Stepwise post‐modification immobilization of palladium Schiff‐base complex on to the OMS‐Cu (BDC) metal–organic framework for Mizoroki‐Heck cross‐coupling reaction
Palladium ions were successfully immobilized within the pores of open metal site (OMS) metal organic frameworks (MOFs) with Schiff‐base (2‐Py‐SI) grafted in OMS‐Cu (BDC) using the hydrothermal method. This Schiff‐base complex on the Cu (BDC) greatly increased catalytic activity and acted as an effic...
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| Veröffentlicht in: | Applied organometallic chemistry 2018-11, Vol.32 (11), p.n/a |
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| container_title | Applied organometallic chemistry |
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| creator | Alamgholiloo, Hassan Rostamnia, Sadegh Hassankhani, Asadollah Khalafy, Jabbar Baradarani, Mehdi M. Mahmoudi, Ghodrat Liu, Xiao |
| description | Palladium ions were successfully immobilized within the pores of open metal site (OMS) metal organic frameworks (MOFs) with Schiff‐base (2‐Py‐SI) grafted in OMS‐Cu (BDC) using the hydrothermal method. This Schiff‐base complex on the Cu (BDC) greatly increased catalytic activity and acted as an efficient stabilizer of Pd ions. The hydrothermal method was a more efficient method for generating small metal ions in the MOF structures. The results revealed that the PdII@Cu (BDC)/2‐Py‐SI is a promising catalyst for the Mizoroki‐Heck coupling reaction. The proposed catalyst has better recyclability and can be reused several times without apparent loss of activity.
Modification of Cu (BDC) MOF toward the direct grafting of pyridyl salicylimine (2‐Py‐SI) and complexation of that with Pd ions was investigated. The synthesized PdII@Cu (BDC)/2‐Py‐SI MOF was then applied to Mizoroki‐Heck reaction. |
| doi_str_mv | 10.1002/aoc.4539 |
| format | Article |
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Modification of Cu (BDC) MOF toward the direct grafting of pyridyl salicylimine (2‐Py‐SI) and complexation of that with Pd ions was investigated. The synthesized PdII@Cu (BDC)/2‐Py‐SI MOF was then applied to Mizoroki‐Heck reaction.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.4539</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>Catalysis ; Catalysts ; Catalytic activity ; Chemistry ; Copper ; Coupling ; Metal-organic frameworks ; Metals ; Mizoroki‐Heck reaction ; open metal site MOF ; Palladium ; PdII@Cu (BDC)/2‐Py‐SI ; Recyclability</subject><ispartof>Applied organometallic chemistry, 2018-11, Vol.32 (11), p.n/a</ispartof><rights>2018 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3309-e095d5590fb100f9fbe24a10818ffb81f2aaea06604acbb1501b0788626c29443</citedby><cites>FETCH-LOGICAL-c3309-e095d5590fb100f9fbe24a10818ffb81f2aaea06604acbb1501b0788626c29443</cites><orcidid>0000-0001-6310-8754</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.4539$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.4539$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Alamgholiloo, Hassan</creatorcontrib><creatorcontrib>Rostamnia, Sadegh</creatorcontrib><creatorcontrib>Hassankhani, Asadollah</creatorcontrib><creatorcontrib>Khalafy, Jabbar</creatorcontrib><creatorcontrib>Baradarani, Mehdi M.</creatorcontrib><creatorcontrib>Mahmoudi, Ghodrat</creatorcontrib><creatorcontrib>Liu, Xiao</creatorcontrib><title>Stepwise post‐modification immobilization of palladium Schiff‐base complex on to the OMS‐Cu (BDC) metal–organic framework for Mizoroki‐Heck cross‐coupling reaction</title><title>Applied organometallic chemistry</title><description>Palladium ions were successfully immobilized within the pores of open metal site (OMS) metal organic frameworks (MOFs) with Schiff‐base (2‐Py‐SI) grafted in OMS‐Cu (BDC) using the hydrothermal method. This Schiff‐base complex on the Cu (BDC) greatly increased catalytic activity and acted as an efficient stabilizer of Pd ions. The hydrothermal method was a more efficient method for generating small metal ions in the MOF structures. The results revealed that the PdII@Cu (BDC)/2‐Py‐SI is a promising catalyst for the Mizoroki‐Heck coupling reaction. The proposed catalyst has better recyclability and can be reused several times without apparent loss of activity.
