Influence of Nickel Sulfate Additives to Electrolytes Subjected to Microarc Oxidation on the Structure, Composition, and Properties of Coatings Formed on Titanium

The influence of nickel sulfate additives to acid and basic electrolytes for microarc oxidation on the structure, composition, and properties of coatings formed on VT1-0 titanium were studied to produce poorly soluble titanium anodes. We established the possibility of incorporating nickel (nickel ox...

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Veröffentlicht in:Surface engineering and applied electrochemistry 2018-07, Vol.54 (4), p.331-337
Hauptverfasser: Bogdashkina, N. L., Gerasimov, M. V., Zalavutdinov, R. Kh, Kasatkina, I. V., Krit, B. L., Lyudin, V. B., Fedichkin, I. D., Shcherbakov, A. I., Apelfeld, A. V.
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container_end_page 337
container_issue 4
container_start_page 331
container_title Surface engineering and applied electrochemistry
container_volume 54
creator Bogdashkina, N. L.
Gerasimov, M. V.
Zalavutdinov, R. Kh
Kasatkina, I. V.
Krit, B. L.
Lyudin, V. B.
Fedichkin, I. D.
Shcherbakov, A. I.
Apelfeld, A. V.
description The influence of nickel sulfate additives to acid and basic electrolytes for microarc oxidation on the structure, composition, and properties of coatings formed on VT1-0 titanium were studied to produce poorly soluble titanium anodes. We established the possibility of incorporating nickel (nickel oxide) into the composition of coatings. X-ray diffraction analysis showed that the coatings contained nickel oxide β-NiO with a cubic lattice, TiO 2 in the form of rutile, and SiO 2 in the form of high-temperature β-cristobalite. The maximum thickness and nickel content in the surface layer and the minimum values of both the anodic dissolution currents and the electrical strength were obtained for the coatings formed in silicate-alkali (3 g/L KOH + 4.5 g/L Na 2 SiO 3 ) electrolyte with the addition of 1 g/L of nickel sulfate NiSO 4 .
doi_str_mv 10.3103/S106837551804004X
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subjects Additives
Anodic dissolution
Coatings
Composition
Cristobalite
Cubic lattice
Dissolution
Electrolytes
Engineering
Machines
Manufacturing
Nickel
Nickel oxides
Nickel sulfate
Oxidation
Processes
Silicon dioxide
Sodium silicates
Surface layers
Titanium
Titanium dioxide
X-ray diffraction
title Influence of Nickel Sulfate Additives to Electrolytes Subjected to Microarc Oxidation on the Structure, Composition, and Properties of Coatings Formed on Titanium
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