Corrosion-protective coatings based on fluorocarbosilane
[Display omitted] •Fluorocarbosiloxane coating inhibits the corrosion process of 304 stainless steel.•MetalOSi covalent bonds are created between steel surface and fluorocarbosilane.•Well-developed chains consisting of SiOSi bonds have been created. This study discusses the effect of 3-(1,1,2,2,3,3,...
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| Veröffentlicht in: | Progress in organic coatings 2018-10, Vol.123, p.374-383 |
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| container_title | Progress in organic coatings |
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| creator | Szubert, Karol Wojciechowski, Jarosław Karasiewicz, Joanna Maciejewski, Hieronim Lota, Grzegorz |
| description | [Display omitted]
•Fluorocarbosiloxane coating inhibits the corrosion process of 304 stainless steel.•MetalOSi covalent bonds are created between steel surface and fluorocarbosilane.•Well-developed chains consisting of SiOSi bonds have been created.
This study discusses the effect of 3-(1,1,2,2,3,3,4,4-octafluoropentyloxy)propyltriethoxysilane (OFTES) based coatings on the anti-corrosive properties of 304 type stainless steel, which has not been described to date. The coatings were deposited from methanol using the anhydrous deposition method and influence of the sonication on this process has also been investigated. Anti-corrosive properties of modified and unmodified steel surfaces have been characterized by electrochemical and surface analysis methods. Since silicon is an element capable of forming bonds with both organic and inorganic substrates, these features allow to combine organofunctional silanes with metal as well as steel surfaces through metalOSi covalent bonds. A fluorinated alkyl chain, which is attached to the silicon atom, forms an effective barrier against an aggressive aqueous environment. |
| doi_str_mv | 10.1016/j.porgcoat.2018.07.030 |
| format | Article |
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•Fluorocarbosiloxane coating inhibits the corrosion process of 304 stainless steel.•MetalOSi covalent bonds are created between steel surface and fluorocarbosilane.•Well-developed chains consisting of SiOSi bonds have been created.
This study discusses the effect of 3-(1,1,2,2,3,3,4,4-octafluoropentyloxy)propyltriethoxysilane (OFTES) based coatings on the anti-corrosive properties of 304 type stainless steel, which has not been described to date. The coatings were deposited from methanol using the anhydrous deposition method and influence of the sonication on this process has also been investigated. Anti-corrosive properties of modified and unmodified steel surfaces have been characterized by electrochemical and surface analysis methods. Since silicon is an element capable of forming bonds with both organic and inorganic substrates, these features allow to combine organofunctional silanes with metal as well as steel surfaces through metalOSi covalent bonds. A fluorinated alkyl chain, which is attached to the silicon atom, forms an effective barrier against an aggressive aqueous environment.</description><identifier>ISSN: 0300-9440</identifier><identifier>EISSN: 1873-331X</identifier><identifier>DOI: 10.1016/j.porgcoat.2018.07.030</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Anhydrous deposition ; Aqueous environments ; Austenitic stainless steels ; Coating effects ; Corrosion ; Corrosion effects ; Covalent bonds ; Fluorination ; Fluorocarbosilane ; Protective coatings ; Silanes ; Silicon ; Silicon steels ; Sonication ; Stainless steel ; Substrates ; Surface analysis (chemical)</subject><ispartof>Progress in organic coatings, 2018-10, Vol.123, p.374-383</ispartof><rights>2018 Elsevier B.V.</rights><rights>Copyright Elsevier BV Oct 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-cde1d8c2c3c2ccdc2b1c8db69d2172cf8c1d82af68e0ddc9176c2df63ed8ad0e3</citedby><cites>FETCH-LOGICAL-c377t-cde1d8c2c3c2ccdc2b1c8db69d2172cf8c1d82af68e0ddc9176c2df63ed8ad0e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0300944017309955$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Szubert, Karol</creatorcontrib><creatorcontrib>Wojciechowski, Jarosław</creatorcontrib><creatorcontrib>Karasiewicz, Joanna</creatorcontrib><creatorcontrib>Maciejewski, Hieronim</creatorcontrib><creatorcontrib>Lota, Grzegorz</creatorcontrib><title>Corrosion-protective coatings based on fluorocarbosilane</title><title>Progress in organic coatings</title><description>[Display omitted]
•Fluorocarbosiloxane coating inhibits the corrosion process of 304 stainless steel.•MetalOSi covalent bonds are created between steel surface and fluorocarbosilane.•Well-developed chains consisting of SiOSi bonds have been created.
