Mechanochemically prepared polyaniline and graphene-based nanocomposites as electrodes of supercapacitors
Conductive nanocomposites based on polyaniline and graphene (PAni/Gr) were prepared by cheap and efficient mechanochemical method. The uniform distribution of Gr nanoparticles in the polymer matrix and the ordering of the polymer chains due to the action of mechanical shear stresses, which were esta...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2018-11, Vol.22 (11), p.3419-3430 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Posudievsky, Oleg Yu Kozarenko, Olga A. Dyadyun, Vyacheslav S. Kotenko, Igor E. Koshechko, Vyacheslav G. Pokhodenko, Vitaly D. |
| description | Conductive nanocomposites based on polyaniline and graphene (PAni/Gr) were prepared by cheap and efficient mechanochemical method. The uniform distribution of Gr nanoparticles in the polymer matrix and the ordering of the polymer chains due to the action of mechanical shear stresses, which were established by TEM, stipulated high specific capacitance about 920 F g
−1
in − 0.2–1.0 V vs. Ag/AgCl potential range. PAni/Gr-based electrodes are able to provide the specific capacitance of ~ 750 F g
−1
at 2 A g
−1
in symmetric supercapacitors (SSC) and stably cycle at the operating voltage
V
= 0.65 V for 10,000 charge-discharge cycles with 96% capacitance retention, whereas the increasing of
V
leads to the loss of stability as a result of the cathode degradation. PAni/Gr-based SSC possessed improved self-discharge showed high rate capability, and the specific power of such SSC could reach ~ 10 kW kg
−1
at the specific energy of ~ 18 W h kg
−1
. |
| doi_str_mv | 10.1007/s10008-018-4052-6 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2116912239</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2116912239</sourcerecordid><originalsourceid>FETCH-LOGICAL-c353t-6169573400f3ff6c7b9ba894bb145105555d87a99f94d664d961ebd06db8992f3</originalsourceid><addsrcrecordid>eNp1kE9PxCAQxYnRxHX1A3hr4hmFQikczcZ_icaLngmlw243XUDoHvbby1oTT3IYZjLv9yZ5CF1TcksJae9yqURiQiXmpKmxOEELyhnDpBXy9KevseRSnqOLnLeE0FZQskDDG9iN8cFuYDdYM46HKiaIJkFfxTAejB_GwUNlfF-tk4kb8IA7k8vaH7GwiyEPE-TK5ApGsFMKfZmCq_I-QrImGjtMIeVLdObMmOHq91-iz8eHj9Uzfn1_elndv2LLGjZhQYVqWsYJccw5YdtOdUYq3nWUN5Q05fWyNUo5xXsheK8Eha4nou-kUrVjS3Qz-8YUvvaQJ70N--TLSV3TYk7rmqmiorPKppBzAqdjGnYmHTQl-pionhPVJVF9TFSLwtQzk4vWryH9Of8PfQOtSHpu</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2116912239</pqid></control><display><type>article</type><title>Mechanochemically prepared polyaniline and graphene-based nanocomposites as electrodes of supercapacitors</title><source>Springer Nature - Complete Springer Journals</source><creator>Posudievsky, Oleg Yu ; Kozarenko, Olga A. ; Dyadyun, Vyacheslav S. ; Kotenko, Igor E. ; Koshechko, Vyacheslav G. ; Pokhodenko, Vitaly D.</creator><creatorcontrib>Posudievsky, Oleg Yu ; Kozarenko, Olga A. ; Dyadyun, Vyacheslav S. ; Kotenko, Igor E. ; Koshechko, Vyacheslav G. ; Pokhodenko, Vitaly D.</creatorcontrib><description>Conductive nanocomposites based on polyaniline and graphene (PAni/Gr) were prepared by cheap and efficient mechanochemical method. The uniform distribution of Gr nanoparticles in the polymer matrix and the ordering of the polymer chains due to the action of mechanical shear stresses, which were established by TEM, stipulated high specific capacitance about 920 F g
−1
in − 0.2–1.0 V vs. Ag/AgCl potential range. PAni/Gr-based electrodes are able to provide the specific capacitance of ~ 750 F g
−1
at 2 A g
−1
in symmetric supercapacitors (SSC) and stably cycle at the operating voltage
V
= 0.65 V for 10,000 charge-discharge cycles with 96% capacitance retention, whereas the increasing of
V
leads to the loss of stability as a result of the cathode degradation. PAni/Gr-based SSC possessed improved self-discharge showed high rate capability, and the specific power of such SSC could reach ~ 10 kW kg
−1
at the specific energy of ~ 18 W h kg
−1
.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-018-4052-6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Capacitance ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Discharge ; Electrochemistry ; Electrodes ; Energy Storage ; Graphene ; Nanocomposites ; Nanoparticles ; Original Paper ; Physical Chemistry ; Polyanilines ; Polymers ; Silver chloride ; Supercapacitors</subject><ispartof>Journal of solid state electrochemistry, 2018-11, Vol.22 (11), p.3419-3430</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-6169573400f3ff6c7b9ba894bb145105555d87a99f94d664d961ebd06db8992f3</citedby><cites>FETCH-LOGICAL-c353t-6169573400f3ff6c7b9ba894bb145105555d87a99f94d664d961ebd06db8992f3</cites><orcidid>0000-0003-2327-3151</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-018-4052-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-018-4052-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Posudievsky, Oleg Yu</creatorcontrib><creatorcontrib>Kozarenko, Olga A.</creatorcontrib><creatorcontrib>Dyadyun, Vyacheslav S.</creatorcontrib><creatorcontrib>Kotenko, Igor E.</creatorcontrib><creatorcontrib>Koshechko, Vyacheslav G.</creatorcontrib><creatorcontrib>Pokhodenko, Vitaly D.</creatorcontrib><title>Mechanochemically prepared polyaniline and graphene-based nanocomposites as electrodes of supercapacitors</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>Conductive nanocomposites based on polyaniline and graphene (PAni/Gr) were prepared by cheap and efficient mechanochemical method. The uniform distribution of Gr nanoparticles in the polymer matrix and the ordering of the polymer chains due to the action of mechanical shear stresses, which were established by TEM, stipulated high specific capacitance about 920 F g
