Temperature dependence of photophysical properties of a dinuclear C^N-cyclometalated Pt() complex with an intimate Pt-Pt contact. Zero-field splitting and sub-state decay rates of the lowest triplet

The temperature dependence (1.7 K < T < 100 K) of emission decay is reported for the first time for a type of di-nuclear Pt complex featuring a metal-metal-to-ligand charge transfer (MMLCT) lowest energy transition that arises from a strong Pt-Pt interaction. The effect of local variation of t...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2018, Vol.2 (38), p.2596-2514
Hauptverfasser:	Deaton, Joseph C, Chakraborty, Arnab, Czerwieniec, Rafal, Yersin, Hartmut, Castellano, Felix N
Format:	Artikel
Sprache:	eng
Schlagworte:	Charge transfer Coordination compounds Decay rate Phosphorescence Photoluminescence Temperature Temperature dependence
Online-Zugang:	Volltext
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