This study discusses the effect of 3-(1,1,2,2,3,3,4,4-octafluoropentyloxy)propyltriethoxysilane (OFTES) based coatings on the anti-corrosive properties of 304 type stainless steel, which has not been described to date. The coatings were deposited from methanol using the anhydrous deposition method and influence of the sonication on this process has also been investigated. Anti-corrosive properties of modified and unmodified steel surfaces have been characterized by electrochemical and surface analysis methods. Since silicon is an element capable of forming bonds with both organic and inorganic substrates, these features allow to combine organofunctional silanes with metal as well as steel surfaces through metalOSi covalent bonds. A fluorinated alkyl chain, which is attached to the silicon atom, forms an effective barrier against an aggressive aqueous environment.</description><subject>Anhydrous deposition</subject><subject>Aqueous environments</subject><subject>Austenitic stainless steels</subject><subject>Coating effects</subject><subject>Corrosion</subject><subject>Corrosion effects</subject><subject>Covalent bonds</subject><subject>Fluorination</subject><subject>Fluorocarbosilane</subject><subject>Protective coatings</subject><subject>Silanes</subject><subject>Silicon</subject><subject>Silicon steels</subject><subject>Sonication</subject><subject>Stainless steel</subject><subject>Substrates</subject><subject>Surface analysis (chemical)</subject><issn>0300-9440</issn><issn>1873-331X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkMFKAzEQhoMoWKuvIAued50kazZ7U4pWoeBFwVvITmZLlrqpybbg25tSPXsYBmb--WfmY-yaQ8WBq9uh2oa4xmCnSgDXFTQVSDhhM64bWUrJP07ZLFegbOsaztlFSgMAKCnbGdOLEGNIPozlNoaJcPJ7Kg5mflynorOJXBHGot_sQgxoY5fFGzvSJTvr7SbR1W-es_enx7fFc7l6Xb4sHlYlyqaZSnTEnUaBMgc6FB1H7TrVOsEbgb3G3Ba2V5rAOWx5o1C4Xkly2jogOWc3R9983teO0mSGsItjXmkEF3WtgMu7rFJHFeZnUqTebKP_tPHbcDAHSmYwf5TMgZKBxmQmefD-OEj5h72naBJ6GpGcjxmGccH_Z_EDAKV2IQ</recordid><startdate>20181001</startdate><enddate>20181001</enddate><creator>Szubert, Karol</creator><creator>Wojciechowski, Jarosław</creator><creator>Karasiewicz, Joanna</creator><creator>Maciejewski, Hieronim</creator><creator>Lota, Grzegorz</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20181001</creationdate><title>Corrosion-protective coatings based on fluorocarbosilane</title><author>Szubert, Karol ; Wojciechowski, Jarosław ; Karasiewicz, Joanna ; Maciejewski, Hieronim ; Lota, Grzegorz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-cde1d8c2c3c2ccdc2b1c8db69d2172cf8c1d82af68e0ddc9176c2df63ed8ad0e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Anhydrous deposition</topic><topic>Aqueous environments</topic><topic>Austenitic stainless steels</topic><topic>Coating effects</topic><topic>Corrosion</topic><topic>Corrosion effects</topic><topic>Covalent bonds</topic><topic>Fluorination</topic><topic>Fluorocarbosilane</topic><topic>Protective coatings</topic><topic>Silanes</topic><topic>Silicon</topic><topic>Silicon steels</topic><topic>Sonication</topic><topic>Stainless steel</topic><topic>Substrates</topic><topic>Surface analysis (chemical)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Szubert, Karol</creatorcontrib><creatorcontrib>Wojciechowski, Jarosław</creatorcontrib><creatorcontrib>Karasiewicz, Joanna</creatorcontrib><creatorcontrib>Maciejewski, Hieronim</creatorcontrib><creatorcontrib>Lota, Grzegorz</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Progress in organic coatings</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Szubert, Karol</au><au>Wojciechowski, Jarosław</au><au>Karasiewicz, Joanna</au><au>Maciejewski, Hieronim</au><au>Lota, Grzegorz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Corrosion-protective coatings based on fluorocarbosilane</atitle><jtitle>Progress in organic coatings</jtitle><date>2018-10-01</date><risdate>2018</risdate><volume>123</volume><spage>374</spage><epage>383</epage><pages>374-383</pages><issn>0300-9440</issn><eissn>1873-331X</eissn><abstract>[Display omitted]
•Fluorocarbosiloxane coating inhibits the corrosion process of 304 stainless steel.•MetalOSi covalent bonds are created between steel surface and fluorocarbosilane.•Well-developed chains consisting of SiOSi bonds have been created.
This study discusses the effect of 3-(1,1,2,2,3,3,4,4-octafluoropentyloxy)propyltriethoxysilane (OFTES) based coatings on the anti-corrosive properties of 304 type stainless steel, which has not been described to date. The coatings were deposited from methanol using the anhydrous deposition method and influence of the sonication on this process has also been investigated. Anti-corrosive properties of modified and unmodified steel surfaces have been characterized by electrochemical and surface analysis methods. Since silicon is an element capable of forming bonds with both organic and inorganic substrates, these features allow to combine organofunctional silanes with metal as well as steel surfaces through metalOSi covalent bonds. A fluorinated alkyl chain, which is attached to the silicon atom, forms an effective barrier against an aggressive aqueous environment.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.porgcoat.2018.07.030</doi><tpages>10</tpages></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | Anhydrous deposition Aqueous environments Austenitic stainless steels Coating effects Corrosion Corrosion effects Covalent bonds Fluorination Fluorocarbosilane Protective coatings Silanes Silicon Silicon steels Sonication Stainless steel Substrates Surface analysis (chemical) |
| title | Corrosion-protective coatings based on fluorocarbosilane |
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