Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides
The reactions of the boraquanidinato germylene (i-Pr) 2 NB(NDmp) 2 Ge ( 1 ) (Dmp = 2,6-Me 2 C 6 H 3 ) with RN 3 and RNCS produced rare examples of Ge 2 N and Ge 3 S rings, while the treatment of 1 with RNCO led to an insertion into the N-Ge bond leading to a novel type of germylene stabilized within...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2018-10, Vol.47 (42), p.1488-14883 |
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| container_issue | 42 |
| container_start_page | 1488 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 47 |
| creator | Böserle, Ji í Zhigulin, Grigory Ketkov, Sergey Jambor, Roman R i ka, Aleš Dostál, Libor |
| description | The reactions of the boraquanidinato germylene (i-Pr)
2
NB(NDmp)
2
Ge (
1
) (Dmp = 2,6-Me
2
C
6
H
3
) with RN
3
and RNCS produced rare examples of Ge
2
N and Ge
3
S rings, while the treatment of
1
with RNCO led to an insertion into the N-Ge bond leading to a novel type of germylene stabilized within a six membered ring,
i.e.
[N(R)C(O)N(Dmp)B(N(i-Pr)
2
)N(Dmp)]Ge (R =
t
-Bu or Ad).
The reactivity of the
N
,
N
-chelated germylene with pseudohalides was investigated producing various types of novel heterocycles. |
| doi_str_mv | 10.1039/c8dt03357a |
| format | Article |
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2
NB(NDmp)
2
Ge (
1
) (Dmp = 2,6-Me
2
C
6
H
3
) with RN
3
and RNCS produced rare examples of Ge
2
N and Ge
3
S rings, while the treatment of
1
with RNCO led to an insertion into the N-Ge bond leading to a novel type of germylene stabilized within a six membered ring,
i.e.
[N(R)C(O)N(Dmp)B(N(i-Pr)
2
)N(Dmp)]Ge (R =
t
-Bu or Ad).
The reactivity of the
N
,
N
-chelated germylene with pseudohalides was investigated producing various types of novel heterocycles.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c8dt03357a</identifier><identifier>PMID: 30283952</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Crystallography ; Crystals ; NMR ; Nuclear magnetic resonance ; Single crystals ; X ray spectra ; X-ray diffraction</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2018-10, Vol.47 (42), p.1488-14883</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-6f9cdf868c14f55ede94f69960533eaf66f044d9c37c9fd6a2bf259ef16bff393</citedby><cites>FETCH-LOGICAL-c337t-6f9cdf868c14f55ede94f69960533eaf66f044d9c37c9fd6a2bf259ef16bff393</cites><orcidid>0000-0001-8191-0273 ; 0000-0002-5982-1239</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30283952$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Böserle, Ji í</creatorcontrib><creatorcontrib>Zhigulin, Grigory</creatorcontrib><creatorcontrib>Ketkov, Sergey</creatorcontrib><creatorcontrib>Jambor, Roman</creatorcontrib><creatorcontrib>R i ka, Aleš</creatorcontrib><creatorcontrib>Dostál, Libor</creatorcontrib><title>Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>The reactions of the boraquanidinato germylene (i-Pr)
2
NB(NDmp)
2
Ge (
1
) (Dmp = 2,6-Me
2
C
6
H
3
) with RN
3
and RNCS produced rare examples of Ge
2
N and Ge
3
S rings, while the treatment of
1
with RNCO led to an insertion into the N-Ge bond leading to a novel type of germylene stabilized within a six membered ring,
i.e.
[N(R)C(O)N(Dmp)B(N(i-Pr)
2
)N(Dmp)]Ge (R =
t
-Bu or Ad).
The reactivity of the
N
,
N
-chelated germylene with pseudohalides was investigated producing various types of novel heterocycles.</description><subject>Crystallography</subject><subject>Crystals</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Single crystals</subject><subject>X ray spectra</subject><subject>X-ray diffraction</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpd0U1Lw0AQBuBFFKvVi3dlwYsI0f1INtljaf2Copd6Dpvd2ZqSZOtuUum_N7W1gqcZmIdheAehC0ruKOHyXmemJZwnqTpAJzRO00gyHh_ueyYG6DSEBSGMkYQdowEnLOMyYSfodVKuwAfAHpRuy1XZrrGzWOHCeTXvVFOaslGtw3Pw9bqCBnDrvpQ32Pl5P9V4GaAz7kNVpYFwho6sqgKc7-oQvT8-zMbP0fTt6WU8mkaa87SNhJXa2ExkmsY2ScCAjK2QUpCEc1BWCEvi2EjNUy2tEYoVliUSLBWFtVzyIbrZ7l1699lBaPO6DBqqSjXgupAzSgVlhIkNvf5HF67zTX9dr5jIUioJ7dXtVmnvQvBg86Uva-XXOSX5JuV8nE1mPymPeny1W9kVNZg9_Y21B5db4IPeT__exL8BLzeCAA</recordid><startdate>20181030</startdate><enddate>20181030</enddate><creator>Böserle, Ji í</creator><creator>Zhigulin, Grigory</creator><creator>Ketkov, Sergey</creator><creator>Jambor, Roman</creator><creator>R i ka, Aleš</creator><creator>Dostál, Libor</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8191-0273</orcidid><orcidid>https://orcid.org/0000-0002-5982-1239</orcidid></search><sort><creationdate>20181030</creationdate><title>Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides</title><author>Böserle, Ji í ; Zhigulin, Grigory ; Ketkov, Sergey ; Jambor, Roman ; R i ka, Aleš ; Dostál, Libor</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-6f9cdf868c14f55ede94f69960533eaf66f044d9c37c9fd6a2bf259ef16bff393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Crystallography</topic><topic>Crystals</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Single crystals</topic><topic>X ray spectra</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Böserle, Ji í</creatorcontrib><creatorcontrib>Zhigulin, Grigory</creatorcontrib><creatorcontrib>Ketkov, Sergey</creatorcontrib><creatorcontrib>Jambor, Roman</creatorcontrib><creatorcontrib>R i ka, Aleš</creatorcontrib><creatorcontrib>Dostál, Libor</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Böserle, Ji í</au><au>Zhigulin, Grigory</au><au>Ketkov, Sergey</au><au>Jambor, Roman</au><au>R i ka, Aleš</au><au>Dostál, Libor</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2018-10-30</date><risdate>2018</risdate><volume>47</volume><issue>42</issue><spage>1488</spage><epage>14883</epage><pages>1488-14883</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>The reactions of the boraquanidinato germylene (i-Pr)
2
NB(NDmp)
2
Ge (
1
) (Dmp = 2,6-Me
2
C
6
H
3
) with RN
3
and RNCS produced rare examples of Ge
2
N and Ge
3
S rings, while the treatment of
1
with RNCO led to an insertion into the N-Ge bond leading to a novel type of germylene stabilized within a six membered ring,
i.e.
[N(R)C(O)N(Dmp)B(N(i-Pr)
2
)N(Dmp)]Ge (R =
t
-Bu or Ad).
The reactivity of the
N
,
N
-chelated germylene with pseudohalides was investigated producing various types of novel heterocycles.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30283952</pmid><doi>10.1039/c8dt03357a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-8191-0273</orcidid><orcidid>https://orcid.org/0000-0002-5982-1239</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2018-10, Vol.47 (42), p.1488-14883 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_journals_2126871901 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crystallography Crystals NMR Nuclear magnetic resonance Single crystals X ray spectra X-ray diffraction |
| title | Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides |
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