Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis

Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐ or alkenyl‐metal reagents, which have a wide range of applications in organic transformations. In recent years, the first row transition metals (such as copper, nickel, cobalt, iron, etc.) have emerged high act...

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Veröffentlicht in:	Chinese journal of chemistry 2018-11, Vol.36 (11), p.1075-1109
Hauptverfasser:	Chen, Jianhui, Guo, Jun, Lu, Zhan
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Alkynes Catalysis Cobalt Dienes Heavy metals hydrometallation Iron Metals metal‐hydride Nickel Reagents Selectivity the first row transition metals Transformations Transition metals
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creator	Chen, Jianhui Guo, Jun Lu, Zhan
description	Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐ or alkenyl‐metal reagents, which have a wide range of applications in organic transformations. In recent years, the first row transition metals (such as copper, nickel, cobalt, iron, etc.) have emerged high activity and selectivity in this area with the aid of a variety of ligands. This review covers the recent advances in the hydrometallation of minimally functionalized unsaturated C—C bonds (including alkenes, alkynes, dienes, allenes, enynes, etc.), as well as transformations involving catalytic hydrometallation process via the first row transition metal catalysis.
doi_str_mv	10.1002/cjoc.201800314
format	Article
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subjects	Alkenes Alkynes Catalysis Cobalt Dienes Heavy metals hydrometallation Iron Metals metal‐hydride Nickel Reagents Selectivity the first row transition metals Transformations Transition metals
title	Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis
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