Preparation of PA6‐g‐LCX‐PAH fiber for removing formaldehyde
The innovative formaldehyde removal fibers (PA6‐g‐LCX‐PAH) have been developed by grafting polyacryloyl hydrazid (PAH) onto the polyamide molecules with bridging agent of Polyketide amide (LCX). The effects of varied grafting parameters including reaction time, reaction temperature, the ratio of PAH...
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Veröffentlicht in: | Polymer engineering and science 2018-09, Vol.58 (9), p.1652-1658 |
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creator | Zhang, Yi‐An Di, Jianfeng Du, Wenqin |
description | The innovative formaldehyde removal fibers (PA6‐g‐LCX‐PAH) have been developed by grafting polyacryloyl hydrazid (PAH) onto the polyamide molecules with bridging agent of Polyketide amide (LCX). The effects of varied grafting parameters including reaction time, reaction temperature, the ratio of PAH/LCX, and pH value have been discussed in detail to optimizing the grafting conditions. PA6‐g‐LCX‐PAH can be easily regenerated after treatment of glacial acetic acid at ambient temperature and the formaldehyde removal rate still reached 79.6% after repeated use for 10 times. The structure and morphology of PA6‐g‐LCX‐PAH were characterized by SEM, DSC and FT‐IR spectroscopy. It is concluded that the PA6‐g‐LCX‐PAH is a suitable removal agent of high‐ or mid‐concentration formaldehyde in a living or industrial environment. POLYM. ENG. SCI., 58:1652–1658, 2018. © 2017 Society of Plastics Engineers |
doi_str_mv | 10.1002/pen.24755 |
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The effects of varied grafting parameters including reaction time, reaction temperature, the ratio of PAH/LCX, and pH value have been discussed in detail to optimizing the grafting conditions. PA6‐g‐LCX‐PAH can be easily regenerated after treatment of glacial acetic acid at ambient temperature and the formaldehyde removal rate still reached 79.6% after repeated use for 10 times. The structure and morphology of PA6‐g‐LCX‐PAH were characterized by SEM, DSC and FT‐IR spectroscopy. It is concluded that the PA6‐g‐LCX‐PAH is a suitable removal agent of high‐ or mid‐concentration formaldehyde in a living or industrial environment. POLYM. ENG. SCI., 58:1652–1658, 2018. © 2017 Society of Plastics Engineers</description><identifier>ISSN: 0032-3888</identifier><identifier>EISSN: 1548-2634</identifier><identifier>DOI: 10.1002/pen.24755</identifier><language>eng</language><publisher>Newtown: Blackwell Publishing Ltd</publisher><subject>Acetic acid ; Ambient temperature ; Formaldehyde ; Grafting ; Infrared spectroscopy ; Morphology ; Polyamide resins ; Polymers ; Reaction time</subject><ispartof>Polymer engineering and science, 2018-09, Vol.58 (9), p.1652-1658</ispartof><rights>2017 Society of Plastics Engineers</rights><rights>2018 Society of Plastics Engineers</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-9711-1169</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpen.24755$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpen.24755$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Zhang, Yi‐An</creatorcontrib><creatorcontrib>Di, Jianfeng</creatorcontrib><creatorcontrib>Du, Wenqin</creatorcontrib><title>Preparation of PA6‐g‐LCX‐PAH fiber for removing formaldehyde</title><title>Polymer engineering and science</title><description>The innovative formaldehyde removal fibers (PA6‐g‐LCX‐PAH) have been developed by grafting polyacryloyl hydrazid (PAH) onto the polyamide molecules with bridging agent of Polyketide amide (LCX). The effects of varied grafting parameters including reaction time, reaction temperature, the ratio of PAH/LCX, and pH value have been discussed in detail to optimizing the grafting conditions. PA6‐g‐LCX‐PAH can be easily regenerated after treatment of glacial acetic acid at ambient temperature and the formaldehyde removal rate still reached 79.6% after repeated use for 10 times. The structure and morphology of