Application of classical thermodynamics to the conductivity in non-polar media
Electrical conductivity in non-polar media is a subject which recently regained interest. If most of experiments and theoretical developments were done more than 50 years ago, new experiments and theories have been recently published. As the electrical conductivity describes, at low field, the equil...
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| Veröffentlicht in: | The Journal of chemical physics 2016-06, Vol.144 (24), p.244501-244501 |
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| container_title | The Journal of chemical physics |
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| creator | Gourdin-Bertin, S. Chassagne, C. |
| description | Electrical conductivity in non-polar media is a subject which recently regained interest. If most of experiments and theoretical developments were done more than 50 years ago, new experiments and theories have been recently published. As the electrical conductivity describes, at low field, the equilibrium state of a system, it is natural to apply theories based on equilibrium thermodynamics. In this article, well-established classical thermodynamics and solvations models are applied to recently published data. This enables to get a new insight in intriguing phenomena, such as the linear dependence of the conductivity on the concentration of ionic surfactant and the evaluation of conductivity for the mixture of two miscible fluids, such as alcohol and alcane, which have very different conductivities. |
| doi_str_mv | 10.1063/1.4954046 |
| format | Article |
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| ispartof | The Journal of chemical physics, 2016-06, Vol.144 (24), p.244501-244501 |
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| language | eng |
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| source | AIP Journals Complete; Alma/SFX Local Collection |
| subjects | Computational fluid dynamics Conductivity Dependence ELECTRIC CONDUCTIVITY Electrical resistivity EXPERIMENTAL DATA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Thermodynamic equilibrium THERMODYNAMICS |
| title | Application of classical thermodynamics to the conductivity in non-polar media |
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