A mechanistic approach to solvolysis of n-caproyl chloride (n-CH3(CH2)4 COCl) in solutions of acetone and acetonitrile with nucleophilic solvents

The study of the rate and rate constants in the alcoholysis of n-caproyl chloride in acetone and acetonitrile, reveals that SN2 mechanism is more favourable than SN1. A plot of logarithm of rate constant against the logarithm of molar concentration of alcohol gives a straight line with a slope close...

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Veröffentlicht in:	Oriental journal of chemistry 2009-01, Vol.25 (4), p.1017
Hauptverfasser:	Raveendran, G, Jayasree, K P
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetone Acetonitrile Enthalpy Entropy of activation Ionization Mercury compounds Rate constants Solvolysis
Online-Zugang:	Volltext
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