The Role of Electron-Density Transfer and Electronegativity in Understanding Chemical Reactivity and Bonding
The Electrostatic-Covalent-Transfer, ECT, model provides a fit of bond energies for a large data base whose accuracy for the full data set exceeds that of any other reported approach. This result has important implications for teaching peridodic trends in ionic-covalent bonding and electronegativity...
Gespeichert in:
Veröffentlicht in: | Journal of chemical education 1996-02, Vol.73 (2), p.123 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | 2 |
container_start_page | 123 |
container_title | Journal of chemical education |
container_volume | 73 |
creator | Drago, Russell S Wong, Ngai M |
description | The Electrostatic-Covalent-Transfer, ECT, model provides a fit of bond energies for a large data base whose accuracy for the full data set exceeds that of any other reported approach. This result has important implications for teaching peridodic trends in ionic-covalent bonding and electronegativity in both general and inorganic chemistry. Several examples are discussed to illustrate the use of the parameters and tables of parameters are presented to encourage their application to new systems. |
doi_str_mv | 10.1021/ed073p123 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_212027469</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>9420001</sourcerecordid><originalsourceid>FETCH-LOGICAL-a284t-fa4c9c5d7a4bc67afe91390478de003ea3fa1b11076f9ed450c716199aa356df3</originalsourceid><addsrcrecordid>eNplkEtPAjEUhRujiYgu_AeNiQsXo73tvLpUwEdCYkJgPbl0bmHI0MF2MOHfOwjBhau7-L5zbnIYuwXxCELCE5UiUxuQ6oz1QKs8AiXzc9YTHYx0kseX7CqElRAgE533WD1dEp80NfHG8lFNpvWNi4bkQtXu-NSjC5Y8R1eeKC2wrb73uHJ85kryoe145RZ8sKR1ZbDmE0JzlPbRl-aXX7MLi3Wgm-Pts9nraDp4j8afbx-D53GEMo_byGJstEnKDOO5STO0pEFpEWd5SUIoQmUR5gAiS62mMk6EySAFrRFVkpZW9dndoXfjm68thbZYNVvvupeFBClkFqe6kx4OkvFNCJ5ssfHVGv2uAFHstyxOW3bu_cFFE_66_ns_GLVzxg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>212027469</pqid></control><display><type>article</type><title>The Role of Electron-Density Transfer and Electronegativity in Understanding Chemical Reactivity and Bonding</title><source>ACS Publications</source><creator>Drago, Russell S ; Wong, Ngai M</creator><creatorcontrib>Drago, Russell S ; Wong, Ngai M</creatorcontrib><description>The Electrostatic-Covalent-Transfer, ECT, model provides a fit of bond energies for a large data base whose accuracy for the full data set exceeds that of any other reported approach. This result has important implications for teaching peridodic trends in ionic-covalent bonding and electronegativity in both general and inorganic chemistry. Several examples are discussed to illustrate the use of the parameters and tables of parameters are presented to encourage their application to new systems.</description><identifier>ISSN: 0021-9584</identifier><identifier>EISSN: 1938-1328</identifier><identifier>DOI: 10.1021/ed073p123</identifier><identifier>CODEN: JCEDA8</identifier><language>eng</language><publisher>Easton: Division of Chemical Education</publisher><subject>Chemical bonds ; Chemical reactions ; Chemistry ; Chlorine ; Donors ; Electronegativity ; Electrons ; Energy ; Inorganic Chemistry ; Ionization ; Ions ; Organic chemistry ; Polarity ; Potassium</subject><ispartof>Journal of chemical education, 1996-02, Vol.73 (2), p.123</ispartof><rights>Copyright American Chemical Society Feb 1996</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a284t-fa4c9c5d7a4bc67afe91390478de003ea3fa1b11076f9ed450c716199aa356df3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ed073p123$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ed073p123$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,778,782,2754,27063,27911,27912,56725,56775</link.rule.ids></links><search><creatorcontrib>Drago, Russell S</creatorcontrib><creatorcontrib>Wong, Ngai M</creatorcontrib><title>The Role of Electron-Density Transfer and Electronegativity in Understanding Chemical Reactivity and Bonding</title><title>Journal of chemical education</title><addtitle>J. Chem. Educ</addtitle><description>The Electrostatic-Covalent-Transfer, ECT, model provides a fit of bond energies for a large data base whose accuracy for the full data set exceeds that of any other reported approach. This result has important implications for teaching peridodic trends in ionic-covalent bonding and electronegativity in both general and inorganic chemistry. Several examples are discussed to illustrate the use of the parameters and tables of parameters are presented to encourage their application to new systems.