Facile preparation of a tetraphenylethylene-doped metal-organic framework for white light-emitting diodes
A highly emissive fluorophore, 1,2-bis(4-(4-carboxyphenyl))-1,2-diphenylethene ( H 2 BCPPE ), has been successfully introduced into a bio-MOF-101 -archetype structure via solvent-assisted ligand exchange (SALE). The crystallinity and topological structure of the as-synthesized compound are retained...
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| Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2018-11, Vol.6 (43), p.1171-1176 |
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| container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
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| creator | Zhao, Si-Si Zhang, Hang Wang, Lei Chen, Li Xie, Zhigang |
| description | A highly emissive fluorophore, 1,2-bis(4-(4-carboxyphenyl))-1,2-diphenylethene (
H
2
BCPPE
), has been successfully introduced into a
bio-MOF-101
-archetype structure
via
solvent-assisted ligand exchange (SALE). The crystallinity and topological structure of the as-synthesized compound are retained after ligand exchange. The exchange ratio of the BCPPE ligand in
bio-MOF-101-BCPPE
reaches 18.3 mol% as determined by
1
H NMR spectra of the dissolved samples. Additionally,
bio-MOF-101-BCPPE
exhibits broadband white emission with CIE coordinates of (0.35,0.36), under an excitation wavelength of 375 nm and an applied bias of 3 V; therefore, it can be used as a white light-emitting diode (WLED). This work can be easily extended to other porous materials for the design and preparation of new light devices.
A highly emissive TPE-based fluorophore was facially introduced into
bio-MOF-101
archetype structure
via
SALE for further using in WLED. |
| doi_str_mv | 10.1039/c8tc03460e |
| format | Article |
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H
2
BCPPE
), has been successfully introduced into a
bio-MOF-101
-archetype structure
via
solvent-assisted ligand exchange (SALE). The crystallinity and topological structure of the as-synthesized compound are retained after ligand exchange. The exchange ratio of the BCPPE ligand in
bio-MOF-101-BCPPE
reaches 18.3 mol% as determined by
1
H NMR spectra of the dissolved samples. Additionally,
bio-MOF-101-BCPPE
exhibits broadband white emission with CIE coordinates of (0.35,0.36), under an excitation wavelength of 375 nm and an applied bias of 3 V; therefore, it can be used as a white light-emitting diode (WLED). This work can be easily extended to other porous materials for the design and preparation of new light devices.
A highly emissive TPE-based fluorophore was facially introduced into
bio-MOF-101
archetype structure
via
SALE for further using in WLED.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/c8tc03460e</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Broadband ; Diodes ; Exchanging ; Ligands ; Metal-organic frameworks ; NMR ; Nuclear magnetic resonance ; Organic light emitting diodes ; Porous materials ; White light</subject><ispartof>Journal of materials chemistry. C, Materials for optical and electronic devices, 2018-11, Vol.6 (43), p.1171-1176</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-b568e612a5f6462ca7442e8e72579b3f3967b17e899031ffd7cbc47d42a4f27e3</citedby><cites>FETCH-LOGICAL-c281t-b568e612a5f6462ca7442e8e72579b3f3967b17e899031ffd7cbc47d42a4f27e3</cites><orcidid>0000-0003-4395-5002 ; 0000-0001-7922-0599 ; 0000-0003-2974-1825</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Zhao, Si-Si</creatorcontrib><creatorcontrib>Zhang, Hang</creatorcontrib><creatorcontrib>Wang, Lei</creatorcontrib><creatorcontrib>Chen, Li</creatorcontrib><creatorcontrib>Xie, Zhigang</creatorcontrib><title>Facile preparation of a tetraphenylethylene-doped metal-organic framework for white light-emitting diodes</title><title>Journal of materials chemistry. C, Materials for optical and electronic devices</title><description>A highly emissive fluorophore, 1,2-bis(4-(4-carboxyphenyl))-1,2-diphenylethene (
H
2
BCPPE
), has been successfully introduced into a
bio-MOF-101
-archetype structure
via
solvent-assisted ligand exchange (SALE). The crystallinity and topological structure of the as-synthesized compound are retained after ligand exchange. The exchange ratio of the BCPPE ligand in
bio-MOF-101-BCPPE
reaches 18.3 mol% as determined by
1
H NMR spectra of the dissolved samples. Additionally,
bio-MOF-101-BCPPE
exhibits broadband white emission with CIE coordinates of (0.35,0.36), under an excitation wavelength of 375 nm and an applied bias of 3 V; therefore, it can be used as a white light-emitting diode (WLED). This work can be easily extended to other porous materials for the design and preparation of new light devices.
