Solvent-free thiophene-based electrolytes: synthesis of new liquid-crystalline ionic conductors for batteries: part I
New liquid crystalline thiophene esters, thiophene-3-yl 3,4,5-tris( n -dodecan-1-yloxy)benzoate (ThBz1) and thiophene-3-yl 3,4,5-tris[4-( n -dodecan-1-yloxy)benzyloxy]benzoate (ThBz2), were synthesized for use in lithium-ion batteries as safe, new solvent-free ionic conductors. Both compounds were s...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2018-11, Vol.47 (44), p.15714-15724 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Bogdanowicz, Krzysztof Artur Gancarz, Pawel Filapek, Michal Pociecha, Damian Marzec, Monika Chojnacka, Ida Iwan, Agnieszka |
| description | New liquid crystalline thiophene esters, thiophene-3-yl 3,4,5-tris(
n
-dodecan-1-yloxy)benzoate (ThBz1) and thiophene-3-yl 3,4,5-tris[4-(
n
-dodecan-1-yloxy)benzyloxy]benzoate (ThBz2), were synthesized for use in lithium-ion batteries as safe, new solvent-free ionic conductors. Both compounds were synthesized in multi-step reactions and were characterized
via
1
H,
13
C NMR and FT-IR spectroscopy, confirming the formation of the desired products. ThBz1 and ThBz2 showed good thermal stability and liquid crystalline behaviour. Electrochemical tests demonstrated a wide electrochemical window of 4 V for both tested ThBz compounds. Moreover, preliminary battery tests for new electrolytes in the LiCoO
2
/Li
4
Ti
5
O
12
system confirmed their applicability in lithium-ion batteries.
We report the synthesis of new liquid crystalline thiophene esters, ThBz1 and ThBz2, for use in lithium-ion batteries as new, safe, solvent-free ionic conductors. |
| doi_str_mv | 10.1039/c8dt02968g |
| format | Article |
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n
-dodecan-1-yloxy)benzoate (ThBz1) and thiophene-3-yl 3,4,5-tris[4-(
n
-dodecan-1-yloxy)benzyloxy]benzoate (ThBz2), were synthesized for use in lithium-ion batteries as safe, new solvent-free ionic conductors. Both compounds were synthesized in multi-step reactions and were characterized
via
1
H,
13
C NMR and FT-IR spectroscopy, confirming the formation of the desired products. ThBz1 and ThBz2 showed good thermal stability and liquid crystalline behaviour. Electrochemical tests demonstrated a wide electrochemical window of 4 V for both tested ThBz compounds. Moreover, preliminary battery tests for new electrolytes in the LiCoO
2
/Li
4
Ti
5
O
12
system confirmed their applicability in lithium-ion batteries.
We report the synthesis of new liquid crystalline thiophene esters, ThBz1 and ThBz2, for use in lithium-ion batteries as new, safe, solvent-free ionic conductors.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c8dt02968g</identifier><identifier>PMID: 30334553</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chemical synthesis ; Conductors ; Crystal structure ; Crystallinity ; Electrolytes ; Esters ; Fourier transforms ; Infrared spectroscopy ; Liquid crystals ; Lithium ; Lithium-ion batteries ; NMR ; Nuclear magnetic resonance ; Rechargeable batteries ; Solvents ; Thermal stability</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2018-11, Vol.47 (44), p.15714-15724</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-78e2cba873a57540a618f4e6a36f8cd688808a866af8f988f533e79378b7d1cc3</citedby><cites>FETCH-LOGICAL-c337t-78e2cba873a57540a618f4e6a36f8cd688808a866af8f988f533e79378b7d1cc3</cites><orcidid>0000-0001-8526-626X ; 0000-0002-4854-9567 ; 0000-0003-4617-1174 ; 0000-0003-2564-2934 ; 0000-0001-7734-3181 ; 0000-0002-7705-6577 ; 