Partition of Cd, Cu, Pb and Zn among mineral particles during their sorption in soils
Purpose Heterogeneity of soil mineral particles may lead to the misinterpretation of bulk sorption data on their role in metal sorption, which may be resolved through the direct observation of metal distribution among the soil particles after the sorption. Materials and methods Analytical transmissi...
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| Veröffentlicht in: | Journal of soils and sediments 2019-04, Vol.19 (4), p.1775-1787 |
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| container_title | Journal of soils and sediments |
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| creator | Sipos, Péter Tóth, Adrienn Kis, Viktória Kovács Balázs, Réka Kovács, Ivett Németh, Tibor |
| description | Purpose
Heterogeneity of soil mineral particles may lead to the misinterpretation of bulk sorption data on their role in metal sorption, which may be resolved through the direct observation of metal distribution among the soil particles after the sorption.
Materials and methods
Analytical transmission electron microscopy was used to study metal (Cd, Cu, Pb, Zn) sorption characteristics of clay minerals, Fe-oxyhydroxides and their natural assemblages in soils with contrasting pH under single element and competitive situations.
Results and discussion
Iron-oxyhydroxides sorbed higher metal amounts than clay mineral particles mostly, and the sorption capacity of the latter phases were more affected by competition. Iron-oxyhydroxide particles acted as effective metal sorbents in soils not only as individual particles but also as coatings on other mineral particles, and the structural Fe in clay minerals may also resulted in higher metal sorption in some cases. Besides the direct observation of metal sorption onto soil mineral particles, metal precipitates could be identified directly, and the role of organic surfaces in metal sorption could be inferred indirectly in certain cases.
Conclusions
Comparison of metal affinity sequences and their partition characteristics between the bulk soil and different mineral particles were found to be an effective tool to specify the most active mineral components in metal sorption at given soil and sorption condition. |
| doi_str_mv | 10.1007/s11368-018-2184-z |
| format | Article |
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Heterogeneity of soil mineral particles may lead to the misinterpretation of bulk sorption data on their role in metal sorption, which may be resolved through the direct observation of metal distribution among the soil particles after the sorption.
Materials and methods
Analytical transmission electron microscopy was used to study metal (Cd, Cu, Pb, Zn) sorption characteristics of clay minerals, Fe-oxyhydroxides and their natural assemblages in soils with contrasting pH under single element and competitive situations.
Results and discussion
Iron-oxyhydroxides sorbed higher metal amounts than clay mineral particles mostly, and the sorption capacity of the latter phases were more affected by competition. Iron-oxyhydroxide particles acted as effective metal sorbents in soils not only as individual particles but also as coatings on other mineral particles, and the structural Fe in clay minerals may also resulted in higher metal sorption in some cases. Besides the direct observation of metal sorption onto soil mineral particles, metal precipitates could be identified directly, and the role of organic surfaces in metal sorption could be inferred indirectly in certain cases.
Conclusions
Comparison of metal affinity sequences and their partition characteristics between the bulk soil and different mineral particles were found to be an effective tool to specify the most active mineral components in metal sorption at given soil and sorption condition.</description><identifier>ISSN: 1439-0108</identifier><identifier>EISSN: 1614-7480</identifier><identifier>DOI: 10.1007/s11368-018-2184-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Cadmium ; Clay ; Clay minerals ; Copper ; Dust ; Earth and Environmental Science ; Electron microscopy ; Environment ; Environmental Physics ; Heavy metals ; Heterogeneity ; Iron ; Lead ; Metals ; Minerals ; Partitions ; Precipitates ; Sec 3 • Remediation and Management of Contaminated or Degraded Lands • Research Article ; Soil ; Soil conditions ; Soil Science & Conservation ; Soils ; Sorbents ; Sorption ; Transmission electron microscopy ; Zinc</subject><ispartof>Journal of soils and sediments, 2019-04, Vol.19 (4), p.1775-1787</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2018</rights><rights>Journal of Soils and Sediments is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-cc8c686d08d2124c1cc34df63e96617f3f9ca1b2148b24e4e4a3f63b4cafbda3</citedby><cites>FETCH-LOGICAL-c359t-cc8c686d08d2124c1cc34df63e96617f3f9ca1b2148b24e4e4a3f63b4cafbda3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11368-018-2184-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11368-018-2184-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sipos, Péter</creatorcontrib><creatorcontrib>Tóth, Adrienn</creatorcontrib><creatorcontrib>Kis, Viktória Kovács</creatorcontrib><creatorcontrib>Balázs, Réka</creatorcontrib><creatorcontrib>Kovács, Ivett</creatorcontrib><creatorcontrib>Németh, Tibor</creatorcontrib><title>Partition of Cd, Cu, Pb and Zn among mineral particles during their sorption in soils</title><title>Journal of soils and sediments</title><addtitle>J Soils Sediments</addtitle><description>Purpose
Heterogeneity of soil mineral particles may lead to the misinterpretation of bulk sorption data on their role in metal sorption, which may be resolved through the direct observation of metal distribution among the soil particles after the sorption.
