Utilizing an effective framework to dye energy transfer in a carbazole-based metal–organic framework for high performance white light emission tuning
By using a carbazole derived triangular carboxylic ligand, a Zn( ii ) based metal–organic framework (MOF) revealing a high porosity framework structure and carbazole based intense blue-light emission is obtained. The structural and photophysical characteristics of the MOF make it an ideal energy tra...
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| Veröffentlicht in: | Inorganic chemistry frontiers 2018-11, Vol.5 (11), p.2868-2874 |
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| container_title | Inorganic chemistry frontiers |
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| creator | Xia, Yu-Pei Wang, Chen-Xue An, Lian-Cai Zhang, Da-Shuai Hu, Tong-Liang Xu, Jialiang Chang, Ze Bu, Xian-He |
| description | By using a carbazole derived triangular carboxylic ligand, a Zn(
ii
) based metal–organic framework (MOF) revealing a high porosity framework structure and carbazole based intense blue-light emission is obtained. The structural and photophysical characteristics of the MOF make it an ideal energy transfer platform for the accommodation and sensitization of red and green fluorescent dyes for the tuning of white light emission. By simultaneously introducing red and green fluorescent dyes into the host MOF framework and carefully controlling their contents, a high performance white-light-emitting luminophore was obtained. The luminophor reveals Commission International de l'Eclairage (CIE) coordinates of (0.32, 0.31), a correlated colour temperature (CCT) of 6186 K, a colour-rendering index (CRI) of 91, and a high quantum yield of up to 39.4%, which could be a candidate for application in white-light-emitting diodes (WLEDs). |
| doi_str_mv | 10.1039/C8QI00747K |
| format | Article |
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ii
) based metal–organic framework (MOF) revealing a high porosity framework structure and carbazole based intense blue-light emission is obtained. The structural and photophysical characteristics of the MOF make it an ideal energy transfer platform for the accommodation and sensitization of red and green fluorescent dyes for the tuning of white light emission. By simultaneously introducing red and green fluorescent dyes into the host MOF framework and carefully controlling their contents, a high performance white-light-emitting luminophore was obtained. The luminophor reveals Commission International de l'Eclairage (CIE) coordinates of (0.32, 0.31), a correlated colour temperature (CCT) of 6186 K, a colour-rendering index (CRI) of 91, and a high quantum yield of up to 39.4%, which could be a candidate for application in white-light-emitting diodes (WLEDs).</description><identifier>ISSN: 2052-1553</identifier><identifier>ISSN: 2052-1545</identifier><identifier>EISSN: 2052-1553</identifier><identifier>DOI: 10.1039/C8QI00747K</identifier><language>eng</language><publisher>London: Royal Society of Chemistry</publisher><subject>Carbazoles ; Color temperature ; Crystallography ; Diodes ; Energy transfer ; Fluorescence ; Fluorescent dyes ; Inorganic chemistry ; Light emission ; Metal-organic frameworks ; Organic light emitting diodes ; Porosity ; Tuning ; White light ; Zinc</subject><ispartof>Inorganic chemistry frontiers, 2018-11, Vol.5 (11), p.2868-2874</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c325t-47ed2b65566dc9d3c131ee48919f41eaeed70d2a2b15f7c22cbfe15cdab1e92e3</citedby><cites>FETCH-LOGICAL-c325t-47ed2b65566dc9d3c131ee48919f41eaeed70d2a2b15f7c22cbfe15cdab1e92e3</cites><orcidid>0000-0001-9619-9867 ; 0000-0002-3865-2165 ; 0000-0002-2646-7974</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Xia, Yu-Pei</creatorcontrib><creatorcontrib>Wang, Chen-Xue</creatorcontrib><creatorcontrib>An, Lian-Cai</creatorcontrib><creatorcontrib>Zhang, Da-Shuai</creatorcontrib><creatorcontrib>Hu, Tong-Liang</creatorcontrib><creatorcontrib>Xu, Jialiang</creatorcontrib><creatorcontrib>Chang, Ze</creatorcontrib><creatorcontrib>Bu, Xian-He</creatorcontrib><title>Utilizing an effective framework to dye energy transfer in a carbazole-based metal–organic framework for high performance white light emission tuning</title><title>Inorganic chemistry frontiers</title><description>By using a carbazole derived triangular carboxylic ligand, a Zn(
ii