</description><subject>Chemical bonds</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chlorine</subject><subject>Donors</subject><subject>Electronegativity</subject><subject>Electrons</subject><subject>Energy</subject><subject>Inorganic Chemistry</subject><subject>Ionization</subject><subject>Ions</subject><subject>Organic chemistry</subject><subject>Polarity</subject><subject>Potassium</subject><issn>0021-9584</issn><issn>1938-1328</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AIMQZ</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNplkEtPAjEUhRujiYgu_AeNiQsXo73tvLpUwEdCYkJgPbl0bmHI0MF2MOHfOwjBhau7-L5zbnIYuwXxCELCE5UiUxuQ6oz1QKs8AiXzc9YTHYx0kseX7CqElRAgE533WD1dEp80NfHG8lFNpvWNi4bkQtXu-NSjC5Y8R1eeKC2wrb73uHJ85kryoe145RZ8sKR1ZbDmE0JzlPbRl-aXX7MLi3Wgm-Pts9nraDp4j8afbx-D53GEMo_byGJstEnKDOO5STO0pEFpEWd5SUIoQmUR5gAiS62mMk6EySAFrRFVkpZW9dndoXfjm68thbZYNVvvupeFBClkFqe6kx4OkvFNCJ5ssfHVGv2uAFHstyxOW3bu_cFFE_66_ns_GLVzxg</recordid><startdate>19960201</startdate><enddate>19960201</enddate><creator>Drago, Russell S</creator><creator>Wong, Ngai M</creator><general>Division of Chemical Education</general><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>0-V</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88B</scope><scope>88E</scope><scope>88I</scope><scope>8A4</scope><scope>8FE</scope><scope>8FG</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AIMQZ</scope><scope>ALSLI</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>CJNVE</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>KB.</scope><scope>LIQON</scope><scope>M0P</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>M2P</scope><scope>MBDVC</scope><scope>PADUT</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEDU</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope></search><sort><creationdate>19960201</creationdate><title>The Role of Electron-Density Transfer and Electronegativity in Understanding Chemical Reactivity and Bonding</title><author>Drago, Russell S ; Wong, Ngai M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a284t-fa4c9c5d7a4bc67afe91390478de003ea3fa1b11076f9ed450c716199aa356df3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>Chemical bonds</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chlorine</topic><topic>Donors</topic><topic>Electronegativity</topic><topic>Electrons</topic><topic>Energy</topic><topic>Inorganic Chemistry</topic><topic>Ionization</topic><topic>Ions</topic><topic>Organic chemistry</topic><topic>Polarity</topic><topic>Potassium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Drago, Russell S</creatorcontrib><creatorcontrib>Wong, Ngai M</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Social Sciences Premium Collection</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Education Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>Education Periodicals</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest One Literature</collection><collection>Social Science Premium Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>Natural Science Collection (ProQuest)</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>Education Collection</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Materials Science Database</collection><collection>ProQuest One Literature - U.S. Customers Only</collection><collection>Education Database</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Research Library</collection><collection>Science Database</collection><collection>Research Library (Corporate)</collection><collection>Research Library China</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Education</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of chemical education</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Drago, Russell S</au><au>Wong, Ngai M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Role of Electron-Density Transfer and Electronegativity in Understanding Chemical Reactivity and Bonding</atitle><jtitle>Journal of chemical education</jtitle><addtitle>J. Chem. Educ</addtitle><date>1996-02-01</date><risdate>1996</risdate><volume>73</volume><issue>2</issue><spage>123</spage><pages>123-</pages><issn>0021-9584</issn><eissn>1938-1328</eissn><coden>JCEDA8</coden><abstract>The Electrostatic-Covalent-Transfer, ECT, model provides a fit of bond energies for a large data base whose accuracy for the full data set exceeds that of any other reported approach. This result has important implications for teaching peridodic trends in ionic-covalent bonding and electronegativity in both general and inorganic chemistry. Several examples are discussed to illustrate the use of the parameters and tables of parameters are presented to encourage their application to new systems.</abstract><cop>Easton</cop><pub>Division of Chemical Education</pub><doi>10.1021/ed073p123</doi></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0021-9584 |
ispartof | Journal of chemical education, 1996-02, Vol.73 (2), p.123 |
issn | 0021-9584 1938-1328 |
language | eng |
recordid | cdi_proquest_journals_212027469 |
source | ACS Publications |
subjects | Chemical bonds Chemical reactions Chemistry Chlorine Donors Electronegativity Electrons Energy Inorganic Chemistry Ionization Ions Organic chemistry Polarity Potassium |
title | The Role of Electron-Density Transfer and Electronegativity in Understanding Chemical Reactivity and Bonding |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T14%3A51%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20Role%20of%20Electron-Density%20Transfer%20and%20Electronegativity%20in%20Understanding%20Chemical%20Reactivity%20and%20Bonding&rft.jtitle=Journal%20of%20chemical%20education&rft.au=Drago,%20Russell%20S&rft.date=1996-02-01&rft.volume=73&rft.issue=2&rft.spage=123&rft.pages=123-&rft.issn=0021-9584&rft.eissn=1938-1328&rft.coden=JCEDA8&rft_id=info:doi/10.1021/ed073p123&rft_dat=%3Cproquest_cross%3E9420001%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=212027469&rft_id=info:pmid/&rfr_iscdi=true |