Materials and methods
Analytical transmission electron microscopy was used to study metal (Cd, Cu, Pb, Zn) sorption characteristics of clay minerals, Fe-oxyhydroxides and their natural assemblages in soils with contrasting pH under single element and competitive situations.
Results and discussion
Iron-oxyhydroxides sorbed higher metal amounts than clay mineral particles mostly, and the sorption capacity of the latter phases were more affected by competition. Iron-oxyhydroxide particles acted as effective metal sorbents in soils not only as individual particles but also as coatings on other mineral particles, and the structural Fe in clay minerals may also resulted in higher metal sorption in some cases. Besides the direct observation of metal sorption onto soil mineral particles, metal precipitates could be identified directly, and the role of organic surfaces in metal sorption could be inferred indirectly in certain cases.
Conclusions
Comparison of metal affinity sequences and their partition characteristics between the bulk soil and different mineral particles were found to be an effective tool to specify the most active mineral components in metal sorption at given soil and sorption condition.</description><subject>Cadmium</subject><subject>Clay</subject><subject>Clay minerals</subject><subject>Copper</subject><subject>Dust</subject><subject>Earth and Environmental Science</subject><subject>Electron microscopy</subject><subject>Environment</subject><subject>Environmental Physics</subject><subject>Heavy metals</subject><subject>Heterogeneity</subject><subject>Iron</subject><subject>Lead</subject><subject>Metals</subject><subject>Minerals</subject><subject>Partitions</subject><subject>Precipitates</subject><subject>Sec 3 • Remediation and Management of Contaminated or Degraded Lands • Research Article</subject><subject>Soil</subject><subject>Soil conditions</subject><subject>Soil Science & Conservation</subject><subject>Soils</subject><subject>Sorbents</subject><subject>Sorption</subject><subject>Transmission electron microscopy</subject><subject>Zinc</subject><issn>1439-0108</issn><issn>1614-7480</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1UMtKxDAUDaLgOPoB7gJup5rbxDRdSvEFA85i3LgJaR6aodPWpF04X29qBVdyF_fCeVzOQegSyDUQUtxEAMpFRkBkOQiWHY7QAjiwrGCCHKeb0TKhRJyisxh3hNAiwQv0ulFh8IPvWtw5XJkVrsYV3tRYtQa_tVjtu_Yd731rg2pwP5F1YyM2Y_AJGD6sDzh2of-x8G26fRPP0YlTTbQXv3uJtg_32-opW788Pld360zT23LItBaaC26IMDnkTIPWlBnHqS05h8JRV2oFdQ5M1DmzaRRNaM20crVRdImuZts-dJ-jjYPcdWNo00eZA4WUkTOSWDCzdOhiDNbJPvi9Cl8SiJzKk3N5MpUnp_LkIWnyWRP7KacNf87_i74BcA5yPw</recordid><startdate>20190401</startdate><enddate>20190401</enddate><creator>Sipos, Péter</creator><creator>Tóth, Adrienn</creator><creator>Kis, Viktória Kovács</creator><creator>Balázs, Réka</creator><creator>Kovács, Ivett</creator><creator>Németh, Tibor</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7UA</scope><scope>7X2</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>H96</scope><scope>H97</scope><scope>HCIFZ</scope><scope>L.G</scope><scope>M0K</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope></search><sort><creationdate>20190401</creationdate><title>Partition of Cd, Cu, Pb and Zn among mineral particles during their sorption in soils</title><author>Sipos, Péter ; Tóth, Adrienn ; Kis, Viktória Kovács ; Balázs, Réka ; Kovács, Ivett ; Németh, Tibor</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-cc8c686d08d2124c1cc34df63e96617f3f9ca1b2148b24e4e4a3f63b4cafbda3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Cadmium</topic><topic>Clay</topic><topic>Clay minerals</topic><topic>Copper</topic><topic>Dust</topic><topic>Earth and Environmental Science</topic><topic>Electron microscopy</topic><topic>Environment</topic><topic>Environmental Physics</topic><topic>Heavy metals</topic><topic>Heterogeneity</topic><topic>Iron</topic><topic>Lead</topic><topic>Metals</topic><topic>Minerals</topic><topic>Partitions</topic><topic>Precipitates</topic><topic>Sec 3 • Remediation and Management of