Hennig, Philipp T., Ignat'ev, Nikolai V., Finze, Maik
Format:	Artikel
Sprache:	eng
Schlagworte:	Boron chlorides Chlorination Chlorine Chloroborates Crystal structure Cyanoborates Ionic liquids Ions NMR Nuclear magnetic resonance Solvents Structural analysis Structure elucidation X ray spectra X-ray diffraction
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