Sodium hydrogen carbonate as an alternative blowing agent in the preparation of palm-based polyurethane foam
An environmental-friendly blowing agent has been used to fabricate flexible polyurethane (PU) foam. Polyurethane foam was prepared from palm kernel oil-based monoester polyol (PKO-p) via prepolymerization method. Acetone has been used as solvent in this study. The developed polyurethane foam was cha...
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creator | Shakir, Amira Shakim Abdul Badri, Khairiah Haji Hua, Chia Chin |
description | An environmental-friendly blowing agent has been used to fabricate flexible polyurethane (PU) foam. Polyurethane foam was prepared from palm kernel oil-based monoester polyol (PKO-p) via prepolymerization method. Acetone has been used as solvent in this study. The developed polyurethane foam was characterized using tensile, differential scanning calorimetry analysis (DSC), thermogravimetric analysis (TGA), optical microscope and drop shape analyzer. The mechanical properties of the PU-reference (PU-R) and PU-NaHCO3 foam was analyzed by tensile using ASTM D 3574-01. From the results, the elongation of PU- NaHCO3 shows reduction to 26.3 % compared to PU-R. The DSC showed two glass transition temperatures in all samples that belonged to the PU-R and PU-NaHCO3. TGA revealed that the incorporation of sodium hydrogen carbonate into the PU system did not show significant difference as compared to the control PU. The morphology of both PU was investigated using optical microscope. Contact angle has been measured to determine the hydrophobicity of the PU. The PU- NaHCO3 exhibited an increase in contact angle (93.1°). |
doi_str_mv | 10.1063/1.4966759 |
format | Conference Proceeding |
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Polyurethane foam was prepared from palm kernel oil-based monoester polyol (PKO-p) via prepolymerization method. Acetone has been used as solvent in this study. The developed polyurethane foam was characterized using tensile, differential scanning calorimetry analysis (DSC), thermogravimetric analysis (TGA), optical microscope and drop shape analyzer. The mechanical properties of the PU-reference (PU-R) and PU-NaHCO3 foam was analyzed by tensile using ASTM D 3574-01. From the results, the elongation of PU- NaHCO3 shows reduction to 26.3 % compared to PU-R. The DSC showed two glass transition temperatures in all samples that belonged to the PU-R and PU-NaHCO3. TGA revealed that the incorporation of sodium hydrogen carbonate into the PU system did not show significant difference as compared to the control PU. The morphology of both PU was investigated using optical microscope. Contact angle has been measured to determine the hydrophobicity of the PU. The PU- NaHCO3 exhibited an increase in contact angle (93.1°).</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/1.4966759</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Acetone ; Blowing agents ; Chlorofluorocarbons ; Contact angle ; Differential scanning calorimetry ; Elongation ; Glass transition temperature ; Hydrophobicity ; Mechanical properties ; Morphology ; Optical properties ; Polyurethane foam ; Sodium bicarbonate ; Thermogravimetric analysis</subject><ispartof>AIP conference proceedings, 2016, Vol.1784 (1)</ispartof><rights>Author(s)</rights><rights>2016 Author(s). 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Polyurethane foam was prepared from palm kernel oil-based monoester polyol (PKO-p) via prepolymerization method. Acetone has been used as solvent in this study. The developed polyurethane foam was characterized using tensile, differential scanning calorimetry analysis (DSC), thermogravimetric analysis (TGA), optical microscope and drop shape analyzer. The mechanical properties of the PU-reference (PU-R) and PU-NaHCO3 foam was analyzed by tensile using ASTM D 3574-01. From the results, the elongation of PU- NaHCO3 shows reduction to 26.3 % compared to PU-R. The DSC showed two glass transition temperatures in all samples that belonged to the PU-R and PU-NaHCO3. TGA revealed that the incorporation of sodium hydrogen carbonate into the PU system did not show significant difference as compared to the control PU. The morphology of both PU was investigated using optical microscope. Contact angle has been measured to determine the hydrophobicity of the PU. The PU- NaHCO3 exhibited an increase in contact angle (93.1°).