Silver-embedded epoxy nanocomposites as organic coatings for steel

[Display omitted] •Solid phase synthesis for AgNPs.•mPEGTH a perfect reducing agent for AgNPs synthesis.•The uniform dispersion of AgNPs /mPEGTH with epoxy resins.•Spray and self-healing of the epoxy Ag nanocomposite coatings. A novel hybrid nanomaterial based on silver nanoparticles, AgNPs, support...

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Veröffentlicht in:Progress in organic coatings 2018-10, Vol.123, p.209-222
Hauptverfasser: El-Faham, Ayman, Atta, Ayman M., Osman, Sameh M., Ezzat, Abdelrahman O., El-saeed, Ashraf M., AL Othman, Zeid A., Al-Lohedan, Hamad A.
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container_end_page 222
container_issue
container_start_page 209
container_title Progress in organic coatings
container_volume 123
creator El-Faham, Ayman
Atta, Ayman M.
Osman, Sameh M.
Ezzat, Abdelrahman O.
El-saeed, Ashraf M.
AL Othman, Zeid A.
Al-Lohedan, Hamad A.
description [Display omitted] •Solid phase synthesis for AgNPs.•mPEGTH a perfect reducing agent for AgNPs synthesis.•The uniform dispersion of AgNPs /mPEGTH with epoxy resins.•Spray and self-healing of the epoxy Ag nanocomposite coatings. A novel hybrid nanomaterial based on silver nanoparticles, AgNPs, supported by 2,4-dihydrazino-6-(methoxypolyethyleneglycol)-1,3,5-triazine (mPEGTH) was prepared using solid phase technique. The synthesis process and the structural properties of the AgNPs were analyzed through X-ray diffraction (XRD), thermogravimetric analysis (TGA), transmittance and scanning electron microscopy (TEM and SEM). The effect of seawater, and pH of solutions on the aggregation and zeta potential of Ag NPs were characterized and identified. The Ag/mPEGTH, hybrid materials produced well dispersion and exhibit a remarkable superiority in enhancing the anticorrosion performance of epoxy coatings and fulfill a significant synergistic effect in anticorrosion and self-healing performance for epoxy composite coatings. The new self-healing mechanism of Ag/mPEGTH nanomaterial for the epoxy coating defects is tentatively proposed and discussed.
doi_str_mv 10.1016/j.porgcoat.2018.07.006
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source ScienceDirect Journals (5 years ago - present)
subjects Ag-nanoparticles
Coating effects
Corrosion prevention
Epoxy coatings
Mechanical properties
mPEG-dihydrazino-s-triazine
Nanocomposites
Nanomaterials
Nanoparticles
Organic coatings
Scanning electron microscopy
Seawater
Self healing materials
Self-healing
Silver
Solid phases
Steel
Synergistic effect
Thermogravimetric analysis
X-ray diffraction
Zeta potential
title Silver-embedded epoxy nanocomposites as organic coatings for steel
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