Polymeric Copper Oxide: Preparation and Investigation of Its Structure and Optical Properties
A complex of polyvinyl alcohol (PVA) with copper hydroxide was used as a precursor to obtain polymeric copper oxide through thermal decomposition. The absence of Cu(OH) 2 crystalline phase was observed for the component ratio up to 1 Cu(OH) 2 molecular unit to 3 PVA residuals. The formation of cryst...
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2018-11, Vol.28 (6), p.2328-2335 |
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| container_title | Journal of inorganic and organometallic polymers and materials |
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| creator | Prosanov, I. Yu Benassi, E. Bulina, N. V. Matvienko, A. A. Gerasimov, K. B. Sidelnikov, A. A. |
| description | A complex of polyvinyl alcohol (PVA) with copper hydroxide was used as a precursor to obtain polymeric copper oxide through thermal decomposition. The absence of Cu(OH)
2
crystalline phase was observed for the component ratio up to 1 Cu(OH)
2
molecular unit to 3 PVA residuals. The formation of crystalline copper oxide was not observed after the dehydration of this material. UV–VIS and IR spectroscopy, and computational modeling were used to study the structure and properties of the obtained materials. A comparison with other similar materials was drawn. It was found that experimental data are in general accordance with the computations based on the polymeric model for copper hydroxide/oxide as a component of hybrid interpolymeric complex with PVA. A distinctive feature observed for polymeric copper oxide is strong broadening of the optical absorption band at 400 nm. It is suggested that this effect is caused by strong electron–phonon interaction, which is also responsible for superconductivity of copper oxide based systems. |
| doi_str_mv | 10.1007/s10904-018-0897-5 |
| format | Article |
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2
crystalline phase was observed for the component ratio up to 1 Cu(OH)
2
molecular unit to 3 PVA residuals. The formation of crystalline copper oxide was not observed after the dehydration of this material. UV–VIS and IR spectroscopy, and computational modeling were used to study the structure and properties of the obtained materials. A comparison with other similar materials was drawn. It was found that experimental data are in general accordance with the computations based on the polymeric model for copper hydroxide/oxide as a component of hybrid interpolymeric complex with PVA. A distinctive feature observed for polymeric copper oxide is strong broadening of the optical absorption band at 400 nm. It is suggested that this effect is caused by strong electron–phonon interaction, which is also responsible for superconductivity of copper oxide based systems.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-018-0897-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Absorption spectra ; Chemistry ; Chemistry and Materials Science ; Copper ; Copper oxides ; Crystal structure ; Crystallinity ; Dehydration ; Infrared spectroscopy ; Inorganic Chemistry ; Optical properties ; Organic Chemistry ; Polymer Sciences ; Polyvinyl alcohol ; Prepolymers ; Superconductivity ; Superconductors ; Thermal decomposition</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2018-11, Vol.28 (6), p.2328-2335</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c305t-cb1e2b8c672d6499b3cafcb25b98397f9123fae912adc353792a1af221a7c2ae3</cites><orcidid>0000-0002-8678-3565</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-018-0897-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-018-0897-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27902,27903,41466,42535,51296</link.rule.ids></links><search><creatorcontrib>Prosanov, I. Yu</creatorcontrib><creatorcontrib>Benassi, E.</creatorcontrib><creatorcontrib>Bulina, N. V.</creatorcontrib><creatorcontrib>Matvienko, A. A.</creatorcontrib><creatorcontrib>Gerasimov, K. B.</creatorcontrib><creatorcontrib>Sidelnikov, A. A.</creatorcontrib><title>Polymeric Copper Oxide: Preparation and Investigation of Its Structure and Optical Properties</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>A complex of polyvinyl alcohol (PVA) with copper hydroxide was used as a precursor to obtain polymeric copper oxide through thermal decomposition. The absence of Cu(OH)
2
crystalline phase was observed for the component ratio up to 1 Cu(OH)
2