A highly emissive TPE-based fluorophore was facially introduced into
bio-MOF-101
archetype structure
via
SALE for further using in WLED.</description><subject>Broadband</subject><subject>Diodes</subject><subject>Exchanging</subject><subject>Ligands</subject><subject>Metal-organic frameworks</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic light emitting diodes</subject><subject>Porous materials</subject><subject>White light</subject><issn>2050-7526</issn><issn>2050-7534</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpFkM9LwzAUx4soOOYu3oWAN6GaX03So5RNhYGXeS5p-rJmtk1NM8b-e6uT-Q7vvcOH7xc-SXJL8CPBLH8yKhrMuMBwkcwoznAqM8Yvzz8V18liHHd4GkWEEvkscSttXAtoCDDooKPzPfIWaRQhBj000B9biM20ekhrP0CNOoi6TX3Y6t4ZZIPu4ODDJ7I-oEPjIqDWbZuYQudidP0W1c7XMN4kV1a3Iyz-7jz5WC03xWu6fn95K57XqaGKxLTKhAJBqM6s4IIaLTmnoEDSTOYVsywXsiISVJ5jRqytpakMlzWnmlsqgc2T-1PuEPzXHsZY7vw-9FNlSQnDCmc0YxP1cKJM8OMYwJZDcJ0Ox5Lg8sdmWahN8WtzOcF3JziM5sz922bf-ItyXQ</recordid><startdate>20181108</startdate><enddate>20181108</enddate><creator>Zhao, Si-Si</creator><creator>Zhang, Hang</creator><creator>Wang, Lei</creator><creator>Chen, Li</creator><creator>Xie, Zhigang</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-4395-5002</orcidid><orcidid>https://orcid.org/0000-0001-7922-0599</orcidid><orcidid>https://orcid.org/0000-0003-2974-1825</orcidid></search><sort><creationdate>20181108</creationdate><title>Facile preparation of a tetraphenylethylene-doped metal-organic framework for white light-emitting diodes</title><author>Zhao, Si-Si ; Zhang, Hang ; Wang, Lei ; Chen, Li ; Xie, Zhigang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-b568e612a5f6462ca7442e8e72579b3f3967b17e899031ffd7cbc47d42a4f27e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Broadband</topic><topic>Diodes</topic><topic>Exchanging</topic><topic>Ligands</topic><topic>Metal-organic frameworks</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic light emitting diodes</topic><topic>Porous materials</topic><topic>White light</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Si-Si</creatorcontrib><creatorcontrib>Zhang, Hang</creatorcontrib><creatorcontrib>Wang, Lei</creatorcontrib><creatorcontrib>Chen, Li</creatorcontrib><creatorcontrib>Xie, Zhigang</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Si-Si</au><au>Zhang, Hang</au><au>Wang, Lei</au><au>Chen, Li</au><au>Xie, Zhigang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile preparation of a tetraphenylethylene-doped metal-organic framework for white light-emitting diodes</atitle><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle><date>2018-11-08</date><risdate>2018</risdate><volume>6</volume><issue>43</issue><spage>1171</spage><epage>1176</epage><pages>1171-1176</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>A highly emissive fluorophore, 1,2-bis(4-(4-carboxyphenyl))-1,2-diphenylethene (
H
2
BCPPE
), has been successfully introduced into a
bio-MOF-101
-archetype structure
via
solvent-assisted ligand exchange (SALE). The crystallinity and topological structure of the as-synthesized compound are retained after ligand exchange. The exchange ratio of the BCPPE ligand in
bio-MOF-101-BCPPE
reaches 18.3 mol% as determined by
1
H NMR spectra of the dissolved samples. Additionally,
bio-MOF-101-BCPPE
exhibits broadband white emission with CIE coordinates of (0.35,0.36), under an excitation wavelength of 375 nm and an applied bias of 3 V; therefore, it can be used as a white light-emitting diode (WLED). This work can be easily extended to other porous materials for the design and preparation of new light devices.
A highly emissive TPE-based fluorophore was facially introduced into
bio-MOF-101
archetype structure
via
SALE for further using in WLED.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c8tc03460e</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-4395-5002</orcidid><orcidid>https://orcid.org/0000-0001-7922-0599</orcidid><orcidid>https://orcid.org/0000-0003-2974-1825</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7526 |
| ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2018-11, Vol.6 (43), p.1171-1176 |
| issn | 2050-7526 2050-7534 |
| language | eng |
| recordid | cdi_proquest_journals_2130805253 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Broadband Diodes Exchanging Ligands Metal-organic frameworks NMR Nuclear magnetic resonance Organic light emitting diodes Porous materials White light |
| title | Facile preparation of a tetraphenylethylene-doped metal-organic framework for white light-emitting diodes |
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