Composition- and pressure-induced ferroelectric to antiferroelectric phase transitions in Sm-doped BiFeO3 system
A three-dimensional phenomenological model is proposed to describe both ferroelectricity and antiferroelectricity based on the Ginzburg-Landau-Devonshire theory. Its application to the multiferroic Sm-doped BiFeO3 system describes the temperature-, pressure-, and composition-induced ferroelectric to...
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Veröffentlicht in: | Applied physics letters 2015-01, Vol.106 (1) |
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creator | Xue, Fei Liang, Linyun Gu, Yijia Takeuchi, Ichiro Kalinin, Sergei V. Chen, Long-Qing |
description | A three-dimensional phenomenological model is proposed to describe both ferroelectricity and antiferroelectricity based on the Ginzburg-Landau-Devonshire theory. Its application to the multiferroic Sm-doped BiFeO3 system describes the temperature-, pressure-, and composition-induced ferroelectric to antiferroelectric phase transitions. The constructed temperature-composition and temperature-pressure phase diagrams show that compressive hydrostatic pressure and Sm doping have similar effects on the ferroelectric and antiferroelectric phase transitions. It is also indicated from the temperature-pressure phase diagram that the experimentally observed phase of BiFeO3 under the hydrostatic pressure from 3 GPa to 10 GPa is a PbZrO3-like antiferroelectric phase. |
doi_str_mv | 10.1063/1.4905444 |
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Its application to the multiferroic Sm-doped BiFeO3 system describes the temperature-, pressure-, and composition-induced ferroelectric to antiferroelectric phase transitions. The constructed temperature-composition and temperature-pressure phase diagrams show that compressive hydrostatic pressure and Sm doping have similar effects on the ferroelectric and antiferroelectric phase transitions. It is also indicated from the temperature-pressure phase diagram that the experimentally observed phase of BiFeO3 under the hydrostatic pressure from 3 GPa to 10 GPa is a PbZrO3-like antiferroelectric phase.</description><identifier>ISSN: 0003-6951</identifier><identifier>EISSN: 1077-3118</identifier><identifier>DOI: 10.1063/1.4905444</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Antiferroelectricity ; Applied physics ; Bismuth ferrite ; Composition ; Ferroelectric materials ; Ferroelectricity ; Hydrostatic pressure ; Phase diagrams ; Phase transitions ; Three dimensional models</subject><ispartof>Applied physics letters, 2015-01, Vol.106 (1)</ispartof><rights>2015 AIP Publishing LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c323t-ffe732251885b21d995d65b62752f36e93b64dd7ad57a8c74b97c443c959d2f83</citedby><cites>FETCH-LOGICAL-c323t-ffe732251885b21d995d65b62752f36e93b64dd7ad57a8c74b97c443c959d2f83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Xue, Fei</creatorcontrib><creatorcontrib>Liang, Linyun</creatorcontrib><creatorcontrib>Gu, Yijia</creatorcontrib><creatorcontrib>Takeuchi, Ichiro</creatorcontrib><creatorcontrib>Kalinin, Sergei V.</creatorcontrib><creatorcontrib>Chen, Long-Qing</creatorcontrib><title>Composition- and pressure-induced ferroelectric to antiferroelectric phase transitions in Sm-doped BiFeO3 system</title><title>Applied physics letters</title><description>A three-dimensional phenomenological model is proposed to describe both ferroelectricity and antiferroelectricity based on the Ginzburg-Landau-Devonshire theory. Its application to the multiferroic Sm-doped BiFeO3 system describes the temperature-, pressure-, and composition-induced ferroelectric to antiferroelectric phase transitions. The constructed temperature-composition and temperature-pressure phase diagrams show that compressive hydrostatic pressure and Sm doping have similar effects on the ferroelectric and antiferroelectric phase transitions. It is also indicated from the temperature-pressure phase diagram that the experimentally observed phase of BiFeO3 under the hydrostatic pressure from 3 GPa to 10 GPa is a PbZrO3-like antiferroelectric phase.