−1
in − 0.2–1.0 V vs. Ag/AgCl potential range. PAni/Gr-based electrodes are able to provide the specific capacitance of ~ 750 F g
−1
at 2 A g
−1
in symmetric supercapacitors (SSC) and stably cycle at the operating voltage
V
= 0.65 V for 10,000 charge-discharge cycles with 96% capacitance retention, whereas the increasing of
V
leads to the loss of stability as a result of the cathode degradation. PAni/Gr-based SSC possessed improved self-discharge showed high rate capability, and the specific power of such SSC could reach ~ 10 kW kg
−1
at the specific energy of ~ 18 W h kg
−1
.</description><subject>Analytical Chemistry</subject><subject>Capacitance</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Discharge</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Energy Storage</subject><subject>Graphene</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polyanilines</subject><subject>Polymers</subject><subject>Silver chloride</subject><subject>Supercapacitors</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kE9PxCAQxYnRxHX1A3hr4hmFQikczcZ_icaLngmlw243XUDoHvbby1oTT3IYZjLv9yZ5CF1TcksJae9yqURiQiXmpKmxOEELyhnDpBXy9KevseRSnqOLnLeE0FZQskDDG9iN8cFuYDdYM46HKiaIJkFfxTAejB_GwUNlfF-tk4kb8IA7k8vaH7GwiyEPE-TK5ApGsFMKfZmCq_I-QrImGjtMIeVLdObMmOHq91-iz8eHj9Uzfn1_elndv2LLGjZhQYVqWsYJccw5YdtOdUYq3nWUN5Q05fWyNUo5xXsheK8Eha4nou-kUrVjS3Qz-8YUvvaQJ70N--TLSV3TYk7rmqmiorPKppBzAqdjGnYmHTQl-pionhPVJVF9TFSLwtQzk4vWryH9Of8PfQOtSHpu</recordid><startdate>20181101</startdate><enddate>20181101</enddate><creator>Posudievsky, Oleg Yu</creator><creator>Kozarenko, Olga A.</creator><creator>Dyadyun, Vyacheslav S.</creator><creator>Kotenko, Igor E.</creator><creator>Koshechko, Vyacheslav G.</creator><creator>Pokhodenko, Vitaly D.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2327-3151</orcidid></search><sort><creationdate>20181101</creationdate><title>Mechanochemically prepared polyaniline and graphene-based nanocomposites as electrodes of supercapacitors</title><author>Posudievsky, Oleg Yu ; Kozarenko, Olga A. ; Dyadyun, Vyacheslav S. ; Kotenko, Igor E. ; Koshechko, Vyacheslav G. ; Pokhodenko, Vitaly D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-6169573400f3ff6c7b9ba894bb145105555d87a99f94d664d961ebd06db8992f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Analytical Chemistry</topic><topic>Capacitance</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Discharge</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Energy Storage</topic><topic>Graphene</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polyanilines</topic><topic>Polymers</topic><topic>Silver chloride</topic><topic>Supercapacitors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Posudievsky, Oleg Yu</creatorcontrib><creatorcontrib>Kozarenko, Olga A.</creatorcontrib><creatorcontrib>Dyadyun, Vyacheslav S.</creatorcontrib><creatorcontrib>Kotenko, Igor E.</creatorcontrib><creatorcontrib>Koshechko, Vyacheslav G.</creatorcontrib><creatorcontrib>Pokhodenko, Vitaly D.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Posudievsky, Oleg Yu</au><au>Kozarenko, Olga A.</au><au>Dyadyun, Vyacheslav S.</au><au>Kotenko, Igor E.</au><au>Koshechko, Vyacheslav G.</au><au>Pokhodenko, Vitaly D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanochemically prepared polyaniline and graphene-based nanocomposites as electrodes of supercapacitors</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2018-11-01</date><risdate>2018</risdate><volume>22</volume><issue>11</issue><spage>3419</spage><epage>3430</epage><pages>3419-3430</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>Conductive nanocomposites based on polyaniline and graphene (PAni/Gr) were prepared by cheap and efficient mechanochemical method. The uniform distribution of Gr nanoparticles in the polymer matrix and the ordering of the polymer chains due to the action of mechanical shear stresses, which were established by TEM, stipulated high specific capacitance about 920 F g
−1
in − 0.2–1.0 V vs. Ag/AgCl potential range. PAni/Gr-based electrodes are able to provide the specific capacitance of ~ 750 F g
−1
at 2 A g
−1
in symmetric supercapacitors (SSC) and stably cycle at the operating voltage
V
= 0.65 V for 10,000 charge-discharge cycles with 96% capacitance retention, whereas the increasing of
V
leads to the loss of stability as a result of the cathode degradation. PAni/Gr-based SSC possessed improved self-discharge showed high rate capability, and the specific power of such SSC could reach ~ 10 kW kg
−1
at the specific energy of ~ 18 W h kg
−1
.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-018-4052-6</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-2327-3151</orcidid></addata></record> |
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| subjects | Analytical Chemistry Capacitance Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Discharge Electrochemistry Electrodes Energy Storage Graphene Nanocomposites Nanoparticles Original Paper Physical Chemistry Polyanilines Polymers Silver chloride Supercapacitors |
| title | Mechanochemically prepared polyaniline and graphene-based nanocomposites as electrodes of supercapacitors |
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