Discrimination of molecular thin films by surface-sensitive time-resolved optical spectroscopy

An optical discrimination technique, tailored to nanometric-sized, low optical absorbance molecular complexes adhering to thin metal films, is proposed and demonstrated. It is based on a time-resolved evanescent-wave detection scheme in conjunction with hierarchical cluster analysis and principal va...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Applied physics letters 2015-10, Vol.107 (16)
Hauptverfasser: Peli, Simone, Nembrini, Nicola, Damin, Francesco, Chiari, Marcella, Giannetti, Claudio, Banfi, Francesco, Ferrini, Gabriele
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue 16
container_start_page
container_title Applied physics letters
container_volume 107
creator Peli, Simone
Nembrini, Nicola
Damin, Francesco
Chiari, Marcella
Giannetti, Claudio
Banfi, Francesco
Ferrini, Gabriele
description An optical discrimination technique, tailored to nanometric-sized, low optical absorbance molecular complexes adhering to thin metal films, is proposed and demonstrated. It is based on a time-resolved evanescent-wave detection scheme in conjunction with hierarchical cluster analysis and principal value decomposition. The present approach aims to differentiate among molecular films based on statistical methods, without using previous detailed knowledge of the physical mechanisms responsible for the detected signal. The technique is open to integration in lab-on-a-chip architectures and nanoscopy platforms for applications ranging from medical screening to material diagnostics.
doi_str_mv 10.1063/1.4934216
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2123863824</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2123863824</sourcerecordid><originalsourceid>FETCH-LOGICAL-c292t-e65d9e7a3712f7a4c1c769a6096973bfcfc2dba9d47ff42dacc92e46d18316373</originalsourceid><addsrcrecordid>eNotUM1LwzAcDaLgnB78DwKePGTml3RJc5T5CQMvejWkaYIZbVOTdLD_3sp2ejx4vC-EboGugAr-AKtK8YqBOEMLoFISDlCfowWllBOh1nCJrnLezXTNOF-g76eQbQp9GEwJccDR4z52zk6dSbj8hAH70PUZNwecp-SNdSS7IYcS9g6X0DuSXI7d3rU4jiVY0-E8OltSzDaOh2t04U2X3c0Jl-jr5flz80a2H6_vm8ctsUyxQpxYt8pJwyUwL01lwUqhjKBKKMkbb71lbWNUW0nvK9YaaxVzlWih5iC45Et0d_QdU_ydXC56F6c0zJGaAeO14DWrZtX9UWXnejk5r8d5ukkHDVT_36dBn-7jfzY4Y34</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2123863824</pqid></control><display><type>article</type><title>Discrimination of molecular thin films by surface-sensitive time-resolved optical spectroscopy</title><source>AIP Journals Complete</source><source>Alma/SFX Local Collection</source><creator>Peli, Simone ; Nembrini, Nicola ; Damin, Francesco ; Chiari, Marcella ; Giannetti, Claudio ; Banfi, Francesco ; Ferrini, Gabriele</creator><creatorcontrib>Peli, Simone ; Nembrini, Nicola ; Damin, Francesco ; Chiari, Marcella ; Giannetti, Claudio ; Banfi, Francesco ; Ferrini, Gabriele</creatorcontrib><description>An optical discrimination technique, tailored to nanometric-sized, low optical absorbance molecular complexes adhering to thin metal films, is proposed and demonstrated. It is based on a time-resolved evanescent-wave detection scheme in conjunction with hierarchical cluster analysis and principal value decomposition. The present approach aims to differentiate among molecular films based on statistical methods, without using previous detailed knowledge of the physical mechanisms responsible for the detected signal. The technique is open to integration in lab-on-a-chip architectures and nanoscopy platforms for applications ranging from medical screening to material diagnostics.</description><identifier>ISSN: 0003-6951</identifier><identifier>EISSN: 1077-3118</identifier><identifier>DOI: 10.1063/1.4934216</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Applied physics ; Cluster analysis ; Coordination compounds ; Discrimination ; Medical materials ; Medical screening ; Metal films ; Statistical methods ; Thin films</subject><ispartof>Applied physics letters, 2015-10, Vol.107 (16)</ispartof><rights>2015 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c292t-e65d9e7a3712f7a4c1c769a6096973bfcfc2dba9d47ff42dacc92e46d18316373</citedby><cites>FETCH-LOGICAL-c292t-e65d9e7a3712f7a4c1c769a6096973bfcfc2dba9d47ff42dacc92e46d18316373</cites><orcidid>0000-0002-7465-8417</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Peli, Simone</creatorcontrib><creatorcontrib>Nembrini, Nicola</creatorcontrib><creatorcontrib>Damin, Francesco</creatorcontrib><creatorcontrib>Chiari, Marcella</creatorcontrib><creatorcontrib>Giannetti, Claudio</creatorcontrib><creatorcontrib>Banfi, Francesco</creatorcontrib><creatorcontrib>Ferrini, Gabriele</creatorcontrib><title>Discrimination of molecular thin films by surface-sensitive time-resolved optical spectroscopy</title><title>Applied physics letters</title><description>An optical discrimination technique, tailored to nanometric-sized, low optical absorbance molecular complexes adhering to thin metal films, is proposed and demonstrated. It is based on a time-resolved evanescent-wave detection scheme in conjunction with hierarchical cluster analysis and principal value decomposition. The present approach aims to differentiate among molecular films based on statistical methods, without using previous detailed knowledge of the physical mechanisms responsible for the detected signal. The technique is open to integration in lab-on-a-chip architectures and nanoscopy platforms for applications ranging from medical screening to material diagnostics.