Super toughened poly(trimethylene terephthalate) composite using flowable crosslink elastomer blend
Super toughened poly(trimethylene terephthalate) (PTT) blend was obtained by melt blending of PTT with a flowable crosslinked elastomer blend. The elastomer blend was prepared through reaction between an epoxy contained ethylene acrylate copolymer (EMMA‐GMA) and an ethylene acrylic copolymer with ca...
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| Veröffentlicht in: | Polymer engineering and science 2018-11, Vol.58 (11), p.2039-2046 |
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| container_end_page | 2046 |
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| container_issue | 11 |
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| container_title | Polymer engineering and science |
| container_volume | 58 |
| creator | Hu, Xilong Wang, Yan Yu, Junrong Zhu, Jing Hu, Zuming |
| description | Super toughened poly(trimethylene terephthalate) (PTT) blend was obtained by melt blending of PTT with a flowable crosslinked elastomer blend. The elastomer blend was prepared through reaction between an epoxy contained ethylene acrylate copolymer (EMMA‐GMA) and an ethylene acrylic copolymer with carboxylic acid and zinc ion (EMAA‐Zn). The EMMA‐GMA/EMAA‐Zn elastomer with rich epoxy groups was found to be an effective impact modifier in PTT resin because the zinc ion in the elastomer catalyzed the reaction between the epoxy and end groups of PTT resin to promote the interfacial compatibilization between the PTT matrix and the crosslinked elastomer phase. It was found that a homogeneous and moderate dispersed size was achieved in the super toughened PTT/(EMMA‐GMA/EMAA‐Zn) blend due to the improvement of interfacial miscibility and the increase of viscosity ratio of crosslinked elastomer to PTT. POLYM. ENG. SCI., 58:2039–2046, 2018. © 2017 Society of Plastics Engineers |
| doi_str_mv | 10.1002/pen.24815 |
| format | Article |
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SCI., 58:2039–2046, 2018. © 2017 Society of Plastics Engineers</description><subject>Copolymers</subject><subject>Crosslinking</subject><subject>Elastomers</subject><subject>Epoxy resins</subject><subject>Ethylene</subject><subject>Mechanical properties</subject><subject>Melt blending</subject><subject>Miscibility</subject><subject>Polyethylene terephthalate</subject><subject>Polymer composites</subject><subject>Polymers</subject><subject>Production processes</subject><subject>Terephthalate</subject><subject>Viscosity ratio</subject><subject>Zinc</subject><issn>0032-3888</issn><issn>1548-2634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>N95</sourceid><recordid>eNp1kkFr3DAQhUVpIdu0h_wDQy8N1BvJkmzrGEKaBEJbmvYsZO3IVipbriST7L-Pki20C1sEEjy-NxpmHkInBK8JxtXZDNO6Yi3hr9CKcNaWVU3Za7TCmFYlbdv2CL2N8R5nlnKxQvpumSEUyS_9ABNsitm77ccU7Ahp2LosFQkCzEMalFMJTgvtx9lHm6BYop36wjj_oDoHhQ4-RmenXwU4FZMfc92sT5t36I1RLsL7P-8x-vn58sfFdXn79erm4vy21KyhvGRaEc0JGMi9Mt4JaBvT1aLjpBEcEwPCAONcAMO8aVTbVaoSXcM3wAiugR6jD7u6c_C_F4hJ3vslTPlLWZGqERVpav6X6pUDaSfjU1B6tFHLc17TltZE0EyVB6g-zyMo5ycwNst7_PoAn88GRqsPGk73DJlJ8Jh6tcQob-6-77Of_mG757lDzFe0_ZDiznKo9MtGAhg5532qsJUEy-eUyJwS-ZKSzJ7t2Ifc3_b_oPx2-WXneALy1bzT</recordid><startdate>201811</startdate><enddate>201811</enddate><creator>Hu, Xilong</creator><creator>Wang, Yan</creator><creator>Yu, Junrong</creator><creator>Zhu, Jing</creator><creator>Hu, Zuming</creator><general>Society of Plastics Engineers, Inc</general><general>Blackwell Publishing Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>N95</scope><scope>XI7</scope><scope>ISR</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-2666-4545</orcidid></search><sort><creationdate>201811</creationdate><title>Super