Composition- and pressure-induced ferroelectric to antiferroelectric phase transitions in Sm-doped BiFeO3 system

A three-dimensional phenomenological model is proposed to describe both ferroelectricity and antiferroelectricity based on the Ginzburg-Landau-Devonshire theory. Its application to the multiferroic Sm-doped BiFeO3 system describes the temperature-, pressure-, and composition-induced ferroelectric to...

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Veröffentlicht in:Applied physics letters 2015-01, Vol.106 (1)
Hauptverfasser: Xue, Fei, Liang, Linyun, Gu, Yijia, Takeuchi, Ichiro, Kalinin, Sergei V., Chen, Long-Qing
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Liang, Linyun
Gu, Yijia
Takeuchi, Ichiro
Kalinin, Sergei V.
Chen, Long-Qing
description A three-dimensional phenomenological model is proposed to describe both ferroelectricity and antiferroelectricity based on the Ginzburg-Landau-Devonshire theory. Its application to the multiferroic Sm-doped BiFeO3 system describes the temperature-, pressure-, and composition-induced ferroelectric to antiferroelectric phase transitions. The constructed temperature-composition and temperature-pressure phase diagrams show that compressive hydrostatic pressure and Sm doping have similar effects on the ferroelectric and antiferroelectric phase transitions. It is also indicated from the temperature-pressure phase diagram that the experimentally observed phase of BiFeO3 under the hydrostatic pressure from 3 GPa to 10 GPa is a PbZrO3-like antiferroelectric phase.
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subjects Antiferroelectricity
Applied physics
Bismuth ferrite
Composition
Ferroelectric materials
Ferroelectricity
Hydrostatic pressure
Phase diagrams
Phase transitions
Three dimensional models
title Composition- and pressure-induced ferroelectric to antiferroelectric phase transitions in Sm-doped BiFeO3 system
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