Oxidant-free oxidative gold catalysis: the new paradigm in cross-coupling reactions
The construction of C-C and C-X (X = hetero atom) bonds is the core aspect for the assembly of molecules. In this regard, late transition-metal-catalyzed cross-coupling reactions have retained their dominance for decades. Lately, gold catalysts have been emerging as a reliable contender for such tra...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018, Vol.54 (79), p.1169-1183 |
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| creator | Akram, Manjur O Banerjee, Somsuvra Saswade, Sagar S Bedi, Vaibhav Patil, Nitin T |
| description | The construction of C-C and C-X (X = hetero atom) bonds is the core aspect for the assembly of molecules. In this regard, late transition-metal-catalyzed cross-coupling reactions have retained their dominance for decades. Lately, gold catalysts have been emerging as a reliable contender for such transformations owing to the recent findings that reveal gold's potential beyond carbophilic π-Lewis acid. The newfound ability of gold to undergo redox transformations under certain circumstances has allowed us to explore gold catalysts as a viable alternative to other late transition-metals for efficient construction of cross-coupled products. This feature article critically presents an overview of all the redox neutral cross-coupling reactions enabled by gold catalysis, which we believe would stimulate further research activities in this promising area.
The construction of C-C and C-X (X = hetero atom) bonds is the core aspect for the assembly of molecules. This feature article critically presents an overview of all the redox neutral cross-coupling reactions enabled by gold catalysis, which we believe would stimulate further research activities in this promising area. |
| doi_str_mv | 10.1039/c8cc05601c |
| format | Article |
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The construction of C-C and C-X (X = hetero atom) bonds is the core aspect for the assembly of molecules. 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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Catalysis Catalysts Chemical reactions Coupling (molecular) Cross coupling Gold Lewis acid Transformations |
| title | Oxidant-free oxidative gold catalysis: the new paradigm in cross-coupling reactions |
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