Synthesis of a Modifier for Rubbers with Silica-filler by Reaction of N-tert-Butyl-2-benzothiazolylsulfenamide with Trimethylolpropane Triglycidyl Ether and Characterization of the Reaction Product
Reaction of N-tert -butyl-2-benzothiazolylsulfenamide with trimethylolpropane triglycidyl ether was performed, and the product was characterized and studied as an additive to rubber. Interaction of this additive with rubber was studied by the method of equilibrium swelling. The additive was found to...
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| Veröffentlicht in: | Russian journal of applied chemistry 2018-07, Vol.91 (7), p.1188-1192 |
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| container_title | Russian journal of applied chemistry |
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| creator | Sedlova, N. G. Shilov, I. B. Fomin, S. V. Mansurova, I. A. |
| description | Reaction of
N-tert
-butyl-2-benzothiazolylsulfenamide with trimethylolpropane triglycidyl ether was performed, and the product was characterized and studied as an additive to rubber. Interaction of this additive with rubber was studied by the method of equilibrium swelling. The additive was found to increase the amount of cross-links in the polymer matrix and to improve the process characteristics of rubber stocks with silica, decreasing their viscosity and vulcanization time and enhancing the resistance to scorching. The use of this additive allows preparation of vulcanized rubbers with higher modulus, compared to the rubbers modified with the product of the reaction of methacrylic acid with trimethylolpropane triglycidyl ether. |
| doi_str_mv | 10.1134/S1070427218070182 |
| format | Article |
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N-tert
-butyl-2-benzothiazolylsulfenamide with trimethylolpropane triglycidyl ether was performed, and the product was characterized and studied as an additive to rubber. Interaction of this additive with rubber was studied by the method of equilibrium swelling. The additive was found to increase the amount of cross-links in the polymer matrix and to improve the process characteristics of rubber stocks with silica, decreasing their viscosity and vulcanization time and enhancing the resistance to scorching. The use of this additive allows preparation of vulcanized rubbers with higher modulus, compared to the rubbers modified with the product of the reaction of methacrylic acid with trimethylolpropane triglycidyl ether.</description><identifier>ISSN: 1070-4272</identifier><identifier>EISSN: 1608-3296</identifier><identifier>DOI: 10.1134/S1070427218070182</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Crosslinking ; Industrial Chemistry/Chemical Engineering ; Macromolecular Compounds and Polymeric Materials ; Methacrylic acid ; Rubber ; Silicon dioxide ; Vulcanization</subject><ispartof>Russian journal of applied chemistry, 2018-07, Vol.91 (7), p.1188-1192</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c305t-bb42a81834a5689b900e75abd5ccddd83ad959b2ef7897168f307c1a812c6b363</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070427218070182$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070427218070182$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Sedlova, N. G.</creatorcontrib><creatorcontrib>Shilov, I. B.</creatorcontrib><creatorcontrib>Fomin, S. V.</creatorcontrib><creatorcontrib>Mansurova, I. A.</creatorcontrib><title>Synthesis of a Modifier for Rubbers with Silica-filler by Reaction of N-tert-Butyl-2-benzothiazolylsulfenamide with Trimethylolpropane Triglycidyl Ether and Characterization of the Reaction Product</title><title>Russian journal of applied chemistry</title><addtitle>Russ J Appl Chem</addtitle><description>Reaction of
N-tert
