Determination of cadmium in commercial tobacco by EMFAAS
In this work we present the use of EMFAAS (Electrothermal Metallic Furnace Atomic Absorption Spectroscopy) for the determination of Cd in the tobacco cigarettes of five commercial brands. Optimization of the experimental conditions was done by controlling the sample flow rate and the temperature of...
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| Veröffentlicht in: | Journal of analytical atomic spectrometry 2018-11, Vol.33 (11), p.1970-1973 |
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| container_end_page | 1973 |
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| container_issue | 11 |
| container_start_page | 1970 |
| container_title | Journal of analytical atomic spectrometry |
| container_volume | 33 |
| creator | Carrone, G. Morzan, E. Tudino, M. Etchenique, R. |
| description | In this work we present the use of EMFAAS (Electrothermal Metallic Furnace Atomic Absorption Spectroscopy) for the determination of Cd in the tobacco cigarettes of five commercial brands. Optimization of the experimental conditions was done by controlling the sample flow rate and the temperature of both the injection capillary and the atomization cell. The determination was made in the whole cigarettes, filters and ashes of the cigarettes once consumed, cases in which the Cd concentration is much lower and its quantification is more difficult. For the validation of the results, the ICP-OES technique was used, obtaining good agreement within the experimental error. The results show that EMFAAS is a promising tool for the determination of volatile analytes. |
| doi_str_mv | 10.1039/C8JA00195B |
| format | Article |
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Optimization of the experimental conditions was done by controlling the sample flow rate and the temperature of both the injection capillary and the atomization cell. The determination was made in the whole cigarettes, filters and ashes of the cigarettes once consumed, cases in which the Cd concentration is much lower and its quantification is more difficult. For the validation of the results, the ICP-OES technique was used, obtaining good agreement within the experimental error. The results show that EMFAAS is a promising tool for the determination of volatile analytes.</description><identifier>ISSN: 0267-9477</identifier><identifier>EISSN: 1364-5544</identifier><identifier>DOI: 10.1039/C8JA00195B</identifier><language>eng</language><publisher>London: Royal Society of Chemistry</publisher><subject>Ashes ; Atomic absorption analysis ; Atomic beam spectroscopy ; Atomizing ; Cigarettes ; Flow velocity ; Tobacco</subject><ispartof>Journal of analytical atomic spectrometry, 2018-11, Vol.33 (11), p.1970-1973</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c295t-219dd368b2394c8040dcd1ca980d0bb9dd8329eded001f8d330816dd220e7d243</citedby><cites>FETCH-LOGICAL-c295t-219dd368b2394c8040dcd1ca980d0bb9dd8329eded001f8d330816dd220e7d243</cites><orcidid>0000-0002-5485-8710 ; 0000-0003-0955-6948</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Carrone, G.</creatorcontrib><creatorcontrib>Morzan, E.</creatorcontrib><creatorcontrib>Tudino, M.</creatorcontrib><creatorcontrib>Etchenique, R.</creatorcontrib><title>Determination of cadmium in commercial tobacco by EMFAAS</title><title>Journal of analytical atomic spectrometry</title><description>In this work we present the use of EMFAAS (Electrothermal Metallic Furnace Atomic Absorption Spectroscopy) for the determination of Cd in the tobacco cigarettes of five commercial brands. Optimization of the experimental conditions was done by controlling the sample flow rate and the temperature of both the injection capillary and the atomization cell. The determination was made in the whole cigarettes, filters and ashes of the cigarettes once consumed, cases in which the Cd concentration is much lower and its quantification is more difficult. For the validation of the results, the ICP-OES technique was used, obtaining good agreement within the experimental error. 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| fulltext | fulltext |
| identifier | ISSN: 0267-9477 |
| ispartof | Journal of analytical atomic spectrometry, 2018-11, Vol.33 (11), p.1970-1973 |
| issn | 0267-9477 1364-5544 |
| language | eng |
| recordid | cdi_proquest_journals_2127422419 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Ashes Atomic absorption analysis Atomic beam spectroscopy Atomizing Cigarettes Flow velocity Tobacco |
| title | Determination of cadmium in commercial tobacco by EMFAAS |
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