Trimerization and orbital ordering in Ba1−xSrxV13O18
We studied the physical properties of Ba1−xSrxV13O18 single crystals, which exhibit three different phases caused by the orbital and charge degrees of freedom in V t2g states. We found from the magnetic susceptibility and the NMR measurement that the low-temperature phase of this series of compounds...
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Veröffentlicht in: | Physical review. B 2017-12, Vol.96 (24) |
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container_title | Physical review. B |
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creator | Kajita, T Obata, Y Kakesu, Y Imai, Y Shmizu, Y Itoh, M Kuwahara, H Katsufuji, T |
description | We studied the physical properties of Ba1−xSrxV13O18 single crystals, which exhibit three different phases caused by the orbital and charge degrees of freedom in V t2g states. We found from the magnetic susceptibility and the NMR measurement that the low-temperature phase of this series of compounds is characterized by the spin-singlet state. We also found from the electrical resistivity and optical conductivity spectra that these compounds become heavily anisotropic in the low-temperature phase with V trimerization, indicating that the orbital ordering of V t2g states causes the anisotropy of the electronic structure of this series of compounds. |
doi_str_mv | 10.1103/PhysRevB.96.245126 |
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We also found from the electrical resistivity and optical conductivity spectra that these compounds become heavily anisotropic in the low-temperature phase with V trimerization, indicating that the orbital ordering of V t2g states causes the anisotropy of the electronic structure of this series of compounds.</description><subject>Anisotropy</subject><subject>Electrical resistivity</subject><subject>Electronic structure</subject><subject>Magnetic permeability</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Physical properties</subject><subject>Single crystals</subject><issn>2469-9950</issn><issn>2469-9969</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNo9jc1KAzEUhYMoWGpfwNWA6xnvTTI3c5e2-AeFllrdlkgSTakzNTOV6hO49hF9EgcUOYvvwAfnCHGKUCCCOp8_v7cL_zYumAqpS5R0IAZSE-fMxIf_vYRjMWrbNQAgARvggaBlii8-xQ_bxabObO2yJj3Gzm56ul7UT1mss7HF78-v_V3aP6CaYXUijoLdtH70x6G4v7pcTm7y6ez6dnIxzbdYmi73DtFokH3YGR9K4MAAkpwlpQGDZaIALJ0x7EJljAfEKhAqj94HNRRnv7vb1LzufNut1s0u1f3lSqJUWJHWUv0A0a9JMA</recordid><startdate>20171221</startdate><enddate>20171221</enddate><creator>Kajita, T</creator><creator>Obata, Y</creator><creator>Kakesu, Y</creator><creator>Imai, Y</creator><creator>Shmizu, Y</creator><creator>Itoh, M</creator><creator>Kuwahara, H</creator><creator>Katsufuji, T</creator><general>American Physical Society</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20171221</creationdate><title>Trimerization and orbital ordering in Ba1−xSrxV13O18</title><author>Kajita, T ; Obata, Y ; Kakesu, Y ; Imai, Y ; Shmizu, Y ; Itoh, M ; Kuwahara, H ; Katsufuji, T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p157t-ed1174020209d7ef509f90026da63401fa966f092d779df877e0118f613e1eef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Anisotropy</topic><topic>Electrical resistivity</topic><topic>Electronic structure</topic><topic>Magnetic permeability</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Physical properties</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kajita, T</creatorcontrib><creatorcontrib>Obata, Y</creatorcontrib><creatorcontrib>Kakesu, Y</creatorcontrib><creatorcontrib>Imai, Y</creatorcontrib><creatorcontrib>Shmizu, Y</creatorcontrib><creatorcontrib>Itoh, M</creatorcontrib><creatorcontrib>Kuwahara, H</creatorcontrib><creatorcontrib>Katsufuji, T</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Physical review. 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We also found from the electrical resistivity and optical conductivity spectra that these compounds become heavily anisotropic in the low-temperature phase with V trimerization, indicating that the orbital ordering of V t2g states causes the anisotropy of the electronic structure of this series of compounds.</abstract><cop>College Park</cop><pub>American Physical Society</pub><doi>10.1103/PhysRevB.96.245126</doi><oa>free_for_read</oa></addata></record> |
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subjects | Anisotropy Electrical resistivity Electronic structure Magnetic permeability NMR Nuclear magnetic resonance Physical properties Single crystals |
title | Trimerization and orbital ordering in Ba1−xSrxV13O18 |
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