-butyl-2-benzothiazolylsulfenamide with trimethylolpropane triglycidyl ether was performed, and the product was characterized and studied as an additive to rubber. Interaction of this additive with rubber was studied by the method of equilibrium swelling. The additive was found to increase the amount of cross-links in the polymer matrix and to improve the process characteristics of rubber stocks with silica, decreasing their viscosity and vulcanization time and enhancing the resistance to scorching. The use of this additive allows preparation of vulcanized rubbers with higher modulus, compared to the rubbers modified with the product of the reaction of methacrylic acid with trimethylolpropane triglycidyl ether.</description><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Crosslinking</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Macromolecular Compounds and Polymeric Materials</subject><subject>Methacrylic acid</subject><subject>Rubber</subject><subject>Silicon dioxide</subject><subject>Vulcanization</subject><issn>1070-4272</issn><issn>1608-3296</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1Uc1O3DAQjlCRoMADcLPUs4vtJI5zpCtakKAgFs6Rf8bEyMRb21GVfb--V73aVhyqnmY039-MpqrOKflMad1crCnpSMM6RkVpqGAH1THlROCa9fxD6csU7_Cj6mNKr4SQnnNxXP1aL1MeIbmEgkUS3QXjrIOIbIjocVYKYkI_XR7R2nmnJbbO-wKrBT2C1NmFaSf8jjPEjL_MefGYYQXTNuTRyW3wi0-ztzDJN2dgb_UU3RvkcfHBb2LYyAl2oxe_aGcWj67KQhHJyaDVKGMJgei28m9UAd-jH2Iws86n1aGVPsHZn3pSPX-9elpd49v7bzery1usa9JmrFTDpKCibmTLRa96QqBrpTKt1sYYUUvTt71iYDvRd5QLW5NO0yJhmqua1yfVp71vWfvHDCkPr2GOU4kcGGVEMN4QWlh0z9IxpBTBDptysIzLQMmw-9bwz7eKhu01qXCnF4jvzv8X_QbPqJtJ</recordid><startdate>20180701</startdate><enddate>20180701</enddate><creator>Sedlova, N. G.</creator><creator>Shilov, I. B.</creator><creator>Fomin, S. V.</creator><creator>Mansurova, I. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180701</creationdate><title>Synthesis of a Modifier for Rubbers with Silica-filler by Reaction of N-tert-Butyl-2-benzothiazolylsulfenamide with Trimethylolpropane Triglycidyl Ether and Characterization of the Reaction Product</title><author>Sedlova, N. G. ; Shilov, I. B. ; Fomin, S. V. ; Mansurova, I. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c305t-bb42a81834a5689b900e75abd5ccddd83ad959b2ef7897168f307c1a812c6b363</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Crosslinking</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Macromolecular Compounds and Polymeric Materials</topic><topic>Methacrylic acid</topic><topic>Rubber</topic><topic>Silicon dioxide</topic><topic>Vulcanization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sedlova, N. G.</creatorcontrib><creatorcontrib>Shilov, I. B.</creatorcontrib><creatorcontrib>Fomin, S. V.</creatorcontrib><creatorcontrib>Mansurova, I. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of applied chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sedlova, N. G.</au><au>Shilov, I. B.</au><au>Fomin, S. V.</au><au>Mansurova, I. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of a Modifier for Rubbers with Silica-filler by Reaction of N-tert-Butyl-2-benzothiazolylsulfenamide with Trimethylolpropane Triglycidyl Ether and Characterization of the Reaction Product</atitle><jtitle>Russian journal of applied chemistry</jtitle><stitle>Russ J Appl Chem</stitle><date>2018-07-01</date><risdate>2018</risdate><volume>91</volume><issue>7</issue><spage>1188</spage><epage>1192</epage><pages>1188-1192</pages><issn>1070-4272</issn><eissn>1608-3296</eissn><abstract>Reaction of
N-tert
-butyl-2-benzothiazolylsulfenamide with trimethylolpropane triglycidyl ether was performed, and the product was characterized and studied as an additive to rubber. Interaction of this additive with rubber was studied by the method of equilibrium swelling. The additive was found to increase the amount of cross-links in the polymer matrix and to improve the process characteristics of rubber stocks with silica, decreasing their viscosity and vulcanization time and enhancing the resistance to scorching. The use of this additive allows preparation of vulcanized rubbers with higher modulus, compared to the rubbers modified with the product of the reaction of methacrylic acid with trimethylolpropane triglycidyl ether.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070427218070182</doi><tpages>5</tpages></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Chemical synthesis Chemistry Chemistry and Materials Science Chemistry/Food Science Crosslinking Industrial Chemistry/Chemical Engineering Macromolecular Compounds and Polymeric Materials Methacrylic acid Rubber Silicon dioxide Vulcanization |
| title | Synthesis of a Modifier for Rubbers with Silica-filler by Reaction of N-tert-Butyl-2-benzothiazolylsulfenamide with Trimethylolpropane Triglycidyl Ether and Characterization of the Reaction Product |
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