Modification of Cu (BDC) MOF toward the direct grafting of pyridyl salicylimine (2‐Py‐SI) and complexation of that with Pd ions was investigated. The synthesized PdII@Cu (BDC)/2‐Py‐SI MOF was then applied to Mizoroki‐Heck reaction.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Copper</subject><subject>Coupling</subject><subject>Metal-organic frameworks</subject><subject>Metals</subject><subject>Mizoroki‐Heck reaction</subject><subject>open metal site MOF</subject><subject>Palladium</subject><subject>PdII@Cu (BDC)/2‐Py‐SI</subject><subject>Recyclability</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kU1OwzAQhS0EEqUgcQRLbGCRMnZ-Gi8h_BQJ1EVhHTmuDaZJJziJCl31CEgchDv1JLiULavRaL438zSPkGMGAwbAzyWqQRSHYof0GAgRwDAUu6QHPEkDnkC8Tw6a5hUARMKiHvmetLpe2EbTGpt2vfqscGqNVbK1OKe2qrCwpV1uWzS0lmUpp7ar6ES9WGO8opBerbCqS_1OPdUibV80HT9M_DDr6OnlVXZGK93Kcr36Qvcs51ZR42SlF-hm1KCjD3aJDmfWK0Zazahy2DS-UdjVpZ0_U6el2ng4JHtGlo0--qt98nRz_ZiNgvvx7V12cR-oMAQRaBDxNI4FmMJ_xQhTaB5JBilLjSlSZriUWkKSQCRVUbAYWAHDNE14oriIorBPTrZ7a4dvnW7a_BU7N_cnc854BPEwjUJPnW6pX79Om7x2tpLuI2eQb-LIfRz5Jg6PBlt0YUv98S-XX4yzX_4HoUKULg</recordid><startdate>201811</startdate><enddate>201811</enddate><creator>Alamgholiloo, Hassan</creator><creator>Rostamnia, Sadegh</creator><creator>Hassankhani, Asadollah</creator><creator>Khalafy, Jabbar</creator><creator>Baradarani, Mehdi M.</creator><creator>Mahmoudi, Ghodrat</creator><creator>Liu, Xiao</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-6310-8754</orcidid></search><sort><creationdate>201811</creationdate><title>Stepwise post‐modification immobilization of palladium Schiff‐base complex on to the OMS‐Cu (BDC) metal–organic framework for Mizoroki‐Heck cross‐coupling reaction</title><author>Alamgholiloo, Hassan ; Rostamnia, Sadegh ; Hassankhani, Asadollah ; Khalafy, Jabbar ; Baradarani, Mehdi M. ; Mahmoudi, Ghodrat ; Liu, Xiao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3309-e095d5590fb100f9fbe24a10818ffb81f2aaea06604acbb1501b0788626c29443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Copper</topic><topic>Coupling</topic><topic>Metal-organic frameworks</topic><topic>Metals</topic><topic>Mizoroki‐Heck reaction</topic><topic>open metal site MOF</topic><topic>Palladium</topic><topic>PdII@Cu (BDC)/2‐Py‐SI</topic><topic>Recyclability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alamgholiloo, Hassan</creatorcontrib><creatorcontrib>Rostamnia, Sadegh</creatorcontrib><creatorcontrib>Hassankhani, Asadollah</creatorcontrib><creatorcontrib>Khalafy, Jabbar</creatorcontrib><creatorcontrib>Baradarani, Mehdi M.</creatorcontrib><creatorcontrib>Mahmoudi, Ghodrat</creatorcontrib><creatorcontrib>Liu, Xiao</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alamgholiloo, Hassan</au><au>Rostamnia, Sadegh</au><au>Hassankhani, Asadollah</au><au>Khalafy, Jabbar</au><au>Baradarani, Mehdi M.</au><au>Mahmoudi, Ghodrat</au><au>Liu, Xiao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stepwise post‐modification immobilization of palladium Schiff‐base complex on to the OMS‐Cu (BDC) metal–organic framework for Mizoroki‐Heck cross‐coupling reaction</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2018-11</date><risdate>2018</risdate><volume>32</volume><issue>11</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>Palladium ions were successfully immobilized within the pores of open metal site (OMS) metal organic frameworks (MOFs) with Schiff‐base (2‐Py‐SI) grafted in OMS‐Cu (BDC) using the hydrothermal method. This Schiff‐base complex on the Cu (BDC) greatly increased catalytic activity and acted as an efficient stabilizer of Pd ions. The hydrothermal method was a more efficient method for generating small metal ions in the MOF structures. The results revealed that the PdII@Cu (BDC)/2‐Py‐SI is a promising catalyst for the Mizoroki‐Heck coupling reaction. The proposed catalyst has better recyclability and can be reused several times without apparent loss of activity.
Modification of Cu (BDC) MOF toward the direct grafting of pyridyl salicylimine (2‐Py‐SI) and complexation of that with Pd ions was investigated. The synthesized PdII@Cu (BDC)/2‐Py‐SI MOF was then applied to Mizoroki‐Heck reaction.</abstract><cop>Chichester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aoc.4539</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-6310-8754</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Catalysis Catalysts Catalytic activity Chemistry Copper Coupling Metal-organic frameworks Metals Mizoroki‐Heck reaction open metal site MOF Palladium PdII@Cu (BDC)/2‐Py‐SI Recyclability |
| title | Stepwise post‐modification immobilization of palladium Schiff‐base complex on to the OMS‐Cu (BDC) metal–organic framework for Mizoroki‐Heck cross‐coupling reaction |
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