Tunable Corrosion Behavior of Calcium Phosphate Coated Fe-Mn-Si Alloys for Bone Implant Applications
This work deals with the electrodeposition of calcium phosphate coatings on the surface of Fe-Mn-Si alloys which is designed for bone implant applications. Three different alloy compositions are considered (Fe-23Mn-5Si, Fe-26Mn-5Si and Fe-30Mn-5Si, all in wt pct). In order to explore the impact of h...
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| Veröffentlicht in: | Metallurgical and materials transactions. A, Physical metallurgy and materials science Physical metallurgy and materials science, 2018-12, Vol.49 (12), p.6553-6560 |
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| creator | Drevet, Richard Zhukova, Yulia Kadirov, Pulat Dubinskiy, Sergey Kazakbiev, Alibek Pustov, Yury Prokoshkin, Sergey |
| description | This work deals with the electrodeposition of calcium phosphate coatings on the surface of Fe-Mn-Si alloys which is designed for bone implant applications. Three different alloy compositions are considered (Fe-23Mn-5Si, Fe-26Mn-5Si and Fe-30Mn-5Si, all in wt pct). In order to explore the impact of hydrogen peroxide (H
2
O
2
) on the electrodeposition process, two different electrolytic solutions are studied, one that contains no H
2
O
2
and the other that contains 9 vol pct H
2
O
2
. The physicochemical characterizations reveal that the electrodeposited coating is made of an apatite phase of low crystallinity with less porosity when hydrogen peroxide is added to the electrolyte solution. The corrosion measurements of the uncoated and coated alloys are also carried out during immersion in Hank’s solution at 310 K (37 °C), a physiological solution that simulates the inorganic composition of the body fluids. Interestingly, it was found that the manganese content in the alloy and the porosity of the coating both modify the corrosion behavior,
i.e
., the biodegradability of the Fe-Mn-Si alloy immersed in the physiological environment. Hence, the corrosion behavior of the calcium phosphate-coated Fe-Mn-Si alloys is tunable as a function of the experimental parameters used during the synthesis of the material. |
| doi_str_mv | 10.1007/s11661-018-4907-6 |
| format | Article |
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2
O
2
) on the electrodeposition process, two different electrolytic solutions are studied, one that contains no H
2
O
2
and the other that contains 9 vol pct H
2
O
2
. The physicochemical characterizations reveal that the electrodeposited coating is made of an apatite phase of low crystallinity with less porosity when hydrogen peroxide is added to the electrolyte solution. The corrosion measurements of the uncoated and coated alloys are also carried out during immersion in Hank’s solution at 310 K (37 °C), a physiological solution that simulates the inorganic composition of the body fluids. Interestingly, it was found that the manganese content in the alloy and the porosity of the coating both modify the corrosion behavior,
i.e
., the biodegradability of the Fe-Mn-Si alloy immersed in the physiological environment. Hence, the corrosion behavior of the calcium phosphate-coated Fe-Mn-Si alloys is tunable as a function of the experimental parameters used during the synthesis of the material.</description><identifier>ISSN: 1073-5623</identifier><identifier>EISSN: 1543-1940</identifier><identifier>DOI: 10.1007/s11661-018-4907-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alloys ; Apatite ; Biodegradability ; Body fluids ; Calcium ; Calcium phosphates ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Coated electrodes ; Composition ; Corrosion ; Electrodeposition ; Ferrous alloys ; Hydrogen peroxide ; Iron ; Manganese ; Materials Science ; Metallic Materials ; Nanotechnology ; Phosphate coatings ; Physiology ; Porosity ; Structural Materials ; Submerging ; Surfaces and Interfaces ; Thin Films</subject><ispartof>Metallurgical and materials transactions. A, Physical metallurgy and materials science, 2018-12, Vol.49 (12), p.6553-6560</ispartof><rights>The Minerals, Metals & Materials Society and ASM International 2018</rights><rights>Metallurgical and Materials Transactions A