0000-0001-5958-2357</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30334553$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bogdanowicz, Krzysztof Artur</creatorcontrib><creatorcontrib>Gancarz, Pawel</creatorcontrib><creatorcontrib>Filapek, Michal</creatorcontrib><creatorcontrib>Pociecha, Damian</creatorcontrib><creatorcontrib>Marzec, Monika</creatorcontrib><creatorcontrib>Chojnacka, Ida</creatorcontrib><creatorcontrib>Iwan, Agnieszka</creatorcontrib><title>Solvent-free thiophene-based electrolytes: synthesis of new liquid-crystalline ionic conductors for batteries: part I</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>New liquid crystalline thiophene esters, thiophene-3-yl 3,4,5-tris(
n
-dodecan-1-yloxy)benzoate (ThBz1) and thiophene-3-yl 3,4,5-tris[4-(
n
-dodecan-1-yloxy)benzyloxy]benzoate (ThBz2), were synthesized for use in lithium-ion batteries as safe, new solvent-free ionic conductors. Both compounds were synthesized in multi-step reactions and were characterized
via
1
H,
13
C NMR and FT-IR spectroscopy, confirming the formation of the desired products. ThBz1 and ThBz2 showed good thermal stability and liquid crystalline behaviour. Electrochemical tests demonstrated a wide electrochemical window of 4 V for both tested ThBz compounds. Moreover, preliminary battery tests for new electrolytes in the LiCoO
2
/Li
4
Ti
5
O
12
system confirmed their applicability in lithium-ion batteries.
We report the synthesis of new liquid crystalline thiophene esters, ThBz1 and ThBz2, for use in lithium-ion batteries as new, safe, solvent-free ionic conductors.</description><subject>Chemical synthesis</subject><subject>Conductors</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Electrolytes</subject><subject>Esters</subject><subject>Fourier transforms</subject><subject>Infrared spectroscopy</subject><subject>Liquid crystals</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Rechargeable batteries</subject><subject>Solvents</subject><subject>Thermal stability</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpd0c9LHDEUB_BQlPqjvfSuBLyUwthM3kyS6a1sWysIHmrPQybz4kayyZpklP3vHV27Qk95kA9fHu9LyKeandcMuq9GjYXxTqjbd-SwbqSsOg7N3m7m4oAc5XzHGOes5e_JATCApm3hkEx_on_AUCqbEGlZurheYsBq0BlHih5NSdFvCuZvNG9CWWJ2mUZLAz5S7-4nN1YmbXLR3ruA1MXgDDUxjJMpMWVqY6KDLgWTe85Y61To5Qeyb7XP-PH1PSZ_f_28Wfyurq4vLhffryoDIEslFXIzaCVBt7JtmBa1sg0KDcIqMwqlFFNaCaGtsp1StgVA2YFUgxxrY-CYfN7mrlO8nzCXfuWyQe91wDjlntect4oL0cz07D96F6cU5u1mBRxAgKxn9WWrTIo5J7T9OrmVTpu-Zv1zGf1C_bh5KeNixqevkdOwwnFH_11_BidbkLLZ_b61CU_2Fo-w</recordid><startdate>20181113</startdate><enddate>20181113</enddate><creator>Bogdanowicz, Krzysztof Artur</creator><creator>Gancarz, Pawel</creator><creator>Filapek, Michal</creator><creator>Pociecha, Damian</creator><creator>Marzec, Monika</creator><creator>Chojnacka, Ida</creator><creator>Iwan, Agnieszka</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8526-626X</orcidid><orcidid>https://orcid.org/0000-0002-4854-9567</orcidid><orcidid>https://orcid.org/0000-0003-4617-1174</orcidid><orcidid>https://orcid.org/0000-0003-2564-2934</orcidid><orcidid>https://orcid.org/0000-0001-7734-3181</orcidid><orcidid>https://orcid.org/0000-0002-7705-6577</orcidid><orcidid>https://orcid.org/0000-0001-5958-2357</orcidid></search><sort><creationdate>20181113</creationdate><title>Solvent-free thiophene-based electrolytes: synthesis of new liquid-crystalline ionic conductors for batteries: part I</title><author>Bogdanowicz, Krzysztof Artur ; Gancarz, Pawel ; Filapek, Michal ; Pociecha, Damian ; Marzec, Monika ; Chojnacka, Ida ; Iwan, Agnieszka</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-78e2cba873a57540a618f4e6a36f8cd688808a866af8f988f533e79378b7d1cc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemical synthesis</topic><topic>Conductors</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Electrolytes</topic><topic>Esters</topic><topic>Fourier transforms</topic><topic>Infrared spectroscopy</topic><topic>Liquid crystals</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Rechargeable batteries</topic><topic>Solvents</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bogdanowicz, Krzysztof Artur</creatorcontrib><creatorcontrib>Gancarz, Pawel</creatorcontrib><creatorcontrib>Filapek, Michal</creatorcontrib><creatorcontrib>Pociecha, Damian</creatorcontrib><creatorcontrib>Marzec, Monika</creatorcontrib><creatorcontrib>Chojnacka, Ida</creatorcontrib><creatorcontrib>Iwan, Agnieszka</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bogdanowicz, Krzysztof Artur</au><au>Gancarz, Pawel</au><au>Filapek, Michal</au><au>Pociecha, Damian</au><au>Marzec, Monika</au><au>Chojnacka, Ida</au><au>Iwan, Agnieszka</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvent-free thiophene-based electrolytes: synthesis of new liquid-crystalline ionic conductors for batteries: part I</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2018-11-13</date><risdate>2018</risdate><volume>47</volume><issue>44</issue><spage>15714</spage><epage>15724</epage><pages>15714-15724</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>New liquid crystalline thiophene esters, thiophene-3-yl 3,4,5-tris(
n
-dodecan-1-yloxy)benzoate (ThBz1) and thiophene-3-yl 3,4,5-tris[4-(
n
-dodecan-1-yloxy)benzyloxy]benzoate (ThBz2), were synthesized for use in lithium-ion batteries as safe, new solvent-free ionic conductors. Both compounds were synthesized in multi-step reactions and were characterized
via
1
H,
13
C NMR and FT-IR spectroscopy, confirming the formation of the desired products. ThBz1 and ThBz2 showed good thermal stability and liquid crystalline behaviour. Electrochemical tests demonstrated a wide electrochemical window of 4 V for both tested ThBz compounds. Moreover, preliminary battery tests for new electrolytes in the LiCoO
2
/Li
4
Ti
5
O
12
system confirmed their applicability in lithium-ion batteries.
We report the synthesis of new liquid crystalline thiophene esters, ThBz1 and ThBz2, for use in lithium-ion batteries as new, safe, solvent-free ionic conductors.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30334553</pmid><doi>10.1039/c8dt02968g</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-8526-626X</orcidid><orcidid>https://orcid.org/0000-0002-4854-9567</orcidid><orcidid>https://orcid.org/0000-0003-4617-1174</orcidid><orcidid>https://orcid.org/0000-0003-2564-2934</orcidid><orcidid>https://orcid.org/0000-0001-7734-3181</orcidid><orcidid>https://orcid.org/0000-0002-7705-6577</orcidid><orcidid>https://orcid.org/0000-0001-5958-2357</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2018-11, Vol.47 (44), p.15714-15724 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical synthesis Conductors Crystal structure Crystallinity Electrolytes Esters Fourier transforms Infrared spectroscopy Liquid crystals Lithium Lithium-ion batteries NMR Nuclear magnetic resonance Rechargeable batteries Solvents Thermal stability |
| title | Solvent-free thiophene-based electrolytes: synthesis of new liquid-crystalline ionic conductors for batteries: part I |
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