molecular unit to 3 PVA residuals. The formation of crystalline copper oxide was not observed after the dehydration of this material. UV–VIS and IR spectroscopy, and computational modeling were used to study the structure and properties of the obtained materials. A comparison with other similar materials was drawn. It was found that experimental data are in general accordance with the computations based on the polymeric model for copper hydroxide/oxide as a component of hybrid interpolymeric complex with PVA. A distinctive feature observed for polymeric copper oxide is strong broadening of the optical absorption band at 400 nm. It is suggested that this effect is caused by strong electron–phonon interaction, which is also responsible for superconductivity of copper oxide based systems.</description><subject>Absorption spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copper</subject><subject>Copper oxides</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Dehydration</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Optical properties</subject><subject>Organic Chemistry</subject><subject>Polymer Sciences</subject><subject>Polyvinyl alcohol</subject><subject>Prepolymers</subject><subject>Superconductivity</subject><subject>Superconductors</subject><subject>Thermal decomposition</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kF9LwzAUxYMoOKcfwLeCz9XcpFka32T4ZzDoQH2UkKbpyNiamqTivr2ZFX3y6Vwuv3Pu5SB0CfgaMOY3AbDARY6hzHEpeM6O0AQYL3IoGBz_zgU9RWchbDCmJWYwQW8rt93vjLc6m7u-Nz6rPm1jbrOVN73yKlrXZaprskX3YUK063Hj2mwRQ_Yc_aDj4M03UvXRarVNVpeCojXhHJ20ahvMxY9O0evD_cv8KV9Wj4v53TLXFLOY6xoMqUs946SZFULUVKtW14TVoqSCtwIIbZVJohpNGeWCKFAtIaC4JsrQKboac3vv3of0p9y4wXfppCRAChDAGSQKRkp7F4I3rey93Sm_l4DloUU5tihTi_LQomTJQ0ZPSGy3Nv4v-X_TFzPkdb4</recordid><startdate>20181101</startdate><enddate>20181101</enddate><creator>Prosanov, I. Yu</creator><creator>Benassi, E.</creator><creator>Bulina, N. V.</creator><creator>Matvienko, A. A.</creator><creator>Gerasimov, K. B.</creator><creator>Sidelnikov, A. A.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-8678-3565</orcidid></search><sort><creationdate>20181101</creationdate><title>Polymeric Copper Oxide: Preparation and Investigation of Its Structure and Optical Properties</title><author>Prosanov, I. Yu ; Benassi, E. ; Bulina, N. V. ; Matvienko, A. A. ; Gerasimov, K. B. ; Sidelnikov, A. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c305t-cb1e2b8c672d6499b3cafcb25b98397f9123fae912adc353792a1af221a7c2ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Absorption spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copper</topic><topic>Copper oxides</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Dehydration</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Optical properties</topic><topic>Organic Chemistry</topic><topic>Polymer Sciences</topic><topic>Polyvinyl alcohol</topic><topic>Prepolymers</topic><topic>Superconductivity</topic><topic>Superconductors</topic><topic>Thermal decomposition</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Prosanov, I. Yu</creatorcontrib><creatorcontrib>Benassi, E.</creatorcontrib><creatorcontrib>Bulina, N. V.</creatorcontrib><creatorcontrib>Matvienko, A. A.</creatorcontrib><creatorcontrib>Gerasimov, K. B.</creatorcontrib><creatorcontrib>Sidelnikov, A. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Prosanov, I. Yu</au><au>Benassi, E.</au><au>Bulina, N. V.</au><au>Matvienko, A. A.</au><au>Gerasimov, K. B.</au><au>Sidelnikov, A. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymeric Copper Oxide: Preparation and Investigation of Its Structure and Optical Properties</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2018-11-01</date><risdate>2018</risdate><volume>28</volume><issue>6</issue><spage>2328</spage><epage>2335</epage><pages>2328-2335</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>A complex of polyvinyl alcohol (PVA) with copper hydroxide was used as a precursor to obtain polymeric copper oxide through thermal decomposition. The absence of Cu(OH)
2
crystalline phase was observed for the component ratio up to 1 Cu(OH)
2
molecular unit to 3 PVA residuals. The formation of crystalline copper oxide was not observed after the dehydration of this material. UV–VIS and IR spectroscopy, and computational modeling were used to study the structure and properties of the obtained materials. A comparison with other similar materials was drawn. It was found that experimental data are in general accordance with the computations based on the polymeric model for copper hydroxide/oxide as a component of hybrid interpolymeric complex with PVA. A distinctive feature observed for polymeric copper oxide is strong broadening of the optical absorption band at 400 nm. It is suggested that this effect is caused by strong electron–phonon interaction, which is also responsible for superconductivity of copper oxide based systems.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-018-0897-5</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-8678-3565</orcidid></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Absorption spectra Chemistry Chemistry and Materials Science Copper Copper oxides Crystal structure Crystallinity Dehydration Infrared spectroscopy Inorganic Chemistry Optical properties Organic Chemistry Polymer Sciences Polyvinyl alcohol Prepolymers Superconductivity Superconductors Thermal decomposition |
| title | Polymeric Copper Oxide: Preparation and Investigation of Its Structure and Optical Properties |
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