</description><subject>Applied physics</subject><subject>Cluster analysis</subject><subject>Coordination compounds</subject><subject>Discrimination</subject><subject>Medical materials</subject><subject>Medical screening</subject><subject>Metal films</subject><subject>Statistical methods</subject><subject>Thin films</subject><issn>0003-6951</issn><issn>1077-3118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNotUM1LwzAcDaLgnB78DwKePGTml3RJc5T5CQMvejWkaYIZbVOTdLD_3sp2ejx4vC-EboGugAr-AKtK8YqBOEMLoFISDlCfowWllBOh1nCJrnLezXTNOF-g76eQbQp9GEwJccDR4z52zk6dSbj8hAH70PUZNwecp-SNdSS7IYcS9g6X0DuSXI7d3rU4jiVY0-E8OltSzDaOh2t04U2X3c0Jl-jr5flz80a2H6_vm8ctsUyxQpxYt8pJwyUwL01lwUqhjKBKKMkbb71lbWNUW0nvK9YaaxVzlWih5iC45Et0d_QdU_ydXC56F6c0zJGaAeO14DWrZtX9UWXnejk5r8d5ukkHDVT_36dBn-7jfzY4Y34</recordid><startdate>20151019</startdate><enddate>20151019</enddate><creator>Peli, Simone</creator><creator>Nembrini, Nicola</creator><creator>Damin, Francesco</creator><creator>Chiari, Marcella</creator><creator>Giannetti, Claudio</creator><creator>Banfi, Francesco</creator><creator>Ferrini, Gabriele</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-7465-8417</orcidid></search><sort><creationdate>20151019</creationdate><title>Discrimination of molecular thin films by surface-sensitive time-resolved optical spectroscopy</title><author>Peli, Simone ; Nembrini, Nicola ; Damin, Francesco ; Chiari, Marcella ; Giannetti, Claudio ; Banfi, Francesco ; Ferrini, Gabriele</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c292t-e65d9e7a3712f7a4c1c769a6096973bfcfc2dba9d47ff42dacc92e46d18316373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Applied physics</topic><topic>Cluster analysis</topic><topic>Coordination compounds</topic><topic>Discrimination</topic><topic>Medical materials</topic><topic>Medical screening</topic><topic>Metal films</topic><topic>Statistical methods</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peli, Simone</creatorcontrib><creatorcontrib>Nembrini, Nicola</creatorcontrib><creatorcontrib>Damin, Francesco</creatorcontrib><creatorcontrib>Chiari, Marcella</creatorcontrib><creatorcontrib>Giannetti, Claudio</creatorcontrib><creatorcontrib>Banfi, Francesco</creatorcontrib><creatorcontrib>Ferrini, Gabriele</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied physics letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peli, Simone</au><au>Nembrini, Nicola</au><au>Damin, Francesco</au><au>Chiari, Marcella</au><au>Giannetti, Claudio</au><au>Banfi, Francesco</au><au>Ferrini, Gabriele</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Discrimination of molecular thin films by surface-sensitive time-resolved optical spectroscopy</atitle><jtitle>Applied physics letters</jtitle><date>2015-10-19</date><risdate>2015</risdate><volume>107</volume><issue>16</issue><issn>0003-6951</issn><eissn>1077-3118</eissn><abstract>An optical discrimination technique, tailored to nanometric-sized, low optical absorbance molecular complexes adhering to thin metal films, is proposed and demonstrated. It is based on a time-resolved evanescent-wave detection scheme in conjunction with hierarchical cluster analysis and principal value decomposition. The present approach aims to differentiate among molecular films based on statistical methods, without using previous detailed knowledge of the physical mechanisms responsible for the detected signal. The technique is open to integration in lab-on-a-chip architectures and nanoscopy platforms for applications ranging from medical screening to material diagnostics.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.4934216</doi><orcidid>https://orcid.org/0000-0002-7465-8417</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0003-6951
ispartof Applied physics letters, 2015-10, Vol.107 (16)
issn 0003-6951
1077-3118
language eng
recordid cdi_proquest_journals_2123863824
source AIP Journals Complete; Alma/SFX Local Collection
subjects Applied physics
Cluster analysis
Coordination compounds
Discrimination
Medical materials
Medical screening
Metal films
Statistical methods
Thin films
title Discrimination of molecular thin films by surface-sensitive time-resolved optical spectroscopy
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T11%3A52%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Discrimination%20of%20molecular%20thin%20films%20by%20surface-sensitive%20time-resolved%20optical%20spectroscopy&rft.jtitle=Applied%20physics%20letters&rft.au=Peli,%20Simone&rft.date=2015-10-19&rft.volume=107&rft.issue=16&rft.issn=0003-6951&rft.eissn=1077-3118&rft_id=info:doi/10.1063/1.4934216&rft_dat=%3Cproquest_cross%3E2123863824%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2123863824&rft_id=info:pmid/&rfr_iscdi=true