is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-b8631a86a7219cf76cc631e2b78a4b8e3f36e3914e974952813dff3ec0337b7c3</citedby><cites>FETCH-LOGICAL-c316t-b8631a86a7219cf76cc631e2b78a4b8e3f36e3914e974952813dff3ec0337b7c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11661-018-4907-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11661-018-4907-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Drevet, Richard</creatorcontrib><creatorcontrib>Zhukova, Yulia</creatorcontrib><creatorcontrib>Kadirov, Pulat</creatorcontrib><creatorcontrib>Dubinskiy, Sergey</creatorcontrib><creatorcontrib>Kazakbiev, Alibek</creatorcontrib><creatorcontrib>Pustov, Yury</creatorcontrib><creatorcontrib>Prokoshkin, Sergey</creatorcontrib><title>Tunable Corrosion Behavior of Calcium Phosphate Coated Fe-Mn-Si Alloys for Bone Implant Applications</title><title>Metallurgical and materials transactions. A, Physical metallurgy and materials science</title><addtitle>Metall Mater Trans A</addtitle><description>This work deals with the electrodeposition of calcium phosphate coatings on the surface of Fe-Mn-Si alloys which is designed for bone implant applications. Three different alloy compositions are considered (Fe-23Mn-5Si, Fe-26Mn-5Si and Fe-30Mn-5Si, all in wt pct). In order to explore the impact of hydrogen peroxide (H
2
O
2
) on the electrodeposition process, two different electrolytic solutions are studied, one that contains no H
2
O
2
and the other that contains 9 vol pct H
2
O
2
. The physicochemical characterizations reveal that the electrodeposited coating is made of an apatite phase of low crystallinity with less porosity when hydrogen peroxide is added to the electrolyte solution. The corrosion measurements of the uncoated and coated alloys are also carried out during immersion in Hank’s solution at 310 K (37 °C), a physiological solution that simulates the inorganic composition of the body fluids. Interestingly, it was found that the manganese content in the alloy and the porosity of the coating both modify the corrosion behavior,
i.e
., the biodegradability of the Fe-Mn-Si alloy immersed in the physiological environment. Hence, the corrosion behavior of the calcium phosphate-coated Fe-Mn-Si alloys is tunable as a function of the experimental parameters used during the synthesis of the material.</description><subject>Alloys</subject><subject>Apatite</subject><subject>Biodegradability</subject><subject>Body fluids</subject><subject>Calcium</subject><subject>Calcium phosphates</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Coated electrodes</subject><subject>Composition</subject><subject>Corrosion</subject><subject>Electrodeposition</subject><subject>Ferrous alloys</subject><subject>Hydrogen peroxide</subject><subject>Iron</subject><subject>Manganese</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Nanotechnology</subject><subject>Phosphate coatings</subject><subject>Physiology</subject><subject>Porosity</subject><subject>Structural Materials</subject><subject>Submerging</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><issn>1073-5623</issn><issn>1543-1940</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp1kEFLAzEQhYMoWKs_wFvAczSTbJPNsV2sFioK1nPIplm7ZbtZk12h_96UFTx5mRmG771hHkK3QO-BUvkQAYQAQiEnmaKSiDM0gVnGCaiMnqeZSk5mgvFLdBXjnlIKiosJ2m6G1pSNw4UPwcfat3jhdua79gH7ChemsfVwwG87H7ud6U9cqlu8dOSlJe81njeNP0ZcJX7hW4dXh64xbY_nXdfU1vTJMV6ji8o00d389in6WD5uimeyfn1aFfM1sRxET8pccDC5MJKBspUU1qaFY6XMTVbmjldcOK4gc0pmasZy4Nuq4s5SzmUpLZ-iu9G3C_5rcLHXez-ENp3UDIApzjKuEgUjZdPDMbhKd6E-mHDUQPUpTD2GqVOY-hSmFknDRk1MbPvpwp_z_6IfJqN2YQ</recordid><startdate>20181201</startdate><enddate>20181201</enddate><creator>Drevet, Richard</creator><creator>Zhukova, Yulia</creator><creator>Kadirov, Pulat</creator><creator>Dubinskiy, Sergey</creator><creator>Kazakbiev, Alibek</creator><creator>Pustov, Yury</creator><creator>Prokoshkin, Sergey</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>4T-</scope><scope>4U-</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AF</scope><scope>8AO</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L6V</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>S0X</scope></search><sort><creationdate>20181201</creationdate><title>Tunable Corrosion Behavior of Calcium Phosphate Coated Fe-Mn-Si Alloys for Bone Implant Applications</title><author>Drevet, Richard ; Zhukova, Yulia ; Kadirov, Pulat ; Dubinskiy, Sergey ; Kazakbiev, Alibek ; Pustov, Yury ; Prokoshkin, Sergey</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-b8631a86a7219cf76cc631e2b78a4b8e3f36e3914e974952813dff3ec0337b7c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Alloys</topic><topic>Apatite</topic><topic>Biodegradability</topic><topic>Body