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The luminophor reveals Commission International de l'Eclairage (CIE) coordinates of (0.32, 0.31), a correlated colour temperature (CCT) of 6186 K, a colour-rendering index (CRI) of 91, and a high quantum yield of up to 39.4%, which could be a candidate for application in white-light-emitting diodes (WLEDs).</description><subject>Carbazoles</subject><subject>Color temperature</subject><subject>Crystallography</subject><subject>Diodes</subject><subject>Energy transfer</subject><subject>Fluorescence</subject><subject>Fluorescent dyes</subject><subject>Inorganic chemistry</subject><subject>Light emission</subject><subject>Metal-organic frameworks</subject><subject>Organic light emitting diodes</subject><subject>Porosity</subject><subject>Tuning</subject><subject>White light</subject><subject>Zinc</subject><issn>2052-1553</issn><issn>2052-1545</issn><issn>2052-1553</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpNUM1Kw0AYDKJgqb34BB94E6L7k5_mKMWfYkEEew6bzbfp1mS37m4t7cl38OD7-SRGKtjTDMMwM0wUnVNyRQkvrifj5ykheZI_HkUDRlIW0zTlxwf8NBp5vySEUJoQmpFB9DUPutU7bRoQBlAplEG_IygnOtxY9wrBQr1FQIOu2UJwwniFDrQBAVK4Suxsi3ElPNbQYRDt98endY0wWh6kKOtgoZsFrND1vBNGImwWOiC0vRwAO-29tgbC2vRrzqITJVqPoz8cRvO725fJQzx7up9Obmax5CwNcZJjzaosTbOslkXNJeUUMRkXtFAJRYFY56RmglU0VblkTFYKaSprUVEsGPJhdLHPXTn7tkYfyqVdO9NXloxyQtl4nOe963Lvks5671CVK6c74bYlJeXv9-X_9_wHUwd7ew</recordid><startdate>20181101</startdate><enddate>20181101</enddate><creator>Xia, Yu-Pei</creator><creator>Wang, Chen-Xue</creator><creator>An, Lian-Cai</creator><creator>Zhang, Da-Shuai</creator><creator>Hu, Tong-Liang</creator><creator>Xu, Jialiang</creator><creator>Chang, Ze</creator><creator>Bu, Xian-He</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-9619-9867</orcidid><orcidid>https://orcid.org/0000-0002-3865-2165</orcidid><orcidid>https://orcid.org/0000-0002-2646-7974</orcidid></search><sort><creationdate>20181101</creationdate><title>Utilizing an effective framework to dye energy transfer in a carbazole-based metal–organic framework for high performance white light emission tuning</title><author>Xia, Yu-Pei ; Wang, Chen-Xue ; An, Lian-Cai ; Zhang, Da-Shuai ; Hu, Tong-Liang ; Xu, Jialiang ; Chang, Ze ; Bu, Xian-He</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-47ed2b65566dc9d3c131ee48919f41eaeed70d2a2b15f7c22cbfe15cdab1e92e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Carbazoles</topic><topic>Color temperature</topic><topic>Crystallography</topic><topic>Diodes</topic><topic>Energy transfer</topic><topic>Fluorescence</topic><topic>Fluorescent dyes</topic><topic>Inorganic chemistry</topic><topic>Light emission</topic><topic>Metal-organic frameworks</topic><topic>Organic light emitting diodes</topic><topic>Porosity</topic><topic>Tuning</topic><topic>White light</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xia, Yu-Pei</creatorcontrib><creatorcontrib>Wang, Chen-Xue</creatorcontrib><creatorcontrib>An, Lian-Cai</creatorcontrib><creatorcontrib>Zhang, Da-Shuai</creatorcontrib><creatorcontrib>Hu, Tong-Liang</creatorcontrib><creatorcontrib>Xu, Jialiang</creatorcontrib><creatorcontrib>Chang, Ze</creatorcontrib><creatorcontrib>Bu, Xian-He</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Inorganic chemistry frontiers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xia, Yu-Pei</au><au>Wang, Chen-Xue</au><au>An, Lian-Cai</au><au>Zhang, Da-Shuai</au><au>Hu, Tong-Liang</au><au>Xu, Jialiang</au><au>Chang, Ze</au><au>Bu, Xian-He</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Utilizing an effective framework to dye energy transfer in a carbazole-based metal–organic framework for high performance white light emission tuning</atitle><jtitle>Inorganic chemistry frontiers</jtitle><date>2018-11-01</date><risdate>2018</risdate><volume>5</volume><issue>11</issue><spage>2868</spage><epage>2874</epage><pages>2868-2874</pages><issn>2052-1553</issn><issn>2052-1545</issn><eissn>2052-1553</eissn><abstract>By using a carbazole derived triangular carboxylic ligand, a Zn(
ii
) based metal–organic framework (MOF) revealing a high porosity framework structure and carbazole based intense blue-light emission is obtained. The structural and photophysical characteristics of the MOF make it an ideal energy transfer platform for the accommodation and sensitization of red and green fluorescent dyes for the tuning of white light emission. By simultaneously introducing red and green fluorescent dyes into the host MOF framework and carefully controlling their contents, a high performance white-light-emitting luminophore was obtained. The luminophor reveals Commission International de l'Eclairage (CIE) coordinates of (0.32, 0.31), a correlated colour temperature (CCT) of 6186 K, a colour-rendering index (CRI) of 91, and a high quantum yield of up to 39.4%, which could be a candidate for application in white-light-emitting diodes (WLEDs).</abstract><cop>London</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/C8QI00747K</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-9619-9867</orcidid><orcidid>https://orcid.org/0000-0002-3865-2165</orcidid><orcidid>https://orcid.org/0000-0002-2646-7974</orcidid></addata></record> |
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| ispartof | Inorganic chemistry frontiers, 2018-11, Vol.5 (11), p.2868-2874 |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Carbazoles Color temperature Crystallography Diodes Energy transfer Fluorescence Fluorescent dyes Inorganic chemistry Light emission Metal-organic frameworks Organic light emitting diodes Porosity Tuning White light Zinc |
| title | Utilizing an effective framework to dye energy transfer in a carbazole-based metal–organic framework for high performance white light emission tuning |
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