Catalytic cracking of polyethylene plastic waste using synthesised zeolite Y from Nigerian kaolin deposit

The increasing rate of accumulation of plastic waste (PW) is quite disturbing to the world, particularly in developing nations due to its non-biodegradable nature and inadequate waste management practices. The need to properly manage this waste and utilize the potential and chemical energy value tha...

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Veröffentlicht in:Applied petrochemical research 2018-12, Vol.8 (4), p.211-217
Hauptverfasser: Ajibola, Abosede A., Omoleye, James A., Efeovbokhan, Vincent E.
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Omoleye, James A.
Efeovbokhan, Vincent E.
description The increasing rate of accumulation of plastic waste (PW) is quite disturbing to the world, particularly in developing nations due to its non-biodegradable nature and inadequate waste management practices. The need to properly manage this waste and utilize the potential and chemical energy value that can be derived from this waste justifies the encouragement and employment of newer and better recycling methods and technology of these wastes. Therefore, this has led us to explore the catalytic pyrolysis of plastic waste using zeolite Y synthesized from kaolin deposit in Covenant University, Sango Ota, Ogun state of Nigeria. A stainless steel packed bed reactor was used in the cracking of low-density polyethylene (LDPE) plastic wastes into liquid fuel components at a temperature of 300 ℃ using zeolite Y catalyst. The liquid fuel obtained from the catalytic pyrolysis was analyzed using GC–MS. Fifty compounds were identified, which revealed the presence of mostly alkenes and aromatics in the hydrocarbons range of C 8 –C 29 . This is made up of 56% of gasoline fractions range of C 6 –C 12 , 26% of diesel and kerosene fractions range C 13 –C 18 , and 10% of fuel oil range C 18 –C 23 , while 8% is residual fuel range greater than C 24 .
doi_str_mv 10.1007/s13203-018-0216-7
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The need to properly manage this waste and utilize the potential and chemical energy value that can be derived from this waste justifies the encouragement and employment of newer and better recycling methods and technology of these wastes. Therefore, this has led us to explore the catalytic pyrolysis of plastic waste using zeolite Y synthesized from kaolin deposit in Covenant University, Sango Ota, Ogun state of Nigeria. A stainless steel packed bed reactor was used in the cracking of low-density polyethylene (LDPE) plastic wastes into liquid fuel components at a temperature of 300 ℃ using zeolite Y catalyst. The liquid fuel obtained from the catalytic pyrolysis was analyzed using GC–MS. Fifty compounds were identified, which revealed the presence of mostly alkenes and aromatics in the hydrocarbons range of C 8 –C 29 . This is made up of 56% of gasoline fractions range of C 6 –C 12 , 26% of diesel and kerosene fractions range C 13 –C 18 , and 10% of fuel oil range C 18 –C 23 , while 8% is residual fuel range greater than C 24 .</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s13203-018-0216-7</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record>
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subjects Alkenes
Biodegradability
Biodegradation
Catalysis
Catalytic cracking
Chemical energy
Chemical synthesis
Chemistry
Chemistry and Materials Science
Clay
Developing countries
Diesel fuels
Energy management
Energy Systems
Energy value
Force and energy
Fuel oil
Fuel oils
Gasoline
Industrial Chemistry/Chemical Engineering
Kaolin
Kerosene
LDCs
Liquid fuels
Low density polyethylenes
Nanochemistry
Nanotechnology and Microengineering
Nigeria
Nuclear fuels
Organic chemistry
Original Article
Packed beds
Petroleum
Plastic debris
Polyethylene
Pyrolysis
Recycling (Waste, etc.)
Refining
Steel
Steel, Stainless
Waste management
Waste management industry
Zeolites
title Catalytic cracking of polyethylene plastic waste using synthesised zeolite Y from Nigerian kaolin deposit
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