Reaction of Benzylidene Chlorides with О-Methyl Diethylphosphinothioate

О -Methyl diethylphosphinothioate reacts with benzylidene chlorides to form arenecarbthioaldehyde trimers and diethylphosphinoyl chloride. This result suggests that the reaction involves initial attack of the thione sulfur atom of the phosphinothioyl group on the methine carbon atom of the gem-dichl...

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Veröffentlicht in:Russian journal of general chemistry 2018-08, Vol.88 (8), p.1754-1756
Hauptverfasser: Gazizov, M. B., Valieva, G. D., Ivanova, S. Yu, Karimova, R. F., Ismagilov, R. K., Khairullin, R. A.
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Sprache:eng
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Zusammenfassung:О -Methyl diethylphosphinothioate reacts with benzylidene chlorides to form arenecarbthioaldehyde trimers and diethylphosphinoyl chloride. This result suggests that the reaction involves initial attack of the thione sulfur atom of the phosphinothioyl group on the methine carbon atom of the gem-dichloride.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363218080327