toughened poly(trimethylene terephthalate) composite using flowable crosslink elastomer blend</title><author>Hu, Xilong ; Wang, Yan ; Yu, Junrong ; Zhu, Jing ; Hu, Zuming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4735-4ca1c51efe03245b9e87fb69b5179501fe9fe4559e40577a8b2a29b75de4106e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Copolymers</topic><topic>Crosslinking</topic><topic>Elastomers</topic><topic>Epoxy resins</topic><topic>Ethylene</topic><topic>Mechanical properties</topic><topic>Melt blending</topic><topic>Miscibility</topic><topic>Polyethylene terephthalate</topic><topic>Polymer composites</topic><topic>Polymers</topic><topic>Production processes</topic><topic>Terephthalate</topic><topic>Viscosity ratio</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Xilong</creatorcontrib><creatorcontrib>Wang, Yan</creatorcontrib><creatorcontrib>Yu, Junrong</creatorcontrib><creatorcontrib>Zhu, Jing</creatorcontrib><creatorcontrib>Hu, Zuming</creatorcontrib><collection>CrossRef</collection><collection>Gale Business: Insights</collection><collection>Business Insights: Essentials</collection><collection>Gale In Context: Science</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer engineering and science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Xilong</au><au>Wang, Yan</au><au>Yu, Junrong</au><au>Zhu, Jing</au><au>Hu, Zuming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Super toughened poly(trimethylene terephthalate) composite using flowable crosslink elastomer blend</atitle><jtitle>Polymer engineering and science</jtitle><date>2018-11</date><risdate>2018</risdate><volume>58</volume><issue>11</issue><spage>2039</spage><epage>2046</epage><pages>2039-2046</pages><issn>0032-3888</issn><eissn>1548-2634</eissn><abstract>Super toughened poly(trimethylene terephthalate) (PTT) blend was obtained by melt blending of PTT with a flowable crosslinked elastomer blend. The elastomer blend was prepared through reaction between an epoxy contained ethylene acrylate copolymer (EMMA‐GMA) and an ethylene acrylic copolymer with carboxylic acid and zinc ion (EMAA‐Zn). The EMMA‐GMA/EMAA‐Zn elastomer with rich epoxy groups was found to be an effective impact modifier in PTT resin because the zinc ion in the elastomer catalyzed the reaction between the epoxy and end groups of PTT resin to promote the interfacial compatibilization between the PTT matrix and the crosslinked elastomer phase. It was found that a homogeneous and moderate dispersed size was achieved in the super toughened PTT/(EMMA‐GMA/EMAA‐Zn) blend due to the improvement of interfacial miscibility and the increase of viscosity ratio of crosslinked elastomer to PTT. POLYM. ENG. SCI., 58:2039–2046, 2018. © 2017 Society of Plastics Engineers</abstract><cop>Newtown</cop><pub>Society of Plastics Engineers, Inc</pub><doi>10.1002/pen.24815</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-2666-4545</orcidid></addata></record> |
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| identifier | ISSN: 0032-3888 |
| ispartof | Polymer engineering and science, 2018-11, Vol.58 (11), p.2039-2046 |
| issn | 0032-3888 1548-2634 |
| language | eng |
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| source | Access via Wiley Online Library |
| subjects | Copolymers Crosslinking Elastomers Epoxy resins Ethylene Mechanical properties Melt blending Miscibility Polyethylene terephthalate Polymer composites Polymers Production processes Terephthalate Viscosity ratio Zinc |
| title | Super toughened poly(trimethylene terephthalate) composite using flowable crosslink elastomer blend |
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