</description><subject>Antiferroelectricity</subject><subject>Applied physics</subject><subject>Bismuth ferrite</subject><subject>Composition</subject><subject>Ferroelectric materials</subject><subject>Ferroelectricity</subject><subject>Hydrostatic pressure</subject><subject>Phase diagrams</subject><subject>Phase transitions</subject><subject>Three dimensional models</subject><issn>0003-6951</issn><issn>1077-3118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpVkMFKAzEURYMoWKsL_yDgykU0yUsmyVKLVaHQhboeZpIMpnQmY5JZ9O8daTeuLu9yOA8uQreMPjBawSN7EIZKIcQZWjCqFAHG9DlaUEqBVEayS3SV824-JQdYoHEV-zHmUEIcCG4Gh8fkc56SJ2Fwk_UOdz6l6PfelhQsLnGmSvhfjt9N9rikZjiaMg4D_uiJi-MseA5rvwWcD7n4_hpddM0--5tTLtHX-uVz9UY229f31dOGWOBQSNd5BZxLprVsOXPGSFfJtuJK8g4qb6CthHOqcVI12irRGmWFAGukcbzTsER3R--Y4s_kc6l3cUrD_LLmjIMWmho2U_dHyqaYc_JdPabQN-lQM1r_DVqz-jQo_AKrVWic</recordid><startdate>20150105</startdate><enddate>20150105</enddate><creator>Xue, Fei</creator><creator>Liang, Linyun</creator><creator>Gu, Yijia</creator><creator>Takeuchi, Ichiro</creator><creator>Kalinin, Sergei V.</creator><creator>Chen, Long-Qing</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20150105</creationdate><title>Composition- and pressure-induced ferroelectric to antiferroelectric phase transitions in Sm-doped BiFeO3 system</title><author>Xue, Fei ; Liang, Linyun ; Gu, Yijia ; Takeuchi, Ichiro ; Kalinin, Sergei V. ; Chen, Long-Qing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c323t-ffe732251885b21d995d65b62752f36e93b64dd7ad57a8c74b97c443c959d2f83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Antiferroelectricity</topic><topic>Applied physics</topic><topic>Bismuth ferrite</topic><topic>Composition</topic><topic>Ferroelectric materials</topic><topic>Ferroelectricity</topic><topic>Hydrostatic pressure</topic><topic>Phase diagrams</topic><topic>Phase transitions</topic><topic>Three dimensional models</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xue, Fei</creatorcontrib><creatorcontrib>Liang, Linyun</creatorcontrib><creatorcontrib>Gu, Yijia</creatorcontrib><creatorcontrib>Takeuchi, Ichiro</creatorcontrib><creatorcontrib>Kalinin, Sergei V.</creatorcontrib><creatorcontrib>Chen, Long-Qing</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied physics letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xue, Fei</au><au>Liang, Linyun</au><au>Gu, Yijia</au><au>Takeuchi, Ichiro</au><au>Kalinin, Sergei V.</au><au>Chen, Long-Qing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Composition- and pressure-induced ferroelectric to antiferroelectric phase transitions in Sm-doped BiFeO3 system</atitle><jtitle>Applied physics letters</jtitle><date>2015-01-05</date><risdate>2015</risdate><volume>106</volume><issue>1</issue><issn>0003-6951</issn><eissn>1077-3118</eissn><abstract>A three-dimensional phenomenological model is proposed to describe both ferroelectricity and antiferroelectricity based on the Ginzburg-Landau-Devonshire theory. Its application to the multiferroic Sm-doped BiFeO3 system describes the temperature-, pressure-, and composition-induced ferroelectric to antiferroelectric phase transitions. The constructed temperature-composition and temperature-pressure phase diagrams show that compressive hydrostatic pressure and Sm doping have similar effects on the ferroelectric and antiferroelectric phase transitions. It is also indicated from the temperature-pressure phase diagram that the experimentally observed phase of BiFeO3 under the hydrostatic pressure from 3 GPa to 10 GPa is a PbZrO3-like antiferroelectric phase.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.4905444</doi></addata></record> |
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subjects | Antiferroelectricity Applied physics Bismuth ferrite Composition Ferroelectric materials Ferroelectricity Hydrostatic pressure Phase diagrams Phase transitions Three dimensional models |
title | Composition- and pressure-induced ferroelectric to antiferroelectric phase transitions in Sm-doped BiFeO3 system |
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