Determination of aluminium phosphide (AlP) in fumigants by ICP OES
A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented. An 8 hour hydrolysis in water achieved complete decomposition of AlP, with the released PH 3 being absorbed in a medium of KMnO 4 /H 2 SO 4 . The s...
Gespeichert in:
| Veröffentlicht in: | Analytical methods 2018-11, Vol.1 (41), p.547-55 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 55 |
|---|---|
| container_issue | 41 |
| container_start_page | 547 |
| container_title | Analytical methods |
| container_volume | 1 |
| creator | Santos, E. J. Dos Zagonel, G. F Herrmann, A. B Fantin, E. B Sturgeon, R. E |
| description | A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented. An 8 hour hydrolysis in water achieved complete decomposition of AlP, with the released PH
3
being absorbed in a medium of KMnO
4
/H
2
SO
4
. The solution was treated with NH
2
OH·HCl to reduce the excess MnO
4
−
and the PO
4
3−
so formed was quantitated as P by ICP OES based on external calibration using the P(
i
) 213.618 nm emission line. A detection limit (3s,
n
= 10) of 0.26 g/100 g AlP and an LOQ (10s,
n
= 10) of 0.85 g/100 g AlP were realized. Ten commercial samples of fumigants were analysed, providing results in agreement with specifications of ∼55-60 g/100 g and concordant with values generated by a spectrophotometric method, as evidenced by a paired
t
-test (95% confidence limit). This simple procedure has been adopted by the Paraná Institute of Technology - TECPAR (Curitiba, Brazil).
A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented. |
| doi_str_mv | 10.1039/c8ay01596a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2124957003</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2124957003</sourcerecordid><originalsourceid>FETCH-LOGICAL-c344t-d332aa5f2ca983a5f0d575d1a48b12905270c497a13b79e93c0f99c2ca13d5c63</originalsourceid><addsrcrecordid>eNp9kMFLwzAUh4MoOKcX70LEiwrVpGmavmOtUweDDdSDp5ClievY2i5pD_vvjU7mzdP7Pb6P9-CH0Dkld5QwuNeZ2hLKIVUHaEAFhwhSAYf7nJJjdOL9kpAUWEoH6OHRdMatq1p1VVPjxmK16sNa9WvcLhrfLqrS4Ot8NbvBVY1tYJ-q7jyeb_G4mOHp6PUUHVm18ubsdw7R-9PorXiJJtPncZFPIs2SpItKxmKluI21goyFQEoueElVks1pDITHgugEhKJsLsAA08QC6KBTVnKdsiG62t1tXbPpje_ksuldHV7KmMYJcEEIC9btztKu8d4ZK1tXrZXbSkrkd0eyyPKPn47yIF_sZOf13vvrMPDL_7hsS8u-AJUjbKY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2124957003</pqid></control><display><type>article</type><title>Determination of aluminium phosphide (AlP) in fumigants by ICP OES</title><source>Royal Society Of Chemistry Journals</source><creator>Santos, E. J. Dos ; Zagonel, G. F ; Herrmann, A. B ; Fantin, E. B ; Sturgeon, R. E</creator><creatorcontrib>Santos, E. J. Dos ; Zagonel, G. F ; Herrmann, A. B ; Fantin, E. B ; Sturgeon, R. E</creatorcontrib><description>A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented. An 8 hour hydrolysis in water achieved complete decomposition of AlP, with the released PH
3
being absorbed in a medium of KMnO
4
/H
2
SO
4
. The solution was treated with NH
2
OH·HCl to reduce the excess MnO
4
−
and the PO
4
3−
so formed was quantitated as P by ICP OES based on external calibration using the P(
i
) 213.618 nm emission line. A detection limit (3s,
n
= 10) of 0.26 g/100 g AlP and an LOQ (10s,
n
= 10) of 0.85 g/100 g AlP were realized. Ten commercial samples of fumigants were analysed, providing results in agreement with specifications of ∼55-60 g/100 g and concordant with values generated by a spectrophotometric method, as evidenced by a paired
t
-test (95% confidence limit). This simple procedure has been adopted by the Paraná Institute of Technology - TECPAR (Curitiba, Brazil).