Contaminated or Degraded Lands • Research Article</topic><topic>Soil</topic><topic>Soil conditions</topic><topic>Soil Science & Conservation</topic><topic>Soils</topic><topic>Sorbents</topic><topic>Sorption</topic><topic>Transmission electron microscopy</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sipos, Péter</creatorcontrib><creatorcontrib>Tóth, Adrienn</creatorcontrib><creatorcontrib>Kis, Viktória Kovács</creatorcontrib><creatorcontrib>Balázs, Réka</creatorcontrib><creatorcontrib>Kovács, Ivett</creatorcontrib><creatorcontrib>Németh, Tibor</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Environment Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Agricultural Science Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ProQuest Central Student</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>SciTech Premium Collection</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Agricultural Science Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>Environment Abstracts</collection><jtitle>Journal of soils and sediments</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sipos, Péter</au><au>Tóth, Adrienn</au><au>Kis, Viktória Kovács</au><au>Balázs, Réka</au><au>Kovács, Ivett</au><au>Németh, Tibor</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Partition of Cd, Cu, Pb and Zn among mineral particles during their sorption in soils</atitle><jtitle>Journal of soils and sediments</jtitle><stitle>J Soils Sediments</stitle><date>2019-04-01</date><risdate>2019</risdate><volume>19</volume><issue>4</issue><spage>1775</spage><epage>1787</epage><pages>1775-1787</pages><issn>1439-0108</issn><eissn>1614-7480</eissn><abstract>Purpose
Heterogeneity of soil mineral particles may lead to the misinterpretation of bulk sorption data on their role in metal sorption, which may be resolved through the direct observation of metal distribution among the soil particles after the sorption.
Materials and methods
Analytical transmission electron microscopy was used to study metal (Cd, Cu, Pb, Zn) sorption characteristics of clay minerals, Fe-oxyhydroxides and their natural assemblages in soils with contrasting pH under single element and competitive situations.
Results and discussion
Iron-oxyhydroxides sorbed higher metal amounts than clay mineral particles mostly, and the sorption capacity of the latter phases were more affected by competition. Iron-oxyhydroxide particles acted as effective metal sorbents in soils not only as individual particles but also as coatings on other mineral particles, and the structural Fe in clay minerals may also resulted in higher metal sorption in some cases. Besides the direct observation of metal sorption onto soil mineral particles, metal precipitates could be identified directly, and the role of organic surfaces in metal sorption could be inferred indirectly in certain cases.
Conclusions
Comparison of metal affinity sequences and their partition characteristics between the bulk soil and different mineral particles were found to be an effective tool to specify the most active mineral components in metal sorption at given soil and sorption condition.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11368-018-2184-z</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Journal of soils and sediments, 2019-04, Vol.19 (4), p.1775-1787 |
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| language | eng |
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| subjects | Cadmium Clay Clay minerals Copper Dust Earth and Environmental Science Electron microscopy Environment Environmental Physics Heavy metals Heterogeneity Iron Lead Metals Minerals Partitions Precipitates Sec 3 • Remediation and Management of Contaminated or Degraded Lands • Research Article Soil Soil conditions Soil Science & Conservation Soils Sorbents Sorption Transmission electron microscopy Zinc |
| title | Partition of Cd, Cu, Pb and Zn among mineral particles during their sorption in soils |
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