fluids</topic><topic>Calcium</topic><topic>Calcium phosphates</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Coated electrodes</topic><topic>Composition</topic><topic>Corrosion</topic><topic>Electrodeposition</topic><topic>Ferrous alloys</topic><topic>Hydrogen peroxide</topic><topic>Iron</topic><topic>Manganese</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Nanotechnology</topic><topic>Phosphate coatings</topic><topic>Physiology</topic><topic>Porosity</topic><topic>Structural Materials</topic><topic>Submerging</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Drevet, Richard</creatorcontrib><creatorcontrib>Zhukova, Yulia</creatorcontrib><creatorcontrib>Kadirov, Pulat</creatorcontrib><creatorcontrib>Dubinskiy, Sergey</creatorcontrib><creatorcontrib>Kazakbiev, Alibek</creatorcontrib><creatorcontrib>Pustov, Yury</creatorcontrib><creatorcontrib>Prokoshkin, Sergey</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Docstoc</collection><collection>University Readers</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>STEM Database</collection><collection>ProQuest Pharma Collection</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Proquest Research Library</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>Metallurgical and materials transactions. A, Physical metallurgy and materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Drevet, Richard</au><au>Zhukova, Yulia</au><au>Kadirov, Pulat</au><au>Dubinskiy, Sergey</au><au>Kazakbiev, Alibek</au><au>Pustov, Yury</au><au>Prokoshkin, Sergey</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tunable Corrosion Behavior of Calcium Phosphate Coated Fe-Mn-Si Alloys for Bone Implant Applications</atitle><jtitle>Metallurgical and materials transactions. A, Physical metallurgy and materials science</jtitle><stitle>Metall Mater Trans A</stitle><date>2018-12-01</date><risdate>2018</risdate><volume>49</volume><issue>12</issue><spage>6553</spage><epage>6560</epage><pages>6553-6560</pages><issn>1073-5623</issn><eissn>1543-1940</eissn><abstract>This work deals with the electrodeposition of calcium phosphate coatings on the surface of Fe-Mn-Si alloys which is designed for bone implant applications. Three different alloy compositions are considered (Fe-23Mn-5Si, Fe-26Mn-5Si and Fe-30Mn-5Si, all in wt pct). In order to explore the impact of hydrogen peroxide (H
2
O
2
) on the electrodeposition process, two different electrolytic solutions are studied, one that contains no H
2
O
2
and the other that contains 9 vol pct H
2
O
2
. The physicochemical characterizations reveal that the electrodeposited coating is made of an apatite phase of low crystallinity with less porosity when hydrogen peroxide is added to the electrolyte solution. The corrosion measurements of the uncoated and coated alloys are also carried out during immersion in Hank’s solution at 310 K (37 °C), a physiological solution that simulates the inorganic composition of the body fluids. Interestingly, it was found that the manganese content in the alloy and the porosity of the coating both modify the corrosion behavior,
i.e
., the biodegradability of the Fe-Mn-Si alloy immersed in the physiological environment. Hence, the corrosion behavior of the calcium phosphate-coated Fe-Mn-Si alloys is tunable as a function of the experimental parameters used during the synthesis of the material.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11661-018-4907-6</doi><tpages>8</tpages></addata></record> |
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| ispartof | Metallurgical and materials transactions. A, Physical metallurgy and materials science, 2018-12, Vol.49 (12), p.6553-6560 |
| issn | 1073-5623 1543-1940 |
| language | eng |
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| source | Springer Online Journals【Remote access available】 |
| subjects | Alloys Apatite Biodegradability Body fluids Calcium Calcium phosphates Characterization and Evaluation of Materials Chemistry and Materials Science Coated electrodes Composition Corrosion Electrodeposition Ferrous alloys Hydrogen peroxide Iron Manganese Materials Science Metallic Materials Nanotechnology Phosphate coatings Physiology Porosity Structural Materials Submerging Surfaces and Interfaces Thin Films |
| title | Tunable Corrosion Behavior of Calcium Phosphate Coated Fe-Mn-Si Alloys for Bone Implant Applications |
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