A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented.</description><identifier>ISSN: 1759-9660</identifier><identifier>EISSN: 1759-9679</identifier><identifier>DOI: 10.1039/c8ay01596a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Aluminum ; Calibration ; Confidence limits ; Emissions control ; Fumigants ; Inductively coupled plasma ; Optical emission spectroscopy ; Phosphides ; Potassium permanganate ; Spectrometry ; Spectrophotometry ; Sulfuric acid</subject><ispartof>Analytical methods, 2018-11, Vol.1 (41), p.547-55</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c344t-d332aa5f2ca983a5f0d575d1a48b12905270c497a13b79e93c0f99c2ca13d5c63</citedby><cites>FETCH-LOGICAL-c344t-d332aa5f2ca983a5f0d575d1a48b12905270c497a13b79e93c0f99c2ca13d5c63</cites><orcidid>0000-0001-8202-9285</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Santos, E. J. Dos</creatorcontrib><creatorcontrib>Zagonel, G. F</creatorcontrib><creatorcontrib>Herrmann, A. B</creatorcontrib><creatorcontrib>Fantin, E. B</creatorcontrib><creatorcontrib>Sturgeon, R. E</creatorcontrib><title>Determination of aluminium phosphide (AlP) in fumigants by ICP OES</title><title>Analytical methods</title><description>A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented. An 8 hour hydrolysis in water achieved complete decomposition of AlP, with the released PH
3
being absorbed in a medium of KMnO
4
/H
2
SO
4
. The solution was treated with NH
2
OH·HCl to reduce the excess MnO
4
−
and the PO
4
3−
so formed was quantitated as P by ICP OES based on external calibration using the P(
i
) 213.618 nm emission line. A detection limit (3s,
n
= 10) of 0.26 g/100 g AlP and an LOQ (10s,
n
= 10) of 0.85 g/100 g AlP were realized. Ten commercial samples of fumigants were analysed, providing results in agreement with specifications of ∼55-60 g/100 g and concordant with values generated by a spectrophotometric method, as evidenced by a paired
t
-test (95% confidence limit). This simple procedure has been adopted by the Paraná Institute of Technology - TECPAR (Curitiba, Brazil).
A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented.</description><subject>Aluminum</subject><subject>Calibration</subject><subject>Confidence limits</subject><subject>Emissions control</subject><subject>Fumigants</subject><subject>Inductively coupled plasma</subject><subject>Optical emission spectroscopy</subject><subject>Phosphides</subject><subject>Potassium permanganate</subject><subject>Spectrometry</subject><subject>Spectrophotometry</subject><subject>Sulfuric acid</subject><issn>1759-9660</issn><issn>1759-9679</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kMFLwzAUh4MoOKcX70LEiwrVpGmavmOtUweDDdSDp5ClievY2i5pD_vvjU7mzdP7Pb6P9-CH0Dkld5QwuNeZ2hLKIVUHaEAFhwhSAYf7nJJjdOL9kpAUWEoH6OHRdMatq1p1VVPjxmK16sNa9WvcLhrfLqrS4Ot8NbvBVY1tYJ-q7jyeb_G4mOHp6PUUHVm18ubsdw7R-9PorXiJJtPncZFPIs2SpItKxmKluI21goyFQEoueElVks1pDITHgugEhKJsLsAA08QC6KBTVnKdsiG62t1tXbPpje_ksuldHV7KmMYJcEEIC9btztKu8d4ZK1tXrZXbSkrkd0eyyPKPn47yIF_sZOf13vvrMPDL_7hsS8u-AJUjbKY</recordid><startdate>20181107</startdate><enddate>20181107</enddate><creator>Santos, E. J. Dos</creator><creator>Zagonel, G. F</creator><creator>Herrmann, A. B</creator><creator>Fantin, E. B</creator><creator>Sturgeon, R. E</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0001-8202-9285</orcidid></search><sort><creationdate>20181107</creationdate><title>Determination of aluminium phosphide (AlP) in fumigants by ICP OES</title><author>Santos, E. J. Dos ; Zagonel, G. F ; Herrmann, A. B ; Fantin, E. B ; Sturgeon, R. E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c344t-d332aa5f2ca983a5f0d575d1a48b12905270c497a13b79e93c0f99c2ca13d5c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aluminum</topic><topic>Calibration</topic><topic>Confidence limits</topic><topic>Emissions control</topic><topic>Fumigants</topic><topic>Inductively coupled plasma</topic><topic>Optical emission spectroscopy</topic><topic>Phosphides</topic><topic>Potassium permanganate</topic><topic>Spectrometry</topic><topic>Spectrophotometry</topic><topic>Sulfuric acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Santos, E. J. Dos</creatorcontrib><creatorcontrib>Zagonel, G. F</creatorcontrib><creatorcontrib>Herrmann, A. B</creatorcontrib><creatorcontrib>Fantin, E. B</creatorcontrib><creatorcontrib>Sturgeon, R. E</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Analytical methods</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Santos, E. J. Dos</au><au>Zagonel, G. F</au><au>Herrmann, A. B</au><au>Fantin, E. B</au><au>Sturgeon, R. E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of aluminium phosphide (AlP) in fumigants by ICP OES</atitle><jtitle>Analytical methods</jtitle><date>2018-11-07</date><risdate>2018</risdate><volume>1</volume><issue>41</issue><spage>547</spage><epage>55</epage><pages>547-55</pages><issn>1759-9660</issn><eissn>1759-9679</eissn><abstract>A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented. An 8 hour hydrolysis in water achieved complete decomposition of AlP, with the released PH
3
being absorbed in a medium of KMnO
4
/H
2
SO
4
. The solution was treated with NH
2
OH·HCl to reduce the excess MnO
4
−
and the PO
4
3−
so formed was quantitated as P by ICP OES based on external calibration using the P(
i
) 213.618 nm emission line. A detection limit (3s,
n
= 10) of 0.26 g/100 g AlP and an LOQ (10s,
n
= 10) of 0.85 g/100 g AlP were realized. Ten commercial samples of fumigants were analysed, providing results in agreement with specifications of ∼55-60 g/100 g and concordant with values generated by a spectrophotometric method, as evidenced by a paired
t
-test (95% confidence limit). This simple procedure has been adopted by the Paraná Institute of Technology - TECPAR (Curitiba, Brazil).
A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c8ay01596a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-8202-9285</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1759-9660 |
| ispartof | Analytical methods, 2018-11, Vol.1 (41), p.547-55 |
| issn | 1759-9660 1759-9679 |
| language | eng |
| recordid | cdi_proquest_journals_2124957003 |
| source | Royal Society Of Chemistry Journals |
| subjects | Aluminum Calibration Confidence limits Emissions control Fumigants Inductively coupled plasma Optical emission spectroscopy Phosphides Potassium permanganate Spectrometry Spectrophotometry Sulfuric acid |
| title | Determination of aluminium phosphide (AlP) in fumigants by ICP OES |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T22%3A03%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Determination%20of%20aluminium%20phosphide%20(AlP)%20in%20fumigants%20by%20ICP%20OES&rft.jtitle=Analytical%20methods&rft.au=Santos,%20E.%20J.%20Dos&rft.date=2018-11-07&rft.volume=1&rft.issue=41&rft.spage=547&rft.epage=55&rft.pages=547-55&rft.issn=1759-9660&rft.eissn=1759-9679&rft_id=info:doi/10.1039/c8ay01596a&rft_dat=%3Cproquest_cross%3E2124957003%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2124957003&rft_id=info:pmid/&rfr_iscdi=true |