Employing (half‐)titanocene complexes as initiators for the synthesis of end‐functionalized polylactides by coordination polymerization

ABSTRACT Seven (half‐)titanocene alkoxide complexes, [Cp2TiCl(OEt)], [Cp2TiCl(O‐2‐Bu)], [Cp2TiCl(OCH2CF2CF2H)], [CpTiCl2(OEt)], [CpTiCl2(O‐(S)‐2‐Bu)], [CpTiCl2(OCH2CF3)], and [Cp2TiCl(OCH2CF3)], were synthesized and employed in lactide coordination polymerization. These organotitanium (IV) compounds...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2018-10, Vol.56 (19), p.2192-2202
Hauptverfasser:	Patias, Georgios, Choinopoulos, Ioannis, Koinis, Spyros, Pitsikalis, Marinos
Format:	Artikel
Sprache:	eng
Schlagworte:	(half)‐titanocenes Block copolymers Chemical synthesis coordination polymerization Differential scanning calorimetry Initiators Isocyanates Magnetic properties NMR Nuclear magnetic resonance Optical properties polyisocyanates Polylactic acid polylactides Polymerization Polymers Ring opening polymerization Size exclusion chromatography Thermodynamic properties Thermogravimetric analysis
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