PA6‐g‐LCX‐PAH were characterized by SEM, DSC and FT‐IR spectroscopy. It is concluded that the PA6‐g‐LCX‐PAH is a suitable removal agent of high‐ or mid‐concentration formaldehyde in a living or industrial environment. POLYM. ENG. SCI., 58:1652–1658, 2018. © 2017 Society of Plastics Engineers</description><subject>Acetic acid</subject><subject>Ambient temperature</subject><subject>Formaldehyde</subject><subject>Grafting</subject><subject>Infrared spectroscopy</subject><subject>Morphology</subject><subject>Polyamide resins</subject><subject>Polymers</subject><subject>Reaction time</subject><issn>0032-3888</issn><issn>1548-2634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNotkEtOwzAQhi0EEiGw4AaRWKf1284yVKVFiiCLLthZbmKHVHnhtKDsOAJn5CS4LYt5Sb9m_vkAuEdwhiDE88F0M0wFYxcgQIzKGHNCL0EAIcExkVJeg5tx3EGvJSwJwGPuzKCd3td9F_U2ylP--_1T-cgWbz7n6Tqy9da4yPYucqbtP-uuOg6tbkrzPpXmFlxZ3Yzm7r-GYPO03CzWcfa6el6kWVwh7ydmpUCwoAUXUgqWMLRNmNGJxZJJCi0ntkAaW55QhqwWWhBdCM2sLDkuvNsQPJzXDq7_OJhxr3b9wXX-osIIE04S6X8Nwfys-qobM6nB1a12k0JQHfEoj0ed8Kh8-XJqyB-g_FqS</recordid><startdate>201809</startdate><enddate>201809</enddate><creator>Zhang, Yi‐An</creator><creator>Di, Jianfeng</creator><creator>Du, Wenqin</creator><general>Blackwell Publishing Ltd</general><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-9711-1169</orcidid></search><sort><creationdate>201809</creationdate><title>Preparation of PA6‐g‐LCX‐PAH fiber for removing formaldehyde</title><author>Zhang, Yi‐An ; Di, Jianfeng ; Du, Wenqin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g1755-5d710c4c678875951b95ea9f285840f63fc1a2f69451fa7a73ac7a5f8d62c023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Acetic acid</topic><topic>Ambient temperature</topic><topic>Formaldehyde</topic><topic>Grafting</topic><topic>Infrared spectroscopy</topic><topic>Morphology</topic><topic>Polyamide resins</topic><topic>Polymers</topic><topic>Reaction time</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yi‐An</creatorcontrib><creatorcontrib>Di, Jianfeng</creatorcontrib><creatorcontrib>Du, Wenqin</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer engineering and science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yi‐An</au><au>Di, Jianfeng</au><au>Du, Wenqin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of PA6‐g‐LCX‐PAH fiber for removing formaldehyde</atitle><jtitle>Polymer engineering and science</jtitle><date>2018-09</date><risdate>2018</risdate><volume>58</volume><issue>9</issue><spage>1652</spage><epage>1658</epage><pages>1652-1658</pages><issn>0032-3888</issn><eissn>1548-2634</eissn><abstract>The innovative formaldehyde removal fibers (PA6‐g‐LCX‐PAH) have been developed by grafting polyacryloyl hydrazid (PAH) onto the polyamide molecules with bridging agent of Polyketide amide (LCX). The effects of varied grafting parameters including reaction time, reaction temperature, the ratio of PAH/LCX, and pH value have been discussed in detail to optimizing the grafting conditions. PA6‐g‐LCX‐PAH can be easily regenerated after treatment of glacial acetic acid at ambient temperature and the formaldehyde removal rate still reached 79.6% after repeated use for 10 times. The structure and morphology of PA6‐g‐LCX‐PAH were characterized by SEM, DSC and FT‐IR spectroscopy. It is concluded that the PA6‐g‐LCX‐PAH is a suitable removal agent of high‐ or mid‐concentration formaldehyde in a living or industrial environment. POLYM. ENG. SCI., 58:1652–1658, 2018. © 2017 Society of Plastics Engineers</abstract><cop>Newtown</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/pen.24755</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-9711-1169</orcidid></addata></record> |
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subjects | Acetic acid Ambient temperature Formaldehyde Grafting Infrared spectroscopy Morphology Polyamide resins Polymers Reaction time |
title | Preparation of PA6‐g‐LCX‐PAH fiber for removing formaldehyde |
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