</description><subject>Acetone</subject><subject>Blowing agents</subject><subject>Chlorofluorocarbons</subject><subject>Contact angle</subject><subject>Differential scanning calorimetry</subject><subject>Elongation</subject><subject>Glass transition temperature</subject><subject>Hydrophobicity</subject><subject>Mechanical properties</subject><subject>Morphology</subject><subject>Optical properties</subject><subject>Polyurethane foam</subject><subject>Sodium bicarbonate</subject><subject>Thermogravimetric analysis</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2016</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNp90E1LxDAQBuAgCq6rB_9BwJvQNd9tj7L4BQseVPAWpk2626VtYpKu7L-36oI3T8PAM8PMi9AlJQtKFL-hC1EqlcvyCM2olDTLFVXHaEZIKTIm-PspOotxSwgr87yYoe7FmXbs8WZvglvbAdcQKjdAshgihgFDl2yY-nZncdW5z3ZYY5hgwu2A08ZiH6yHMAE3YNdgD12fVRCtwd51-zHYtIHB4sZBf45OGuiivTjUOXq7v3tdPmar54en5e0q80zylHFrjC0b2khe8FowaSAnJSeqZkZCUZm6loU0poKCSCYq1VhVldYWOTMFAcHn6Op3rw_uY7Qx6a0bpye6qBllVApBOJvU9a-KdZt-7tc-tD2Evd65oKk-JKm9af7DlOjv6P8G-BfXnHfR</recordid><startdate>20161117</startdate><enddate>20161117</enddate><creator>Shakir, Amira Shakim Abdul</creator><creator>Badri, Khairiah Haji</creator><creator>Hua, Chia Chin</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20161117</creationdate><title>Sodium hydrogen carbonate as an alternative blowing agent in the preparation of palm-based polyurethane foam</title><author>Shakir, Amira Shakim Abdul ; Badri, Khairiah Haji ; Hua, Chia Chin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p253t-3edde9f1f5383c425da709306c2d5a8bdcc585ddba80524b6fe6b9ee872d80a43</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acetone</topic><topic>Blowing agents</topic><topic>Chlorofluorocarbons</topic><topic>Contact angle</topic><topic>Differential scanning calorimetry</topic><topic>Elongation</topic><topic>Glass transition temperature</topic><topic>Hydrophobicity</topic><topic>Mechanical properties</topic><topic>Morphology</topic><topic>Optical properties</topic><topic>Polyurethane foam</topic><topic>Sodium bicarbonate</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shakir, Amira Shakim Abdul</creatorcontrib><creatorcontrib>Badri, Khairiah Haji</creatorcontrib><creatorcontrib>Hua, Chia Chin</creatorcontrib><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shakir, Amira Shakim Abdul</au><au>Badri, Khairiah Haji</au><au>Hua, Chia Chin</au><au>Badri, Khairiah Hj</au><au>Yaacob, Wan Zuhairi Wan</au><au>Ibrahim, Nazlina</au><au>Noorani, Mohd Salmi Md</au><au>Jumali, Mohammad Hafizuddin Hj</au><au>Ibrahim, Kamarulzaman</au><au>Rasol, Noor Hayati Ahmad</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>Sodium hydrogen carbonate as an alternative blowing agent in the preparation of palm-based polyurethane foam</atitle><btitle>AIP conference proceedings</btitle><date>2016-11-17</date><risdate>2016</risdate><volume>1784</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>An environmental-friendly blowing agent has been used to fabricate flexible polyurethane (PU) foam. Polyurethane foam was prepared from palm kernel oil-based monoester polyol (PKO-p) via prepolymerization method. Acetone has been used as solvent in this study. The developed polyurethane foam was characterized using tensile, differential scanning calorimetry analysis (DSC), thermogravimetric analysis (TGA), optical microscope and drop shape analyzer. The mechanical properties of the PU-reference (PU-R) and PU-NaHCO3 foam was analyzed by tensile using ASTM D 3574-01. From the results, the elongation of PU- NaHCO3 shows reduction to 26.3 % compared to PU-R. The DSC showed two glass transition temperatures in all samples that belonged to the PU-R and PU-NaHCO3. TGA revealed that the incorporation of sodium hydrogen carbonate into the PU system did not show significant difference as compared to the control PU. The morphology of both PU was investigated using optical microscope. Contact angle has been measured to determine the hydrophobicity of the PU. The PU- NaHCO3 exhibited an increase in contact angle (93.1°).</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.4966759</doi><tpages>5</tpages></addata></record> |
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language | eng |
recordid | cdi_proquest_journals_2121544032 |
source | AIP Journals Complete |
subjects | Acetone Blowing agents Chlorofluorocarbons Contact angle Differential scanning calorimetry Elongation Glass transition temperature Hydrophobicity Mechanical properties Morphology Optical properties Polyurethane foam Sodium bicarbonate Thermogravimetric analysis |
title | Sodium hydrogen carbonate as an alternative blowing agent in the preparation of palm-based polyurethane foam |
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